| 研究生: |
龔柏誠 Kung, Bo-Cheng |
|---|---|
| 論文名稱: |
氧化鋅之MIS二極體的研究 The study of ZnO based MIS(metal-insulator-semiconductor) Diode |
| 指導教授: |
洪茂峰
Houng, Mau-Phon |
| 學位類別: |
碩士 Master |
| 系所名稱: |
電機資訊學院 - 微電子工程研究所 Institute of Microelectronics |
| 論文出版年: | 2006 |
| 畢業學年度: | 94 |
| 語文別: | 中文 |
| 論文頁數: | 104 |
| 中文關鍵詞: | 金屬-絕緣層-半導體 、雙氧水 、氧化鋅 |
| 外文關鍵詞: | hydrogen peroxide, ZnO, MIS |
| 相關次數: | 點閱:89 下載:1 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
氧化鋅是一種寬能隙(3.4eV)半導體,且其在常溫下具有較大的激子束縛能(60meV),在光電產業上提供了另一項選擇。
由於p型氧化鋅較難形成,故我們以金屬-絕緣層-半導體結構取代常見的p-n接面型式的二極體,且本實驗也以較易的方式形成絕緣層。在實驗中我們以Sapphire做為我們的基板,利用射頻磁控濺鍍法成長我們的氧化鋅薄膜,由於氧化鋅薄膜本質上較偏向n型,所以我們利用雙氧水法來使我們的氧化鋅薄膜呈現絕緣性。將試片置於30%的雙氧水溶液中,使其表面與雙氧水反應呈絕緣性,以熱蒸鍍的方式鍍上我們的金電極,使其成為金屬-絕緣層-半導體結構,而未反應的氧化鋅薄膜我們鍍上鋁電極形成歐姆接觸,以HP4156量測其電性。
ZnO is a wide band-gap semiconductor and it has larger Exciton binding energy at room temperature. So, it provides another choice in optoelectronic applications.
Because of the difficulty in making p-type ZnO, we use MIS structure instead of p-n junction structure. We also use easier method for making our insulator layer. We use Sapphire substrate and ZnO thin film was grown by RF Sputter. Then, we immerse our sample in hydrogen peroxide to be an insulator layer. The third step, Gold Schottky contact was grown by thermal evaporation. A MIS structure is complete. Also, we use aluminum as an Ohmic contact. We can get its I-V curve by HP4156.
[1] Azuma Shimizu, Minoru Kanbara, Makoto Hada, and Masanobu Kasuga, “ZnO Green Light Emitting Diode,” Japan. J. Appl. Phys., vol. 17, no 8, pp1435-1436, Feb. 1978.
[2] S. M. Sze, “Physics of Semiconductor Devices”, John Wiley & Sons, 1981.
[3] 李世鴻, “半導體物理及元件”, McGraw-Hill, 2003.
[4] Ya. I. Alivov, D. C. Look, B. M. Ataev, M. V. Chukichev, V. V. Manedov, V.I. Zinenko, Yu. A. Agafonov, and A. N. Pustovit, “Fabrication of ZnO-based metal-insulator-semiconductor diode by ion implantation”, Solid-State Electronics, vol. 48, no 48, pp2343-2346, July 2004.
[5] Y.Chen, F. Jiang, L.Wang, C. Mo, Y. Pu, and W. Fang, “Influence of hydrogen peroxide solution on the properties of ZnO thin films”, J. Cry. Grow., vol 268, pp71-75, March 2004.
[6] Y.Chen, L.Wang, C. Mo, Y. Pu, and W. Fang, and F. Jiang, “Study of structural and luminescent propertiesof high-quality ZnO thin films treatment with hydrogen peroxide solution ”, Mat. Sci. Semi. Pro.,vol 8, pp569-575, Oct. 2005.
[7] H. K. Kim, J. W. Bae, T. K. Kim, K. K. Kim, T. Y. Seong, and I. Adesida, “Inductively coupled plasma reactive ion etching of ZnO using BCl3-based plasmas”, J. Vac. Sci. Technol. B, vol 21, pp1273-1277, Jul/Aug 2003.
[8] J. Zhu, N. W. Emanetoglu, Y. Chen, B. V. Yakshinskiy, and Y. Lu, “Wet-Chemical Etching of (1120) ZnO Films”, J. Ele. Mat., vol 33 pp556-559,Dec. 2003.
[9] S. H. Kim, H. K. Kim, S. W. Jeong, and T. Y. Seong, “Characteristics of Pt Schottky contacts on hydrogen peroxide-treated n-type ZnO(0001) layers ”, Superlattices and Microstructures, vol 39, pp211-217, Janu./April 2006.
[10] G. Yuan, Z. Ye, L. Zhu, J. Huang Q. Qian, B. Zhao, “Gold schottky contacts on n-type ZnO thin films with an Al/Si(100) substrates”, J. Cry. Grow., vol 268, pp169-173, March 2004.
[11] H. K. Kim, K. K. Kim, S. J. Park, T. Y. Seong, and I. Adesida, “Formation of low resistance nonalloyed Al/Pt ohmic contacts on n-type ZnO epitaxial layer”, J. Appl. Phy., vol 94, pp4225-4227, Sep. 2003.
[12] D. K. Schroder, “Semiconductor Material And Device Characterization”, John Wiley & Sons, 1998.
[13] 許義忠,“氮化鎵材料的蝕刻以及金屬接觸之研究”成功大學光電工程與科學研究所碩士論文, 2004.
[14] 陳漢珍,“可積體化表面聲波帶拒濾波器之研製”成功大學電機工程學系微電子所碩士論文, 2002.
[15] 莊達人, “VLSI製造技術”,高立圖書, 2003.
[16] 李建宜,“以溼式蝕刻研製微機電微波濾波器”成功大學電機工程學系微電子所碩士論文, 2005.
[17] 汪建民, “材料分析”, 中國材料科學學會, 2001.
[18] 許樹恩,吳泰伯, “X光繞射原理與材料結構分析”, 中國材料科學學會, 1986.
[19] H. W. Kim, and N. H. Kim, “Influence of the substrate on the structural properties of sputter-deposited ZnO films”, Phys. Stat. Sol. (a), vol 201, pp235-238, Dec. 2003.
[20] G. Fang, D. Li, and B. L. Yao, “Fabrication and vacuum annealing of transparent conductive AZO thin films prepared by DC magnetron sputtering”, Vacuum, vol 68, pp363-372, June 2002.
[21] Donald A. Neamen, “Semiconductor Physics and Devices”, McGraw-Hill, 2003.
[22] K. K. Kim, H. Tampo, J. O. Song, T. Y. Seong, S. J. Park, J. M. Lee, S. W. Kim, S. Fujita, and S. Niki “Effect of rapid thermal annealing on Al doped n-ZnO films grown by RF-magnetron sputtering”, Jap. J. Appl. Phy. , vol 44, pp4776-4779, July 2005.
[23] H. K. Kim, T. Y. Seong, K. K. Kim, S. J. Park, Y. S. Yoon, and I. Adesida “Mechanism of nonalloyed Al ohmic contacts to n-type ZnO:Al epitaxial layer”, Jap. J. Appl. Phy. , vol 43, pp976-979, March 2004.
[24] John F. Moulder, Jill Chastain, Roger C. King, “Handbook of x-ray photoelectron spectroscopy :a reference book of standard spectra for identification and interpretation of XPS data”, Physical Electronics, 1995.