| 研究生: |
彭鈺博 Peng, Yu-Po |
|---|---|
| 論文名稱: |
Ti-7.5Mo合金的熱處理效應及於牙科鑄造的應用 Heat treatment effect and dental casting application of Ti-7.5Mo alloy |
| 指導教授: |
陳瑾惠
Chern Lin, Jiin-Huey 朱建平 Ju, Chien-Ping |
| 學位類別: |
博士 Doctor |
| 系所名稱: |
工學院 - 材料科學及工程學系 Department of Materials Science and Engineering |
| 論文出版年: | 2020 |
| 畢業學年度: | 108 |
| 語文別: | 中文 |
| 論文頁數: | 126 |
| 中文關鍵詞: | Ti-Mo合金 、牙科鑄造 、雙相區內固溶處理 、機械性質 |
| 外文關鍵詞: | Ti-Mo alloy, α/β dual-phase, dental casting, mechanical properties |
| 相關次數: | 點閱:59 下載:0 |
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本研究分為兩個部分,第一部分為探討Ti-7.5Mo合金與純鈦(Grade 2)運用於牙科中的活動式假牙鑄造的差異性,以釐清Ti-7.5Mo合金作為牙科鑄造合金之潛力。第二部分,則研究不同固溶處理溫度以及不同含量的Ti-Mo二元合金,經熱處理後的機械性質與微結構探討。
首先,Ti-7.5Mo合金與純鈦進行所有包含在牙科鑄造合金規範的測試並探討Ti-7.5Mo合金與純鈦在實際應用上的差距。可發現到Ti-7.5Mo合金除了在雜質元素、密度、熱膨脹率以及固態液態轉換溫度皆無太大的差別。經X光相鑑定結果顯示,Ti-7.5Mo合金多由α”相所組成以極少量的β相,而純鈦則由α/α’相所組成。而金相結果顯示純鈦多為板狀結構,Ti-7.5Mo合金則為針狀α”相以及等軸β相所組成。在實際應用的方面,Ti-7.5Mo合金在網狀鑄造試驗較純鈦高出許多,且由穿透式X光可發現純鈦所製成的活動式假牙有缺陷以及空孔的存在。拉伸測試顯示Ti-7.5Mo合金相較於純鈦更佳的機械性質(Ti-7.5Mo合金:拉伸強度806MPa、拉伸率42%以及70GPa的彈性模數;純鈦:拉伸強度571MPa、拉伸率22%以及113GPa的彈性模數),而且彎曲測試也顯示Ti-7.5Mo合金由於較純鈦來比有更高的彎曲強度以及更低的彈性模數,使得Ti-7.5Mo合金有更好的彈性回復角(31.5°比上2.8°),因此可判定Ti-7.5Mo合金較純鈦相比具有更佳的性質,更適合應用於活動式假牙。
第二部分,則探討不同比例的Ti-xMo合金於雙相區內固溶處理後的微結構以及機械性質表現。X光繞射結果顯示,隨著固溶溫度以及Mo含量的上升,β相的峰值也隨之上升,而α/α’相的峰值則隨之下降。Ti-9.5Mo於800℃進行固溶處理後,主要皆由β相所組成,而α”相則於Ti-7.5Mo進行800℃固溶處理後可被觀察到。而Ti-1.5Mo不論在何種溫度之下,大部分板狀的α相結構組成。而機械性質的方面,當固溶溫度為700℃時,降伏強度及最大拉伸強度皆隨Mo含量的上升而上升,最高的拉伸強度則發生於Ti-7.5以及9.5Mo。當固溶溫度達到750℃時,Ti-5.5Mo合金的機械強度有明顯的提升,且其伸長率並未下降,而Mo含量持續上升會導致伸長率隨之增加,但機械強度並無明顯改變。最後,當固溶溫度達到800℃時Ti-3.5、5.5以及7.5Mo合金具有與Ti-1.5以及9.5Mo相對低的機械強度。然而,機械性質的變化由於影響因素眾多,還未有一完善的解釋,但,經由於雙相區內固溶處理後的Ti-Mo合金仍表現出不錯的機械性質。
In this study, first of all a head-to-head comparison was made between an in-house-developed Ti-7.5Mo alloy and commonly-used grade-2 commercially pure titanium (CP-Ti) for dental casting applications. Both metals had undergone a series of tests, and Ti-7.5Mo alloy shows better castability and mechanical properties. Second, investigation of the effect of heat treatment within the alpha (α)/beta (β) dual-phase field on the structure and tensile properties of Ti-(1.5-9.5) mass% Mo alloys. When heat-treated at 700℃, the yield strength (YS) and ultimate tensile strength (UTS) increased while the elongation generally decreased with Mo content. The highest YS and UTS were found in Ti-7.5Mo and Ti-9.5Mo. When heat-treated at 750℃, the strength of Ti-5.5Mo was improved without reducing elongation. With Mo concentration increased to 7.5% or higher, the elongation further increased while the strength maintained a similar level. When treated at 800℃, the YS of Ti-3.5Mo, Ti-5.5Mo and Ti-7.5Mo maintained a lower level than Ti-1.5Mo and Ti-9.5Mo.
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校內:2025-02-19公開