本實驗是採用CuSO4和Cu(OAc)2分別與有機配體1,2-di(4-pyridyl)ethylene透過界面擴散養晶法的方式，藉由不同的金屬鹽類、金屬鹽類與有機配體莫耳數比和溶劑等條件，合成出有機-無機高分子材料，分別為使用CuSO4金屬鹽類合成出的錯合物1-{[Cu(SO4)(bpe)1.5]·H2O}n 和
錯合物2-[Cu(SO4)(bpe)(H2O)3]n 跟使用Cu(OAc)2金屬鹽類合成出的
錯合物3- [Cu(C2O2H3)2(bpe)0.5]n 和錯合物4-[Cu2(C2O2H3)4(bpe)]n 。錯合物1是二維延伸的網狀結構，其孔洞尺寸約為13.40(7) x 12.85(9) Å2。錯合物2是一維延伸的鏈狀結構，藉由氫鍵和pi-pi作用力將不同條的鏈狀結構連接起來，形成具有菱形孔洞的三維結構，其孔洞尺寸約為24.17(4) x 11.33(18) Å2。錯合物3和錯合物4是一維延伸的鏈狀結構，藉由C-H···pi作用力將不同條的鏈狀結構連接起來，形成二維結構網狀。
之後透過x-ray單晶繞射做結構上的鑑定、元素分析作純度的鑑定、熱重分析測量錯合物的熱穩定度以及紅外線光譜來鑑定錯合物的性質，並去探討錯合物2的陰離子交換應用特性。

In this study﹐we use CuSO4 and Cu(OAc)2﹐respectively﹐and the organic ligand﹐1,2-di(4-pyridyl)ethylene(bpe)﹐through diffusion method to synthesize organic-inorganic polymer materials﹐with the conditions of different metal salts、solvents and molar ratio of metal salts and organic ligands. It was synthesized by using CuSO4 metal salt that complex 1-{[Cu(SO4)(bpe)1.5]·H2O}n and complex 2-[Cu(SO4)(bpe)(H2O)3]n﹐and by using Cu(OAc)2 metal salt that complex 3-[Cu(C2O2H3)2(bpe)0.5]n and complex 4-[Cu2(C2O2H3)4(bpe)]n. Complex 1 is 2-dimensional (2-D) grid﹐and the pore size of complex 1 is ca. 13.40(7) x 12.85(9) Å2. Complex 2 is 1-dimensional (1-D) chain which﹐linking by hydrogen bondings and pi-piinteractions﹐line up in chain s with each chain crossing the chain beneath to form 3-dimensional (3-D) structure having rhombic channels﹐and the pore size of complex 2 is ca. 24.17(4) x 11.33(18) Å2. Complex 3 and complex 4 are 1-dimensional (1-D) chain which﹐linking by C-H···pi interactions﹐line up in chains with each chain crossing the chain beneath to form 2-dimensional (2-D) grid.
Then﹐those complexes are characterized by single crystal x-ray diffractometer、elemental analyzer、thermogravimetric analyzer and FTIR spectra. Finally﹐we research application property of anion-exchange of complex 2.

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