| 研究生: |
黃詠華 Vong, Weng-Wa |
|---|---|
| 論文名稱: |
不同鐵氧磁體透水性催化牆降解苯之研究 Degradation of benzene by different types of ferrite in permeable catalytic barriers |
| 指導教授: |
張祖恩
Chang, Juu-En |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 環境工程學系 Department of Environmental Engineering |
| 論文出版年: | 2010 |
| 畢業學年度: | 98 |
| 語文別: | 中文 |
| 論文頁數: | 120 |
| 中文關鍵詞: | 鐵氧磁體 、苯 、降解 、透水性催化牆 |
| 外文關鍵詞: | ferrite, benzene, degradation, permeable catalytic barriers |
| 相關次數: | 點閱:145 下載:1 |
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鐵氧磁體MFe2O4為具化學穩定性之尖晶石結構鐵氧化物,由於鐵氧磁體中同時含有Fe3+ 與 M2+ 離子,使其具有催化H2O2產生氫氧自由基以氧化有機污染物之Fenton-like反應潛勢。本研究探討以電鍍污泥燒成多孔性鐵氧磁體作為透水性催化牆之可行性,研究首先將銅、鎳、鋅與錳等金屬氧化物分別與氧化鐵於不同生料配比、燒結溫度下燒成鐵氧磁體,並測試其進行之Fenton-like反應對苯之去除效率,歸納適合用於Fenton-like反應之鐵氧磁體種類與燒結條件。接續採用上述最適實驗條件以低碳鐵礦泥調質後電鍍污泥添加PVA與高嶺土製備多孔性鐵氧磁體,並用於管柱實驗進行對苯降解之研究。
研究結果顯示Fe3+/M2+ = 2莫耳比、燒結溫度為1000℃所合成之鐵氧磁體,於Fenton-like反應中對苯之去除效果以NiFe2O4最好,其餘依序為ZnFe2O4 > CuFe2O4 > MnFe2O4 > Fe3O4。在管柱實驗中苯/H2O2重量比1/32與330 sec之水力停留時間為操作條件時,NiFe2O4觸媒對苯有顯著之降解效果,可達94.98%。此外經調質之電鍍污泥所燒成之多孔性鐵氧磁體,其降解苯之效率與純物質合成NiFe2O4之處理效率相似,而且高溫鐵氧磁體化過程對電鍍污泥中重金屬亦達穩定化效果,其TCLP試驗Ni之溶出濃度由286 mg/L降為11.7 mg/L。此外,於Fenton-like反應中Ni亦幾乎不溶出。
綜合研究結果,經低碳鐵礦泥調質之電鍍污泥所製成之多孔性鐵氧磁體,其Fenton-like觸媒效果佳且穩定性良好,具有作為透水性催化牆材料之潛力,為一環境友善之再生催化材料。
Ferrite (MFe2O4) is spinel structured iron oxide with high chemical stability. With the presence of Fe3+ and M2+ ions in MFe2O4, it will be regarded as potential catalytic material in generation Fenton-like reaction. During Fenton-like reaction, ferrite will catalyze H2O2 decomposition, forming hydroxyl free radicals with high oxidation capacity towards organic pollutants. In this study, feasibility of porous ferrite synthesis from electroplating sludge (EPS) for permeable catalytic barriers (PCBs) was evaluated.
Investigation of ferrite synthesis using CuO, ZnO, NiO, MnCO3 and Fe2O3 under different Fe/M molar ratio and sintering temperature was carried out. Selections of appropriate type of ferrite with respect to sintering conditions were derived from Fenton-like degradation of benzene using ferrite as catalyst. Porous ferrite synthesized from EPS with BF, polyvinyl alcohol (PVA) and kaolinite addition with appropriate sintering conditions was utilized in column tests for studies on benzene degradation in accordance with experimental conditions summarized.
Results from this research showed NiFe2O4 sintered with Fe3+/M2+ = 2 molar ratio at 1000℃ sintering temperature had highest removal efficiency on Fenton-like benzene degradation. The order of different types of ferrite on benzene degradation was: ZnFe2O4 > CuFe2O4 > MnFe2O4 > Fe3O4. In column tests, significant removal of benzene was observed when reaction parameters were controlled at benzene/H2O2 (w/w) ratio of 1/32 with hydraulic retention time of 330 sec. At relative liquid volume of 120, 94.98% of benzene was degraded using porous NiFe2O4 under such reaction conditions. Porous ferrite sintered from EPS with BF alterations showed similar removal efficiency of benzene compared with NiFe2O4 sintered with chemicals. High temperature ferritization was able to stabilized heavy metals in EPS. From the results of TCLP, leaching concentration of Ni decreased from 286 mg/L to 11.7 mg/L. Moreover, no heavy metals were leached from sintered EPS during Fenton-like reaction.
According to above observations, porous ferrite synthesized from EPS with BF alterations was favourable catalyst with high chemical stability in generating Fenton-like reaction. It was regarded as potential catalytic material used in PCBs with environmental friendly characteristics.
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