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研究生: 蔡欽評
Tsai, Chin-ping
論文名稱: Ni離子摻雜與(Ni,Si)離子共同摻雜對CaCu3Ti4O12的介電性質及顯微結構之影響
The effect of Ni doping and (Ni,Si) co-doping on the dielectric properties and microstructure of CaCu3Ti4O12
指導教授: 方滄澤
Fang, Tsang-Tse
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2008
畢業學年度: 96
語文別: 中文
論文頁數: 109
中文關鍵詞: CaCu3Ti4O12介電常數Ni摻雜
外文關鍵詞: dielectric constant, Ni doping, CaCu3Ti4O12
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  • CaCu3Ti4O12是一種具有很高的介電常數及對溫度變化敏感度低(100~400K)的介電材料。本研究的目的在於探討摻雜Ni和共摻雜(Ni, Si)對於CaCu3Ti4O12的介電常數及顯微結構之影響。實驗結果發現摻雜Ni及共摻雜(Ni, Si)的含量愈高,整體的電阻率下降;其介電常數也會降低。但以實驗結果來看,共摻雜(Ni, Si)仍能提升純CaCu3Ti4O12的介電常數,且效果亦較純粹摻雜Ni來得理想。

    CaCu3Ti4O12 is a remarkable dielectric material which exhibits a large dielectric constant and its dielectric constant is weakly sensitive to temperature range 100~400K. The purpose of this research is try to discuss effects to the dielectric constant and microstructure of CaCu3Ti4O12 by Ni doping and (Ni, Si) co-doping. According to the result, if the quantity of Ni doping or (Ni, Si) co-doping increases, the whole resistivity decreases, also the dielectric constant. But actually speaking, (Ni, Si) co-doping still enhances the dielectric constant larger than pure CaCu3Ti4O12, and more effective than Ni doping.

    中英文摘要...............................................I 致謝.....................................................II 目錄.....................................................III 表目錄...................................................V 圖目錄...................................................VII 第一章 序論...............................................1 1-1 前言..................................................1 1-2研究目的...............................................4 第二章 理論基礎與前人研究.................................6 2-1 介電陶瓷概述..........................................6 2-2 基本介電性質..........................................7 2-3 介電陶瓷內的極化機制..................................13 2-4 Maxwell-Wagner model..................................24 2-5 障壁層電容器 (Barrier layer capacitor)................29 2-6 阻抗分析法 (Impedance spectroscopy)...................32 2-7 電模數分析法 (Electric modulus spectroscopy)..........42 2-8 介電陶瓷材料CaCu3Ti4O12的概述.........................47 第三章 實驗步驟及方法.....................................55 3-1 使用藥品..............................................55 3-2 實驗流程..............................................56 3-3 材料特性分析及量測....................................58 第四章 實驗結果與討論.....................................64 4-1 粉末合成之XRD繞射分析.................................64 4-2 SEM顯微結構...........................................66 4-3 TEM顯微結構...........................................71 4-4 相對緻密度測量結果....................................74 4-5 介電性質分析..........................................76 4-6 電性分析..............................................95 第五章 實驗結論..........................................105 參考文獻.................................................106

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