| 研究生: |
張順欽 Zhang, Shun-Qin |
|---|---|
| 論文名稱: |
興建中都市垃圾焚化廠周遭環境中重金屬之特徵 Characteristics of Heavy Metals near a Municipal Solid Waste Incineration Plant during Construction Period |
| 指導教授: |
李文智
Lee, Wen-Jhy |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 環境工程學系 Department of Environmental Engineering |
| 論文出版年: | 2004 |
| 畢業學年度: | 92 |
| 語文別: | 中文 |
| 論文頁數: | 129 |
| 中文關鍵詞: | 重金屬 、大氣 、都市垃圾焚化廠 、底泥 、水體 |
| 外文關鍵詞: | municipal solid waste incineration plant, ambient air, heavy metal, water, sediment |
| 相關次數: | 點閱:120 下載:1 |
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本研究係針對U垃圾焚化廠周界大氣、水體及底泥進行重金屬之採樣與分析,建立U垃圾焚化廠周界大氣、水體及底泥重金屬之背景資料。並收集當地之氣象資料以ISCST模式評估U焚化廠於(一)正常操作狀況下(二)緊急狀況下(三)停爐重新啟動狀況下之重金屬(鉛、鎘、汞)對U淨水場及取水口可能造成之水質影響,以及飲用水中含上述物質濃度對於人體健康風險評估。研究結果歸納如下:1. U垃圾焚化廠周界大氣中重金屬鉛之濃度介於0.0178~0.133 μg/Nm3之間,平均濃度為0.042 μg/Nm3;金屬鎘之濃度介於0.00023~0.0031 μg/Nm3之間,平均濃度為0.000905 μg/Nm3;金屬汞之濃度介於0.000014~0.0015 μg/Nm3之間,平均濃度為0.000362 μg/Nm3。2. U垃圾焚化廠周界水體中重金屬之濃度均以地殼元素錳和鈣濃度較高,其平均濃度分別為19.9 mg/L及47.4 mg/L,金屬鉛之濃度介於ND~0.008 mg/L之間;金屬鎘之濃度介於ND~0.00154 mg/L之間;金屬汞四次之濃度均低於偵測極限。3. U垃圾焚化廠周界底泥中重金屬之含量均以鎂、鈣與鐵含量最高,其平均含量分別為1645、6709及23572 μg/g。金屬鉛之含量介於4.34~33.7 μg/g之間,平均為12.8 μg/g;金屬鎘之含量前兩季均低於偵測極限,後兩季之含量介於0.007~0.035 μg/g之間,平均為0.0215 μg/g;金屬汞之含量前兩季亦均低於偵測極限,後兩季之含量介於.0016~0.0440 μg/g之間,平均為0.0619 μg/g。4. 模擬U焚化廠於一般操作狀況下排放煙道廢氣之重金屬鉛、鎘及汞之平均沈降率分別為鉛沈降率介於12.2~15.8 ng/m2.day,平均值為14.0 ng/m2.day;鎘沈降率介於1.83~2.37 ng/m2.day,平均值為2.10 ng/m2.day;汞沈降率介於1.83~2.37 ng/m2.day,平均值為2.10 ng/m2.day。5. 模擬U焚化廠於緊急狀況下排放煙道廢氣之重金屬鉛、鎘及汞之平均沈降率分別為鉛沈降率介於848~1134 μg/m2.day,平均值為986 μg/m2.day;鎘沈降率介於165~220 μg/m2.day,平均值為191 μg/m2.day;汞沈降率介於160~214 μg/m2.day,平均值為186 μg/m2.day。6. 模擬U焚化廠於停爐重新啟動狀況下排放煙道廢氣之重金屬鉛、鎘及汞之平均沈降率分別為鉛沈降率介於6783~9074 μg/m2.day,平均值為7885 μg/m2.day;鎘沈降率介於1017~1361 μg/m2.day,平均值為1183 μg/m2.day;汞沈降率介於1017~1361 μg/m2.day,平均值為1183 μg/m2.day。7. 重金屬鎘及汞之危害商數分別為5.47×10-10與9.12×10-10,其值遠低於1之危害風險管理值上限。
This study is to characterize the heavy metals from ambient air, water and sediment surrounding the U incinerator. We already established the background of it’s surrounding environment and collected local information of meteorology. Using these data and the ISCST3 model was used to estimate the influence of heavy metals ( Pb, Cd, Hg ) emitting from the U incinerator to the quality of water inlet and the water treatment plant in following conditions:1. normal operation 2. emergency effluent 3. re-operation. Furthermore, to evaluate the risk of public health. The study results were as follows : 1. the concentration of Pb in ambient air ranged from 0.0178 to 0.133 μg/Nm3 (mean=0.042 μg/Nm3 ), concentration of Cd ranged from 0.00023 to 0.0031 μg/Nm3 (mean=0.000905 μg/Nm3 ), and concentration of Hg ranged from 0.000014 to 0.0015 μg/Nm3 (mean=0.000362 μg/Nm3 ). 2. the concentration of Mn
( mean=19.9 mg/L ) and Ca ( mean=47.4 mg/L ) were higher than other metals in water. Concentration of Pb in water ranged from ND to 0.008 mg/L, concentration of Cd ranged from ND to 0.00154 mg/L, and concentration of Hg is ND. 3. Concentration of Mg ( mean=1645 μg/g ), Ca ( mean=6709 μg/g ), Fe ( mean=23572μg/g ) were higher than other metals in bottom sediments. The content of Pb ranged from 4.34 to 33.7 μg/g ( mean=12.8 μg/g ), content of Cd ranged from 0.007 to 0.035 μg/g ( mean=0.0215 μg/g ), and content of Hg ranged from ND to 0.0440 μg/g( mean=0.0619 μg/g ). 4. In normal operation of the incinerator, the deposition of Pb ranged from 12.2 to 15.8 ng/m2.day ( mean=14.0 ng/m2.day ), deposition of Cd ranged from 1.83 to 2.37 ng/m2.day ( mean=2.10 ng/m2.day ), deposition of Hg ranged from 1.83 to 2.37 ng/m2.day (mean=2.10 ng/m2.day ). 5. In emergency effluent, the deposition of Pb ranged from 848 to 1134 μg/m2.day ( mean=986 μg/m2.day ), deposition of Cd ranged from 165 to 220 μg/m2.day ( mean=191 μg/m2.day ), deposition of Hg ranged from 160 to 214 μg/m2.day ( mean=186 μg/m2.day ). 6. In re-operation state, the deposition of Pb ranged from 6783 to 9074 μg/m2.day ( mean=7885 μg/m2.day ), deposition of Cd ranged from 1017 to 1361 μg/m2.day ( mean=1183 μg/m2.day ), deposition of Hg ranged from 1017 to 1361 μg/m2.day ( mean=1183 μg/m2.day ). 7. the Hazard Quotient of the Cd and Hg were 5.47×10-10 and 9.12×10-10, both were lower than 1 which is the Hazard Quotient in law.
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