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研究生: 梅立人
Mei, Li-Then
論文名稱: 添加LiF對CaCu3Ti4O12的介電、導電和顯微結構的影響
Effects of LiF addition on dielectric properties, conductivity, and microstructure of CaCu3Ti4O12
指導教授: 方滄澤
Fang, Tsang-Tse
向性一
Hsiang, Hsing-I
學位類別: 碩士
Master
系所名稱: 工學院 - 資源工程學系
Department of Resources Engineering
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 87
中文關鍵詞: 介電常數介電損失
外文關鍵詞: Dielectric Constant, CaCu3Ti4O12, tangent loss
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  • CaCu3Ti4O12具有很高及對溫度變化率低(100-400K)的介電常數,此性質極符合電子元件的實際應用規格如X5R。但其介電損失過大,使其無法完全符合應用規格。本研究為探討CaCu3Ti4O12的高介電來源和添加氟化鋰對CaCu3Ti4O12的影響,希望能找出使產品有較好的性質及可靠度之製程和材料配方。

    CaCu3Ti4O12 which exhibits a large dielectric constant and the dielectric constant is weakly varying in the temperature range 100~400K. This property is conformed to the electronic component’s application specification, for example X5R.But the large tangent loss makes it can not conform to the application specification. This study is to investigate the origin of high permittivity in CaCu3Ti4O12 and the effects of LiF addition to CaCu3Ti4O12. Through these investigations a large resistivity and process in preparing for CaCu3Ti4O12 could be suggested.

    第一章 序論.......................................1 1-1 前言..........................................1 1-2 研究目的......................................1 第二章 理論基礎與前人研究.........................1 2-1 電容器的功用..................................2 2-2 介電性質......................................2 2-2-1 介電基本原理................................2 2-2-2 鬆弛時間....................................3 2-2-3 極化的機制..................................4 2-2-4 Barrier layer capacitor.....................8 2-3 電性分析法....................................9 2-3-1 阻抗分析法..................................9 2-3-2 電模數分析法...............................12 2-4 介電材料CaCu3Ti4O12概述......................13 2-4-1 CaCu3Ti4O12之介電性質概述..................13 2-4-2 CaCu3Ti4O12結構............................14 2-4-3巨大介電的機制..............................14 第三章 實驗步驟與方法............................31 3-1 實驗藥品.....................................31 3-2 實驗流程.....................................31 3-2-1 粉末製備...................................31 3-2-2 試片製備...................................31 3-3 材料特性分析.................................31 3-3-1 X-ray繞射分析..............................31 3-3-2 密度測量...................................32 3-3-3 SEM顯微結構觀察............................32 3-3-4 導電率、介電性質、交流阻抗分析.............32 3-3-5 TEM顯微結構觀察............................33 第四章 實驗結果與討論............................36 4-1 X-ray繞射分析................................36 4-2 密度量測.....................................36 4-3 SEM顯微結構觀察..............................36 4-4 電性分析.....................................37 4-4-1電阻率......................................37 4-4-2介電性質....................................37 4-4-3阻抗分析....................................38 4-5 TEM顯微結構觀察..............................39 第五章 結論......................................85 參考文獻.........................................86

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