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研究生: 陳彥廷
Chen, Yan-Ting
論文名稱: 殼聚醣奈米銀粒子複合材料做為永續應用之SERS基板製程與特性研究
Research on the process and characteristics of chitosan nano-silver composite as SERS substrate for sustainable application
指導教授: 林建宏
Lin, Chien-Hong
共同指導教授: 施士塵
Shi, Shih-Chen
學位類別: 碩士
Master
系所名稱: 工學院 - 機械工程學系
Department of Mechanical Engineering
論文出版年: 2023
畢業學年度: 112
語文別: 中文
論文頁數: 71
中文關鍵詞: 殼聚醣奈米金屬增塑劑SERSBPA檢測
外文關鍵詞: Chitosan, SERS, Nano-silver, Plasticizer, BPA
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  • 摘要 I Extended Abstract II 致謝 XI 目錄 XII 表目錄 XV 圖目錄 XVI 第1章 緒論 1 1-1 . 前言 1 1-1-1 . 環境賀爾蒙 1 1-1-2 . 殼聚醣 4 1-1-3 . Surface-enhanced Raman Spectroscopy (SERS) 4 1-2 . 研究動機 5 1-3 . 文獻回顧 7 1-3-1 . 殼聚糖綠色還原奈米粒子 7 1-3-2 . 多元醇做為增塑劑提升機械強度 12 1-3-3 . ONE-STEP SERS基板檢測 14 1-4 . 研究歷程及目標 17 第2章 應用理論 18 2-1 . 殼聚醣綠色還原奈米粒子 18 2-1-1 . 化學還原法製備奈米顆粒 18 2-2 . 多元醇做為增塑劑提升機械強度 19 2-2-1 . 增塑機制 19 2-2-2 . 增塑劑分子量與增塑性質關係 20 2-2-3 . 機械性質 21 2-3 . SERS基板檢測 22 2-3-1 . One-Step基板 22 2-3-2 . SERS增強因子(Enhancement Factor) 22 第3章 實驗設計與實施 24 3-1 . 實驗材料及儀器 24 3-1-1 . 還原奈米粒子實驗材料 24 3-1-2 . SERS基板成膜實驗 24 3-1-3 . SERS 檢測 24 3-1-4 . 製程及測試儀器 25 3-2 . 實驗流程 25 3-2-1 . 綠色還原奈米粒子 26 3-2-2 . One-Step SERS基板-成膜和檢測 26 3-3 . 實驗分析 27 3-3-1 . 紫外/可見光譜儀 (UV-Vis) 27 3-3-2 . 傅里葉轉換紅外光譜 (FTIR) 27 3-3-3 . 掃描式電子顯微鏡(SEM) 27 3-3-4 . 高解析場發射掃描穿透式電子顯微鏡(TEM) 28 3-3-5 . 數位顯微鏡 28 3-3-6 . 微小維克氏硬度 28 3-3-7 . 奈微拉伸測試 28 3-4 . SERS檢測試驗 29 3-4-1 . 結晶紫檢測 29 第4章 結果與討論 30 4-1 . 殼聚醣綠色還原奈米粒子 30 4-1-2 . 控制金屬粒子尺寸 34 4-1-3 . SERS基板上金屬顆粒的分散性 38 4-2 . 多元醇做為增塑劑 43 4-2-1 . 成膜底材測試. 43 4-2-2 . 硬度試驗 45 4-2-3 . 拉伸試驗 46 4-3 . SERS檢測 47 4-3-1 . 結晶紫染料 47 4-3-2 . 環境荷爾蒙 - 雙酚A (BPA) 50 4-3-3 . 感熱紙溶水SERS檢測 52 第5章 總結 53 5-1 . 結論 53 5-2 . 未來展望 54 附件A . 不同Acetic acid添加量的外觀及尺寸分佈 55 附件B . 不同Chitosan添加量的外觀及尺寸分佈 60 參考文獻 63

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