摘 要
本研究主要是以自行合成之含二胺類2,7-Bis(4-aminophenoxy) naphthalene(BAN)與含柔曲鍵結的二雙酐類BTDA與ODPA合成含苯氧基之聚醯亞胺。並另以對位或間位和含第三丁基之二胺類合成含苯氧基之聚醯亞胺，作為比較物性差異之對照組。
利用傅立葉紅外線光譜儀(IR)、核磁共振分析儀(NMR)及X-ray繞射分析儀(XRD)鑑定聚醯亞胺的結構；並藉由熱重分析儀(TGA)、微差熱掃描分析儀(DSC)及動態機械分析儀(DMA)測試其熱性質等；與利用萬能拉力機測定其機械性質及接著性。
結果顯示含環之聚醯亞胺呈現無結晶型態，其熱安定性－玻璃轉移溫度和熱裂解溫度（5﹪重量損失），有明顯上升的趨勢。其機械性質和韌性也較對照組來得佳。
關鍵字:聚醯亞胺,苯氧基,第三丁基對苯二酚,奈二酚

Abstract
This thesis is major in phenoxy-containing polyimide that synthesized from aromatic di-acid anhydrides (e.g. BTDA、ODPA) and naphthalene – containing diamine.
These compounds are compared and discussed with those polyimides which synthesized from di-acid anhydrides and various diamides (e.g. para、meta and tert–butyl). All the polymers are subjected to FT-IR、1H-NMR and XRD for the analysis of molecular structure. TGA、DSC、DMA and Instron also have been used to measure their thermal and mechanical properties.
We found that naphthalene–containing polyimides showed an amorphous state. Also it’s degree of thermal stability–like the glass transition temperature and thermal degradation temperature (5% weight loss) were increased. And mechanical strength and toughness were improved.
keyword:polyimide,phenoxy,dihydroxynaphthalene,tert-butylhydroquinone

參 考 文 獻
1. 江選雅，聚醯亞胺的合成及其在LCD上的應用，化工資訊月刊， Vol.13,No.7,43~53(1999)
2. W.M., I.M. Robinson, British Pat. 570858;U.S. Pat. 2710853(1955)
3. M.K.Ghosh, K.L.Mittal, Polyimides, Fundamentals and applications, 1~6,Marcel Dekker,Inc.(1996)
4. 林金雀，聚醯亞胺薄膜全球市場及應用現況，化工資訊月刊，Vol.13,No.7,58~62(1999)
5. 陳立閔，含矽聚醯亞胺之合成研究，國立成功大學化工研究所碩士論文(2000)
6. T. T. Serafini, P. Delvigs and W. B. Alston, PMR-15 Polyimides review and update, NASA TM-82821, Washington D.C.(1982)。
7. 金進興，聚醯亞胺在IC元件之應用，工業材料，No.114, 118~125(1996)
8. 劉怡君，新配向技術，工業材料，No.156, pp.98~106(1999)
9. R.W.Lauver, J.Polym.:Sci.Polym.Chem.,17,2529(1979)
10. H.D.Stenzenberger, Brit.Polym.J.,15,1(1979)
11. 工研院化工所專題調查報告聚醯亞胺樹酯篇(1988)
12. M.I.Bessonov, M.M.Koton, V.V.Kudryavtser and L.A. Laius, ”Polyimide-Thermally stable Polymers”,Consultants Bureau,N.Y.(1987)
13. T.L.St.Clair, progar.D.J.Sci.Adv.Makr. Process Eng.Ser., 24(2),1081(1979)
14. S.Kataoka. Plastic age Meg. 97(1983)
15. M.grundschober, British Pat. 1190718(1978)
16. N.A.Adrova, M.I.Bessonov, L.A.Laius and A.P.Rudakov, Polyimide：A new class of thermally stable polymers(in Russian), Nauka, Leningrad(1968)
17. 吳宏明，聚醯亞胺覆銅膜之製備及其裂化現象之研究，國立成功大學化工研究所碩士論文(1996)
18. M.I.Bessonov, M.M.Koton, V.V.Kudravtsev and L.A.Laius, Polyimides：Thermal stable polymers, Plenum,New York(1987)
19. T.Takekoshi, J.E.Kochanowski, US patent 3,833,546, General Electric Co.(1974)
20. T.Takekoshi, J.E.Kochanowski, US patent 3,905,942, General Electric Co.(1975)
21. W.F.Gresham, M.A.Naylor, US patent 2,731,447(1956)
22. T.T.Serafini, P.Delvigs and G.R.Lightsey, Thermally stable polyimides from solutions of monomeric reactant, NASA Technical Note D-6611(1972)
23. T.T.Serafini, P.Delvigs and W.B.Alston, PMR-15 Polyimides review and update, NASA TM-82821, Washington D.C.(1982)
24. R.A.Meyers, A novel condensation polymerization, Am. Chem. Soc., Polym. Prepr., Vol.10, No.1, 186~192(1969)
25. W.M.Alvino, L.E.Edelman, Polyimides from diisocyanates, dianhydride and tetracarboxylic acids, J. Appl. Polym. Sci., Vol.19, No.11, 2961~2980(1975)
26. G.D.Khune, Preparation and properties of polyimides from diisocyanates, J. Macromol. Sci., Polym. Chem. Ed., Vol.18,No.6,1905-1909(1980)
27. P.R.Young and A.C.Chang, Characterization of a thermally imidized soluble polyimide film, J. Polym.Sci.：Part A, Vol.28,3107~3122(1990).
28. J.Malinge, J.Garapon and B.Sillion, New developments in polybenzhydrolimide resins：Application in the field of heat resistant coatings, adhesives and laminates, British Polym. J., Vol.20,431~439(1988)
29. M.K.Ghosh, K.L.Mittal, Polyimides, Fundamentals and applications, p.18, Marcel Dekker Inc.(1996)
30. Yaw Terng Chern, Chin Min Huang and Shih Chieh Huang, Synthesis and Characterization of new poly(amide-imide)s Containing 4,9’-diamantane moieties in the main chain, Polymer Vol.39, No.13,2929～2934(1998)。
31. 丁孟賢、何天白，聚醯亞胺新型材料，8~10，科學出版社(1998)
32. Walter H. Stockmayer and Fumihike Tanaka, Macromolecules, 27,3943(1994)
33. D.L.Tipton and P. S. Russo, Macromolecules,29,3943(1994)
34. Sung koo Lee, Frank.W.Harris and Chul Joo Lee, Polym. Inter.,30,115(1993)
35. Chin Ping Yang, Sheng Huei Hsiao and Chun Cheng Yang, New Poly(amide-imide) Synthesis XXI. Synthesis and Properties of Aromatic Poly(amide-imide)s Based on 2.6’- Bis (4-trimelli timidophenoxy)naththalene and Aromatic Diamines, Journal of Polymer Science：Part A：Polymer Chemistry, Vol.36,919～927(1998)。
36. 王宗呂、謝達華、何國賢，”聚合物合成與鑑定法”(1995)
37. Huei-Hsiung Wang, Chu-Chi Chang, The Synthesis of Thermostable Polyimide Fiber and It’s Spinning, Chinese Journal of Materials Science, Vol.27, No.2, PP.119-129 (1995)
38. J.R.Fried, Polymer science and technology, 156~158, Prentice-Hall International Inc. (1995)
39. R.A.Dine-Hart, W.W.Wright, Preparation and fabrication of romatic polyimides, J.Appl.Polymer Sci., Vol.11,609~627 (1967)