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研究生: 龔柏誠
Kung, Bo-Cheng
論文名稱: 氧化鋅之MIS二極體的研究
The study of ZnO based MIS(metal-insulator-semiconductor) Diode
指導教授: 洪茂峰
Houng, Mau-Phon
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 微電子工程研究所
Institute of Microelectronics
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 104
中文關鍵詞: 金屬-絕緣層-半導體雙氧水氧化鋅
外文關鍵詞: hydrogen peroxide, ZnO, MIS
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  • 氧化鋅是一種寬能隙(3.4eV)半導體,且其在常溫下具有較大的激子束縛能(60meV),在光電產業上提供了另一項選擇。
    由於p型氧化鋅較難形成,故我們以金屬-絕緣層-半導體結構取代常見的p-n接面型式的二極體,且本實驗也以較易的方式形成絕緣層。在實驗中我們以Sapphire做為我們的基板,利用射頻磁控濺鍍法成長我們的氧化鋅薄膜,由於氧化鋅薄膜本質上較偏向n型,所以我們利用雙氧水法來使我們的氧化鋅薄膜呈現絕緣性。將試片置於30%的雙氧水溶液中,使其表面與雙氧水反應呈絕緣性,以熱蒸鍍的方式鍍上我們的金電極,使其成為金屬-絕緣層-半導體結構,而未反應的氧化鋅薄膜我們鍍上鋁電極形成歐姆接觸,以HP4156量測其電性。

    ZnO is a wide band-gap semiconductor and it has larger Exciton binding energy at room temperature. So, it provides another choice in optoelectronic applications.
    Because of the difficulty in making p-type ZnO, we use MIS structure instead of p-n junction structure. We also use easier method for making our insulator layer. We use Sapphire substrate and ZnO thin film was grown by RF Sputter. Then, we immerse our sample in hydrogen peroxide to be an insulator layer. The third step, Gold Schottky contact was grown by thermal evaporation. A MIS structure is complete. Also, we use aluminum as an Ohmic contact. We can get its I-V curve by HP4156.

    第一章 緒論-----------------------------------------------------------------------1 1-1 研究背景----------------------------------------------------------------1 1-2 研究動機----------------------------------------------------------------2 1-3 論文架構----------------------------------------------------------------3 第二章 MIS二極體原理--------------------------------------------------------5 2-1理想MIS二極體的簡介------------------------------------------------5 2-2理想MIS電容------------------------------------------------------------7 2-3實際情況的 MIS電容--------------------------------------------------9 2-4外來影響MIS二極體的因素-----------------------------------------13 2-5 MIS二極體的傳導現象-----------------------------------------------15 2-6 MIS穿隧二極體--------------------------------------------------------17 第三章 實驗製程相關理論---------------------------------------------------34 3-1雙氧水的機制----------------------------------------------------------34 3-2溼式蝕刻氧化鋅薄膜-------------------------------------------------36 3-3薄膜表面經雙氧水處理及表面保護層對蕭基接觸(Schottky contact)的影響-------------------------------------------------------38 3-4 歐姆接觸---------------------------------------------------------------41 3-4-1鋁與氧化鋅之間的毆姆接觸------------------------------------- 41 3-4-2 比接觸電阻傳輸線量測方法-----------------------------------42 第四章 製程機台的理論及方法---------------------------------------------57 4-1基板選擇與清洗-------------------------------------------------------57 4-2薄膜濺鍍過程---------------------------------------------------------59 4-3微影製程----------------------------------------------------------------61 4-4蝕刻製程---------------------------------------------------------------63 4-5 蒸鍍製程---------------------------------------------------------------65 4-6 舉離(Lift-off)------------------------------------------------------66 4-7 快速熱回火(RTA)----------------------------------------------------66 4-8 浸泡雙氧水及蒸鍍金(Au)------------------------------------------68 4-9 元件的量測------------------------------------------------------------69 第五章 結果與討論------------------------------------------------------------75 5-1濺鍍機厚度參數-------------------------------------------------------75 5-2 ZnO的XRD(X-ray diffractometer)量測----------------------76 5-3 浸泡雙氧水前後的XPS量測---------------------------------------77 5-4 薄膜的TLM量測-------------------------------------------------------78 5-5 元件的I-V量測-------------------------------------------------------80 第六章 結論與未來工作------------------------------------------------------98 參考文獻------------------------------------------------------------------------101

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