| 研究生: |
張智偉 Chang, Chih-Wei |
|---|---|
| 論文名稱: |
燃燒法合成氮化鋁粉體之新製程開發 Combustion Synthesis of Aluminum Nitride Powder:New Process Development |
| 指導教授: |
鍾賢龍
Chung, Shyan-Lung |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 化學工程學系 Department of Chemical Engineering |
| 論文出版年: | 2003 |
| 畢業學年度: | 91 |
| 語文別: | 中文 |
| 論文頁數: | 110 |
| 中文關鍵詞: | 燃燒合成法 、氮化鋁 |
| 外文關鍵詞: | combustion synthesis, aluminum nitride |
| 相關次數: | 點閱:66 下載:3 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本論文研究是以燃燒合成法進行氮化鋁粉体新製程開發。主要探討可分為兩部分:(1)反應錠製備方式:係以鋁箔與石墨坩堝所作成之容器盛裝反應物,將其置入氮氣壓力約1~3 atm 的不鑄鋼反應器中,於頂部以900 ~1000 瓦的功率加熱,促使燃燒反應的發生
A new combustion synthesis process was developed for the production of AlN powder. This study includes two part: (1) the method for holding the reactant powders: Reactants were poured into a porous containers made by aluminum foil and graphite crucibles. The container was then placed in a stainless reactor filled with nitrogen pressure around
1~3 atm. A combustion synthesis reaction was ignited by heating the top surface and the heating power was about 900~1000W. Especially, a nitrogen gas was reinforced to flow through the reactant powders from the bottom of the container to enhance the combustion reaction.
1. 汪建民,陶瓷技術手冊Ceramic technology handbook(1994).
2. 吳朗,電子陶瓷-入門,p1-2,(1992).
3. Sander,H.K.”High-tech Ceramics”,C&E News,July 9,(1984).
4. Bowen,H.K.”Basic Reseach Needs on High Temperature Cerics for Energy Application”,Material Science and Engineering 44,1,(1980).
5. Takanori Watari”Shape of AIN powders prepared by Vapor Phase Reaction of AlCl3.NH3-N2”,日本窯業協會學術論文誌,97 [8], 864,(1989).
6. Crider,J.F.”Self-propagating High Temperature Synthesis-A Soviet Method for producing Ceramic Materials”, Ceram. Eng.Sci.Proc.,3[9-10]:519,(1982).
7. S.Kumar,Key Engineering Materials,Vol 56-57,p183-188, (1991).
8. A.G.Merzhanov,”Self-Propagating High Temperature Synthesis: Twenty Years of Search and Findings”,In Combustion and Plasma Synthesis of High-Temperature Materials,edited by Z.A.Munir and J.B.Holt,VCH,New York,USA,(1990),pp.1-53.
9. Z.A.Munir,”Synthesis of High Temperature Materials by Self-Propagating Combustion Methods”, Ceram. Bull.,67 [2], (1988),pp.342-349.
10. Y. Miyamoto, T. Nakamoto, M. Koizumi, and O. Yamado, “Ceramic-to-Metal welding by a pressurized Combustion Reaction.” J. Mater. Res., 1, 7-9(1986)
11. J. Subrahmanyam, M. Vijayakumar,”Review:Self-propagating high-temperature synthesis.” J. Mater. Sci., 27, 6249-6273(1992).
12. B.I.Khachin and A.G.Merzhanov,”Theory of Termal Propa-gating of a Chemical Reaction Front”, Comb. Explos. Shock Wave,2[3],(1962),pp.22-27.
13. A.G.Strunina,T.M.Martemyanova,V.V.Barzykin and V. I. Ermakov,”Ignition of Gasless systems by a Combustion Wave”,ibid,10,(1974),pp.449-455.
14. B.V.Novozhilov,”Burning Velocity of Propagating Front with Exothermic Reaction in Condensed Phase”,Dokl.Akad.Nauk SSSR,141,(1961),pp.151-153.
15. A.G.Merzhanov,”The Theory of Stable Homogeneous Combustion of Condensed Substances”, Combust. Flame, 13, (1969), pp.143-156.
16. Z.A.Munri and J.B,Holt,”The Combustion Synthesis of Refractory Nitrides”,J.Mater.Sci.,22,(1987),pp.710-714.
17. J.Karpinski and S.Porowski,”High Pressure Thermodynamics of GaN”,J.Crystal Growth,66,(1984),pp.11-20.
18. (a)李威昌,”燃燒法合成高性能材料:製程開發與反應機構探討”,
成功大學博士論文84年畢業。
(b)W.C.Lee,C.L.Tu,and S.L. Chung,J.Mater.Res.,10(3),
pp.774, (1995).
(c)中華民國專利第71873號、美國第5460794號.
(d)中華民國專利第67194號、美國第5453407號.
19. A.S.Mukasyan,V.M.MARTYNENKO,a.g.Merzhanov,I.P.Borvin-skaya,and M.Y.Bilinov,”The Mechanism and Laws of the Combustion of Silicon in Nitrogen”,Combust.Explos.Shock Wave,22,(1986),pp.43-49.
20. L.M.Sheppard,Advanced Materials&Processes,2,p25,(1986).
21. J.B.Holt,Industrial Research & Development,p89- 91, Apri.,(1983).
22. J.Bermudo,M.I.Osemdi,” Study of AlN and Si3N4 powders synthesized by SHS reactions” ,ceram. inter. ,25(1999) p607-612.
23. H.C.YI and J.J.MOORE, ”Review Self-propagating high-temperature (combustion) Synthesis (SHS) of powder-compacted materials” , J. Mater. Sci., 25(1990) p1159-1168.
24. G.Selvaduray and L. Sheet “Aluminium nitride : review of synthesis method”, Mater. Sci. and Tech. June 1993 Vol. 9, p463-473.
25. J. NG GUOJIAN, ZHUANG HANRUI, ZHANG JIONG, “Morphologies and growth mechanisms of aluminum nitride whiskers by SHS method – part I”, J. Mater. Sci. 35(2000) p.57-63.
29. (a)翁彰嶽,”燃燒法合成氮化鋁粉體與鬚晶”,成功大學碩士論文
82年畢業。
(b)W.C.Lee,C.L.Tu,C.Y.Weng,and S. L. Chung, J. Mater. Res., 10(3),pp.774,(1995).
30. 陳泰源,”燃燒法合成氮化鋁粉體及產物特性研究”,成功大學碩士論文85年畢業。
31. 余文良,”燃燒合成氮化鋁粉體製程開發”,成功大學碩士論文86年畢業。
32. 歐名洲,” 氮化鋁粉體之燃燒合成反應機構探討”,成功大學碩士論文87年畢業。
33. 林政曉,” 燃燒合成氮化鋁粉體新方法與量產技術開發”,成功大學碩士論文88年畢業。
34. 劉敬遠,“燃燒合成氮化鋁製程新方法”,成功大學碩士論文89年畢業。
35. 陳政權,“燃燒合成氮化鋁反應機構探討”成功大學碩士論文90年畢業。
36. 林俊男,“燃燒法合成氮化鋁之製程開發”,成功大學博士論文90年畢業。
37. 柳水金,“燃燒法合成氮化鋁粉體之新方法”成功大學碩士論文91年畢業。