| 研究生: |
謝明蒲 Hsieh, Ming-Pu |
|---|---|
| 論文名稱: |
廢玻璃鹼激發膠結材之吸水性能研究 Water Absorption of Alkali-activated Waste Glass Binders |
| 指導教授: |
黃忠信
Huang, Jong-Shin |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 土木工程學系 Department of Civil Engineering |
| 論文出版年: | 2012 |
| 畢業學年度: | 100 |
| 語文別: | 中文 |
| 論文頁數: | 87 |
| 中文關鍵詞: | 廢玻璃 、鹼激發 、吸水 |
| 外文關鍵詞: | Waste Glass, Alkali-Activated, Water Absorption |
| 相關次數: | 點閱:87 下載:2 |
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本研究提供一廢玻璃之有效再利用方式,使用素玻璃及茶色容器玻璃作為鹼激發膠結材之原料,為求改善其吸水性能,於廢玻璃鹼激發膠結材中加入添加物或改質劑。其中,對吸水性能產生正面影響之添加物及改質劑,皆造成膠結材之強度下降,鈣含量高之添加物則可有效增加膠結材強度,但吸水性能卻相對降低。當飛灰作為添加物時,其受鹼侵蝕時間越短者,越能有效保有吸水介質之特性,若採用偏高嶺土作為添加物時,則需經適量之鹼侵蝕後方能增加其吸水性能。本研究發現添加物取代之最佳配比,乃是以偏高嶺土取代25%素玻璃,於常溫拌合之素玻璃鹼激發膠結材,其抗壓強度可達26.45MPa,且飽和吸水量為自身重量之17%。
此外,本研究結果顯示,改質劑於鹼性環境中無法有效發揮吸水性能,將PEG200添加於無鹼激發茶色玻璃膠結材中,可明顯改善其吸水性能,但抗壓強度亦大幅降低。
An effective way for the reuse of waste pure glass and container glass as raw materials of alkali-activated binders is proposed here. Different types and various amounts of admixtures or modifiers were added in the production of waste glass alkali-activated binders to enhance their water absorption. From experimental results, it is found that the admixture and modifier which make a positive impact on the water absorption of waste glass alkali-activated binders reduce their compressive strengths. The addition of calcium-rich admixtures increases the compressive strength of waste glass alkali-activated binders but decreases their water absorption. When fly ash is used as a raw material and alkali-activated in a short time, the water absorption of alkali-activated waste glass binders can be enhanced. But, when meta-kaolin is used, the water absorption of waste glass alkali-activated binders can be increased only if they are activated by adequate amount of alkali. The best replacement of pure glass by meta-kaolin for waste glass binders alkali-activated at room temperature is 25%, resulting in a compressive strength of 26.45 MPa and a saturated water-absorption of 17%. In addition, experimental results indicate that the effect of modifiers on the water absorption of waste glass alkali-activated binders is insignificant. However, the water absorption of waste glass binders activated without alkalis can be improved significantly when the modifier PEG200 is used.
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