雙核銅錯合物[Cu2(dppm)2(MeCN)2][BF4]2 (14(BF4)2)與鹽類 NaBH3CN、KSCN、NaNCO、NaN3反應，得到了四核結構的[Cu4(dppm)4(BH3CN)4] (15)與[Cu4(dppm)4(SCN)4] (16)的結構，三核結構的[Cu3(dppm)3(NCO)2][BF4] (17)與[Cu3(dppm)3(N3)2][BF4] (18)
錯合物15與PPNCl、Bu4NBr、Bu4NI反應得到了[PPN][Cu2(dppm)2(BH3CN)2(μ-Cl)] ((PPN)19)、 [Cu2(dppm)2(BH3CN)2(μ-Br)][ Cu3(dppm)3(μ3-Br)](20)、[ Cu3(dppm)3(μ3-I)][BH3CN] (21(BH3CN))，所有新合成的錯合物，均以ESI-MS、NMR(1H、31P及11B)、IR、EA鑑定，其中錯合物15、16、17、(PPN)19、20及21(BH3CN)單晶構造也用X光繞射數據確定。錯合物15與過量NaCl在CH3OH迴流的產物中，長出一個晶體，其結構為[Cu4(dppm)4(CN)2(BH3CN)2](22)

Dinuclear copper(I) complex [Cu2(dppm)2(MeCN)2][BF4]2 (14(BF4)2) reacted with salts of NaBH3CN, KSCN, NaNCO and NaN3, producing tetranuclear copper(I) complexes of [Cu4(dppm)4(BH3CN)4] (15) and [Cu4(dppm)4(SCN)4] (16), and trinuclear copper(I) complexes of [Cu3(dppm)3(NCO)2][BF4] (17) and [Cu3(dppm)3(NCO)2][BF4] (18). Complex 15 reacted with PPNCl, Bu4NBr and Bu4NI, producing complexes of [PPN][Cu2(dppm)2(BH3CN)2(μ-Cl)] ((PPN)19), [Cu2(dppm)2(BH3CN)2(μ-Br)][ Cu3(dppm)3(μ3-Br)](20) and [Cu3(dppm)3(μ3-I)][BH3CN] (21(BH3CN)). All of the new complexes have been characterized by ESI-MS, NMR(1H、31P and 11B), IR and EA. The single crystal structure of complexes 15, 16, 17, (PPN)19, 20 and 21(BH3CN) have also been confirmed by X-ray crystallography. Complex 15 reacted with excess NaCl under reflux in CH3OH, producing complicated products. From the products, one single crystal with the structure of [Cu4(dppm)4(CN)2(BH3CN)2] (22) was determined.

1. Cotton, F. A.; Wilkinson, G. “Advance Inorganic chemistry”, 5th Ed. John Wiley & Son; NewYork, 1988, chapter 14, p. 544
2. (a) Vrieze, K.; Koten, G. V. “Sulfurdiimine, Triazenido, Azabutadiene and Triatomic Hetero Anion Ligands” in “Comprehensive Coordination Chemistry”, Wilkinson, G.(Ed.), Pergamon; Oxford, 1987, vol.2, p. 225. (b) http://en.wikipedia.org/wiki/Pseudohalogen.
3. Palenik, G. J.; Mathew, M.; Steffen, W. L.; Beran, G. J. Am. Chem.Soc., 1975, 97, 1059
4. Randaccio, L.; Marsich, N.; Nardin, G. J. Am. Chem.Soc., 1973, 95, 4053
5. Ramaprabhu, S.; Amstutz, N.; Edwin, A. C.; Luckena; Bernardinellib, G. J. Chem. Soc., Dalton Trans., 1993, 871
6. Randaccio, L.; Marsich, N.; Nardin, G.; Nardin, G. Inorg. Chim. Acta, 1974, 10, L5
7. Nicola, C. D.; Effendy; Fazaroh, F.; Pettinari, C.; Skelton, B. W. Somers, N.; White, A. H. Inorg. Chim. Acta, 2005, 358, 720
8. Tatsumi, K.; Lang, J. P. Inorg. Chem., 1998, 37, 6308
9. Bera, J. K.; Nethaji, M.; Samuelson, A. G. Inorg. Chem., 1999, 38, 218
10. Zhou, W. B.; Dong, Z. C.; Song, J. L.; Zeng, H. Y.; Cao, R.; Guo, G. C.; Huang, J. S.; Li, J. Cluster Sci., 2002, 13, 119
11. Ziolo, R. F.; Gaughan, A. P.; Dori, Z.; Pierpont, C. G.; Eisenberg, R. Inorg. Chem., 1971, 10, 1289
12. Melmed, K. M.; Li, T.I.; Mayerle, J. J.; Lippard, S. J. J. Am. Chem.Soc., 1974, 96, 69
13. Homsy, N. K.; Noltemeyer, M.; Roesky, H. W.; Schmidt, H. G.; Sheldrick, G. M. Inorg. Chim. Acta, 1984, 90, L59
14. Zhang, L.; Ren, Z. G.; Lia, H. X.; Lang, J. P. CrystEngComm, 2011, 13, 1400
15. Vreshch, V.; Nohra, B.; Lescop, C.; Réau, R. Inorg. Chem. 2013, 52, 1496
16. Diez, J.; Gamasa, M. P.; Gimeno, J. J. Chem. Soc. Dalton Trans, 1987, 1275
17. Ratliff, K. S.; Fanwick, P. E.; Kubiak, C. P. Polyhedron 1990, 9, 1487
18. Ferguson, G.; Lloyed, B. R.; Puddephatt, R. J. Organometallics 1986, 5, 344
19. Yam, Vivian W. W.; Lee, W. K.; Cheung, K. K.; Crystall, B.; Phillips, D. J. Chem. Soc., Dalton Trans. 1996, 3283
20. Nardin, G.; Randaccio, L.; Zangrando, E. J. Chem. Soc., Dalton Trans. 1975, 2566
21. Harvey, P. D.; Drouin, M.; Zhang, T. Inorg. Chem. 1997, 36, 4998
22. Diez, J.; Gamasa, M. P.; Gimeno, J.; Aguirre, A.; Garcı´a-Granda, S. Organometallics 1997, 16, 3684
23. Ruina, Y.; Kunhua, L.; Yimin, H.; Dongmei, W.; Douman, J. Polyhedron 1997, 16, 4033
24. Chan, C. K.; Guo, C. X.; Wang, R. J.; Mak, T. C. W.; Che, C. M. J. Chem. Soc., Dalton Trans. 1995, 753
25. Cuesta, R.; Ruiz, J.; Moreno, J. M.; Colacio, E. Inorg. Chim. Acta 1994, 227, 43
26. Colacio, E.; Cuesta, R.; Moreno, J. M. Inorg. Chem., 1997, 36, 1084