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研究生: 李盈儒
Li, Ing-Ju
論文名稱: 9-取代-3-(5-芳香基-[1,3,4] oxadiazole -2-基)-9氫-carbazole之合成及發光性質研究
Studies on the Synthesis and Light-Emitting Properties of 9-Substituted-3-(5-aryl-[1,3,4]oxadiazol-2-yl)-9H-carbazole
指導教授: 葉茂榮
Yeh, Mou-Yung
學位類別: 碩士
Master
系所名稱: 理學院 - 化學系
Department of Chemistry
論文出版年: 2003
畢業學年度: 91
語文別: 中文
論文頁數: 110
中文關鍵詞: �Q二�t環�w�t
外文關鍵詞: oxadiazole, carbazole
相關次數: 點閱:158下載:2
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  • 本論文係利用�w�t(carbazole)為原料,以KMnO4當環化試劑製備發光小分子材料,並經由NMR、EA、IR、DSC、TGA、UV-VIS、CV、PL光譜數據及EL測試,以探討含�w�t系列以及�w�t含�G�H化合物之結構、物性及光電性質影響。
    在熱穩定性質方面,所合成化合物均具有良好的的熱裂解溫度(Td>306℃)。在玻璃轉化溫度(glass transition temperature,Tg)方面,化合物有Tg點,而且Tg點低,屬於不理想的。
    由PL結果中,發現取代基的改變,歸納�`�t化合物氮上取代基為長碳鏈有影響,而氮上取代基為�`基沒有影響放光的波長。
    元件製作方面,以真空蒸鍍的方式成膜而製成元件。測試時,由於發光時間過短,無法得到EL圖譜為本論文之遺憾。歸納原因,由於電洞傳輸速度比電子傳輸速度快太多。因此加入一材質使電洞傳輸速度降低,或著改變元件設計。

    In this thesis the luminescent organic material was synthesized using carbazole as a starting material and KMnO4 as a cyclization reagent. The structure, physical and electroluminiecent properties for the obtained products including carbazole series and their indole derivatives were studied by the analysis of NMR elemental analysis IR, DSC,TGA,UV-VIS,CV,PL spectrum and EL test.
    For the thermal stability , all synthesized compounds had good thermal decomposition temperatures ,but low glass transition temperatures.
    The result for PL spectrum analysis indicated that substituted groups for the compounds with a long chain on N position effect the PL spectrum but with benzyl group on N position not.
    The EL device was fabricated by depositing as a film in vacumn and tested to emit too instantly to gain the EL spectrum . This was attributed to the larger velocity for hole-transport than electron-transport.
    This can be modified by adding the material which can lower the velocity of hole-transport or enhancing the thickness of the deposited film for emitting layer.

    中文摘要 英文摘要 謝誌 目錄 第一章、有機發光二極體的介紹 1-1、簡介 9 1-2、元件介紹 11 1-3、材料特性的需求 16 1-4、元件基本結構 18 1-5、未來展望 26 參考文獻 28 第二章、含�w�t化合物的合成 2-1、合成動機 30 2-2、實驗方法 33 2-3、實驗部份 44 第三章、9-取代-3-(5-芳香基-[1,3,4] �Q二�t環-2-基)-9氫-�w�t之發光性質研究 3-1、實驗儀器與裝置 67 3-2、以�w�t化合物為主體含1,3,4-�Q二�t環的光學研究 70 3-3、熱穩定性 81 3-4、電化學分析 84 3-5、元件測試 92 第四章、結論 95 第五章、參考文獻 98 附錄、各化合物之UV、PL、CV圖譜 100

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