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研究生: 黃雅鈴
Huang, Ya-Ling
論文名稱: 類紙式膽固醇液晶顯示器
The paper-like cholesteric liquid crystal display
指導教授: 傅永貴
Fuh, Ying-Guey Andy
學位類別: 碩士
Master
系所名稱: 理學院 - 物理學系
Department of Physics
論文出版年: 2005
畢業學年度: 93
語文別: 中文
論文頁數: 64
中文關鍵詞: 類紙式顯示器膽固醇液晶
外文關鍵詞: paper-like display, cholesteric liquid crystal
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  •   本論文主要是利用光聚合引致相分離方法製作可撓曲黑白膽固醇液晶顯示器。我們以垂直不摩擦的表面配向,搭配相分離產生的分散高分子枝條,成功地製成多重區域的膽固醇平面結構。且藉著高分子來穩定其結構,使具有雙穩態的特性,進而產生黑白顯示。同時利用相分離產生高分子間隔物,來提高其機械強度,而成為可曲撓式的顯示器材料,使其可隨意曲折成任何形狀,因此很適合作成為電子紙。

      In this work, we developed a novel flexible black and white cholesteric liquid crystal (CLC) display by using photoinitiated polymerization-induced phase separation (PIPS). The process makes the device to contain polymer walls and dispersed polymer between glass (or plastic) substrates. The dispersed polymer provides the multi-domain CLC planar structure. Thus, the orientation of the helical axes of the multi-domain CLCs has a wide distribution, which results the reflection of white light under room light condition. The polymer walls give the mechanical strength that prevents the CLC domains from changing their structure in bending condition. When the mixture is in the focal conic texture, it has a black appearance because the incident light is scattered and absorbed by an absorption layer on the bottom plate. Both the planar and focal conic states are stable at zero field. Therefore, this display could be implemented for use as an electronic paper and other flexible display applications.

    中文摘要 --------------------------------------------- I 英文摘要 --------------------------------------------- Ⅱ 誌謝 --------------------------------------------- Ⅲ 目錄 --------------------------------------------- Ⅳ 圖表索引 --------------------------------------------- Ⅶ 第一章 前言 ----------------------------------------- 01 第二章 簡介 ----------------------------------------- 03 2.1 膽固醇液晶 --------------------------------------- 03 2.2 聚合反應的過程 ----------------------------------- 07 第三章 論文研究目的與方法 --------------------------- 09 3.1 研究目的 ----------------------------------------- 09 3.2 研究方法 ----------------------------------------- 09 第四章 實驗準備 ------------------------------------- 12 4.1 材料種類 ----------------------------------------- 14 4.2 光罩圖案 ----------------------------------------- 14 4.3 曝光機 ------------------------------------------- 14 4.4 實驗樣品的準備 ----------------------------------- 14 4.4.1 玻璃基板樣品的準備 ---------------------------- 14 4.4.2 塑膠基板樣品的準備 ----------------------------- 16 4.5 SEM樣品製備 ------------------------------------- 20 4.6 儀器(Setup)及量測方式 ----------------------------- 20 (a)反射率(reflection)對波長(wavelength)的量測 ------------ 20 (b)黑白膽固醇液晶顯示器對電壓脈衝的反應之量測 ------- 21 第五章 實驗結果與分析 -------------------------------- 23 5.1在玻璃基板上的實驗結果 ----------------------------- 23 5.1.1 最佳化 ----------------------------------------- 27 5.1.1—1 增加multi domain的結構 ---------------------- 27 5.1.1—2 選擇chiral濃度 ----------------------------- 32 5.1.2 視角 ------------------------------------------- 34 5.2 在塑膠基板上的實驗結果 ---------------------------- 36 5.2.1 機械力VS. 顯示品質 ----------------------------- 37 5.2.2 視角 ------------------------------------------- 40 第六章 驅動 ------------------------------------------ 41 6.1 黑白膽固醇液晶顯示元件的光電特性反應 ------------- 41 6.1.1 黑白膽固醇液晶顯示元件對脈衝電壓的反應 --------- 41 6.1.2 頻率(frequency)與脈衝寬度(pulse width)的對於反射率對脈衝電壓的曲線圖之影響 ------------------------------ 43 6.2 驅動方法 ----------------------------------------- 46 6.2.1 一般驅動方法(Conventional drive scheme) ------------ 46 6.2.2 動態驅動方法(dynamic drive scheme) ---------------- 50 6.2.3累積驅動方法(Cumulative drive scheme) -------------- 57 第七章 結論 ------------------------------------------ 60 參考文獻 ---------------------------------------------- 62

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