簡易檢索 / 詳目顯示

研究生: 張智偉
Chang, Chih-Wei
論文名稱: 燃燒法合成氮化鋁粉體之新製程開發
Combustion Synthesis of Aluminum Nitride Powder:New Process Development
指導教授: 鍾賢龍
Chung, Shyan-Lung
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2003
畢業學年度: 91
語文別: 中文
論文頁數: 110
中文關鍵詞: 燃燒合成法氮化鋁
外文關鍵詞: combustion synthesis, aluminum nitride
相關次數: 點閱:66下載:3
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 本論文研究是以燃燒合成法進行氮化鋁粉体新製程開發。主要探討可分為兩部分:(1)反應錠製備方式:係以鋁箔與石墨坩堝所作成之容器盛裝反應物,將其置入氮氣壓力約1~3 atm 的不鑄鋼反應器中,於頂部以900 ~1000 瓦的功率加熱,促使燃燒反應的發生

    A new combustion synthesis process was developed for the production of AlN powder. This study includes two part: (1) the method for holding the reactant powders: Reactants were poured into a porous containers made by aluminum foil and graphite crucibles. The container was then placed in a stainless reactor filled with nitrogen pressure around
    1~3 atm. A combustion synthesis reaction was ignited by heating the top surface and the heating power was about 900~1000W. Especially, a nitrogen gas was reinforced to flow through the reactant powders from the bottom of the container to enhance the combustion reaction.

    中文摘要.........................Ⅰ 英文摘要.........................Ⅱ 目錄...........................Ⅲ 表目錄..........................Ⅵ 圖目錄.......................... VII 符號........................... X 第一章緒論.......................1 第二章原理與研究動機..................5 2-1 氮化鋁物理性質.................5 2-2 燃燒合成法簡介.................8 2-3 燃燒反應熱力學.................12 2-4 燃燒反應動力學.................16 2-5 燃燒合成氮化物.................17 2-5-1 熱力學限制..................17 2-5-2 動力學影響..................20 2-6 研究動機................... 25 第三章實驗裝置與藥品..................27 3-1 實驗反應器裝置.................27 3-2 其他設備....................28 3-3 實驗藥品....................29 第四章實驗方法.....................31 4-1 反應錠製備...................31 4-2 氮化鋁燃燒合成反應...............31 4-3 氫氣收集與量測.................32 4-3-1 實驗目的..................32 4-3-2 實驗步驟..................32 4-3-3 產物轉化率之計算..............33 4-4 產物處理與分析.................33 第五章結果與討論....................36 第六章結論.......................102 參考文獻.........................104

