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研究生：	黃家瑜 Huang, Jia-Yu
論文名稱：	中孔洞氧化矽及氧化鋁之合成與應用 Synthesis and Application of Mesoporous Silica and Alumina
指導教授：	林弘萍 Lin, Hong-Ping
學位類別：	碩士 Master
系所名稱：	理學院 - 化學系 Department of Chemistry
論文出版年：	2021
畢業學年度：	109
語文別：	中文
論文頁數：	79
中文關鍵詞：	中孔洞氧化矽、氧化鋁孔洞材料、智慧玻璃窗、CsPbBr3鈣鈦礦螢光粉、水溶液中氟離子之移除
外文關鍵詞：	mesoporous silica, porous alumina, fluoride ion removal, liquid crystal, CsPbBr3 perovskite nanocrystals
相關次數：	點閱：121 下載：0
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目錄
第一章、緒論...................................................................................................1
1 中孔洞材料................................................................................................................. 1
1.1 中孔洞氧化矽....................................................................................................... 1
1.2 中孔洞氧化鋁....................................................................................................... 3
2 界面活性劑................................................................................................................. 5
2.1界面活性劑基本性質及種類............................................................................... 5
2.2 微胞的形成........................................................................................................... 6
3 氧化矽源介紹............................................................................................................. 9
3.1 矽酸鈉(Sodium Silicate, S.S) ............................................................................... 9
3.2 四乙氧基矽烷(Tetraethyl Orthosilicate, TEOS) ............................................ 11
4 水熱法簡介............................................................................................................... 13
5 智慧玻璃窗(Smart Window)介紹............................................................................ 15
6 鈣鈦礦螢光粉之介紹27, 28........................................................................................ 18
7 吸附水溶液中氟離子之方法簡介34........................................................................ 19
7.1 吸附動力學......................................................................................................... 19
第二章、合成與鑑定.....................................................................................22
1 化學藥品................................................................................................................... 22
2 中孔洞氧化矽材料合成之步驟............................................................................... 23
2.1 合成長條形中孔洞氧化矽................................................................................. 23
2.2 合成特殊型態之中孔洞氧化矽......................................................................... 24
3 智慧玻璃窗的製作................................................................................................... 25
3.1 中孔洞氧化矽之材料疏水性官能基修飾......................................................... 25
3.2 智慧玻璃窗的製作............................................................................................. 26
4 合成CsPbBr3@SiO2螢光粉之步驟......................................................................... 27
4.1 合成中孔洞氧化矽載體..................................................................................... 27
4.2 合成CsPbBr3@SiO2螢光粉.............................................................................. 28
5吸附氟離子之中孔洞氧化鋁材料合成步驟............................................................ 29
6 儀器鑑定分析........................................................................................................... 30
6.1 穿透式電子顯微鏡(Transmission Electron Microscopy, TEM)........................ 30
6.2 掃描式電子顯微鏡(Scanning Electron Microscopy, SEM) ............................. 30
6.3 熱重分析儀(Thermogravimetry Analysis, TGA).............................................. 31
6.4 氮氣等溫吸附/脫附測量(N2 Adsorption-Desorption Isotherm)....................... 31
6.5 X-射線粉末繞射光譜(Powder X-Ray Diffraction, PXRD).............................. 35
6.6 螢光光譜儀(Fluorescence Spectrophotometer).................................................. 36
6.7 氟離子電極......................................................................................................... 37
第三章、不同型態之中孔洞氧化矽運用於智慧玻璃窗及螢光粉載體....38
1 研究動機................................................................................................................... 38
2 合成長條狀中孔洞氧化矽材料............................................................................... 39
2.1以倒入大量鹼性緩衝溶液方式合成長條型中孔洞氧化矽............................. 39
2.2探討C16TABr/SDS莫耳比對型態之影響........................................................ 42
3 合成多種形態之中孔洞氧化矽材料....................................................................... 43
3.1 探討硬脂酸鈉/C16TAB莫耳比和反應pH值對型態之影響........................... 44
3.2 探討不同反應時間及水熱與否對型態之影響................................................. 49
4 不同構型之中孔洞氧化矽材料應用於智慧玻璃窗............................................... 51
5 中孔洞氧化矽應用於合成CsPbBr3@SiO2 ............................................................. 56
5.1選擇silica gel/MS莫耳比例.............................................................................. 56
5.2 中孔洞氧化矽之孔洞大小對發光強度的影響................................................. 57
5.3 選擇CsBr/PbBr2之比例.................................................................................... 59
5.4 摻雜不同鹵素對螢光粉之放光波長的影響..................................................... 59
第四章、氧化鋁孔洞材料於吸附水中氟離子之應用................................62
III
1 研究動機................................................................................................................... 62
2 不同金屬氧化物孔洞材料對於吸附氟離子之效率............................................... 63
3 藉由調控反應條件來改變活性氧化鋁之晶相....................................................... 63
4 探討不同氧化鋁晶相對氟離子吸附之效率........................................................... 66
5氧化鋁孔洞材料對於吸附氟離子之動力學探討.................................................... 68
6 探討雙金屬造粒對於吸附氟離子之效率............................................................... 71
第五章、總結.....................................................................................74
參考文獻............................................................................................76
                                    

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