由於鋰資源的稀缺性問題，同族且成本較低的鈉、鉀離子電池研究逐年攀升。然而，為發揮高理論電容量特性，傳統電池多半是選擇有機電解液，這也使得電池有汙染環境及安全上的隱憂。因此，許多研究將目光放到更安全的水系電池上，尤其水系鋅離子電池，因具有低成本、高安全性、組裝環境簡便、高理論電容量(820 mAh/g)等特性，成為熱門選擇之一。
然而至此，水系離子電池仍有許多需要克服的難題：對於陰極活性材料而言，隨著鋅離子的遷入遷出，許多材料不堪負荷充放電過程的體積膨脹問題，進而造成急劇電容量衰減以及低循環壽命。此外，氧化物的低導電特性，也使得電荷轉移電阻的提升，從而降低電池的性能。因此開發合適的陰極材料，正是目前水系離子電池迫切需要解決的難題。
本研究透過水熱法，在合成金屬有機骨架材料過程中摻雜碲元素，經碳化後，得到碳骨架及氧化釩的複合材料。透過結合釩的多價態、碲元素高導電性、金屬有機骨架材料堅固結構等性質，得到高電容量、循環壽命佳、低電荷轉移電阻的水系鋅離子電池陰極材料。

Rechargeable aqueous zinc-ion batteries are regard as excellent candidate for next generation storage device due to their high theorical capacity (820 mAh/g), low cost and safety. However, most of the cathode materials are suffer in short-cycle life due to the insertion/extraction during charge and discharge process. Here in, we proposed a new type of composition, which combined carbon frameworks and vanadium oxide, and doped it with Tellurium to enhanced the electrical performance of batteries. Benefitting from the doping of Te and framework structure, the batteries shows high specific capacity (331 mAh/g),and long cycle life (500 cycles). Besides, with XPS and in-situ Raman, we revealed the reaction mechanism behind. It is helpful for the development of aqueous zinc batteries in near future.

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