    1. 汪建民,陶瓷技術手冊Ceramic technology handbook(1994).
    2. 吳朗,電子陶瓷-入門,p1-2,(1992).
    3. Sander,H.K.”High-tech Ceramics”,C&E News,July 9,(1984).
    4. Bowen,H.K.”Basic Reseach Needs on High Temperature Cerics for Energy Application”,Material Science and Engineering 44,1,(1980).
    5. Takanori Watari”Shape of AIN powders prepared by Vapor Phase Reaction of AlCl3.NH3-N2”,日本窯業協會學術論文誌,97 [8], 864,(1989).
    6. Crider,J.F.”Self-propagating High Temperature Synthesis-A Soviet Method for producing Ceramic Materials”, Ceram. Eng.Sci.Proc.,3[9-10]:519,(1982).
    7. S.Kumar,Key Engineering Materials,Vol 56-57,p183-188, (1991).
    8. A.G.Merzhanov,”Self-Propagating High Temperature Synthesis: Twenty Years of Search and Findings”,In Combustion and Plasma Synthesis of High-Temperature Materials,edited by Z.A.Munir and J.B.Holt,VCH,New York,USA,(1990),pp.1-53.
    9. Z.A.Munir,”Synthesis of High Temperature Materials by Self-Propagating Combustion Methods”, Ceram. Bull.,67 [2], (1988),pp.342-349.
    10. Y. Miyamoto, T. Nakamoto, M. Koizumi, and O. Yamado, “Ceramic-to-Metal welding by a pressurized Combustion Reaction.” J. Mater. Res., 1, 7-9(1986)
    11. J. Subrahmanyam, M. Vijayakumar,”Review:Self-propagating high-temperature synthesis.” J. Mater. Sci., 27, 6249-6273(1992).
    12. B.I.Khachin and A.G.Merzhanov,”Theory of Termal Propa-gating of a Chemical Reaction Front”, Comb. Explos. Shock Wave,2[3],(1962),pp.22-27.
    13. A.G.Strunina,T.M.Martemyanova,V.V.Barzykin and V. I. Ermakov,”Ignition of Gasless systems by a Combustion Wave”,ibid,10,(1974),pp.449-455.
    14. B.V.Novozhilov,”Burning Velocity of Propagating Front with Exothermic Reaction in Condensed Phase”,Dokl.Akad.Nauk SSSR,141,(1961),pp.151-153.
    15. A.G.Merzhanov,”The Theory of Stable Homogeneous Combustion of Condensed Substances”, Combust. Flame, 13, (1969), pp.143-156.
    16. Z.A.Munri and J.B,Holt,”The Combustion Synthesis of Refractory Nitrides”,J.Mater.Sci.,22,(1987),pp.710-714.
    17. J.Karpinski and S.Porowski,”High Pressure Thermodynamics of GaN”,J.Crystal Growth,66,(1984),pp.11-20.
    18. (a)李威昌,”燃燒法合成高性能材料:製程開發與反應機構探討”,
    成功大學博士論文84年畢業。
    (b)W.C.Lee,C.L.Tu,and S.L. Chung,J.Mater.Res.,10(3),
    pp.774, (1995).
    (c)中華民國專利第71873號、美國第5460794號.
    (d)中華民國專利第67194號、美國第5453407號.
    19. A.S.Mukasyan,V.M.MARTYNENKO,a.g.Merzhanov,I.P.Borvin-skaya,and M.Y.Bilinov,”The Mechanism and Laws of the Combustion of Silicon in Nitrogen”,Combust.Explos.Shock Wave,22,(1986),pp.43-49.
    20. L.M.Sheppard,Advanced Materials&Processes,2,p25,(1986).
    21. J.B.Holt,Industrial Research & Development,p89- 91, Apri.,(1983).
    22. J.Bermudo,M.I.Osemdi,” Study of AlN and Si3N4 powders synthesized by SHS reactions” ,ceram. inter. ,25(1999) p607-612.
    23. H.C.YI and J.J.MOORE, ”Review Self-propagating high-temperature (combustion) Synthesis (SHS) of powder-compacted materials” , J. Mater. Sci., 25(1990) p1159-1168.
    24. G.Selvaduray and L. Sheet “Aluminium nitride : review of synthesis method”, Mater. Sci. and Tech. June 1993 Vol. 9, p463-473.
    25. J. NG GUOJIAN, ZHUANG HANRUI, ZHANG JIONG, “Morphologies and growth mechanisms of aluminum nitride whiskers by SHS method – part I”, J. Mater. Sci. 35(2000) p.57-63.

    29. (a)翁彰嶽,”燃燒法合成氮化鋁粉體與鬚晶”,成功大學碩士論文
    82年畢業。
    (b)W.C.Lee,C.L.Tu,C.Y.Weng,and S. L. Chung, J. Mater. Res., 10(3),pp.774,(1995).
    30. 陳泰源,”燃燒法合成氮化鋁粉體及產物特性研究”,成功大學碩士論文85年畢業。
    31. 余文良,”燃燒合成氮化鋁粉體製程開發”,成功大學碩士論文86年畢業。
    32. 歐名洲,” 氮化鋁粉體之燃燒合成反應機構探討”,成功大學碩士論文87年畢業。
    33. 林政曉,” 燃燒合成氮化鋁粉體新方法與量產技術開發”,成功大學碩士論文88年畢業。
    34. 劉敬遠,“燃燒合成氮化鋁製程新方法”,成功大學碩士論文89年畢業。
    35. 陳政權,“燃燒合成氮化鋁反應機構探討”成功大學碩士論文90年畢業。
    36. 林俊男,“燃燒法合成氮化鋁之製程開發”,成功大學博士論文90年畢業。
    37. 柳水金,“燃燒法合成氮化鋁粉體之新方法”成功大學碩士論文91年畢業。

    下載圖示 校內:2005-06-24公開
    校外:2005-06-24公開
    QR CODE