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研究生: 陳曉鳴
Chen, Sheau-Ming
論文名稱: 以蒙脫土吸附磷酸鹽之研究
A study on phosphate adsorption by montmorillonite as a sorbent
指導教授: 申永輝
Shen, Yun-Hwei
學位類別: 博士
Doctor
系所名稱: 工學院 - 資源工程學系
Department of Resources Engineering
論文出版年: 2011
畢業學年度: 99
語文別: 中文
論文頁數: 60
中文關鍵詞: 膨土(bentonite)磷酸鹽UV/TiO2吸附效率時間效應
外文關鍵詞: Bentonite, Phosphate, UV/TiO2, Adsorption efficiency, Time effect
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  • 本研究目的以蒙脫土(膨土)進行吸附人工調製的含磷酸鹽廢水。操作參數共有污染標的物、吸附劑、光觸媒等的劑量濃度,攪拌轉速,反應溫度,pH酸鹼度,反應時間;另外一組實驗是由蒙脫土搭配光觸媒UV/TiO2。從實驗結果得知,吸附效率大致隨著操作參數的正向增加同時也跟著提昇。

    實驗室級的最佳操作系統針對1000 μg P/L含磷廢水,使用蒙脫土與二氧化鈦濃度各8 ppm的組合,攪拌速率250 rpm,溫度330 T(K),在pH=4下操作1 hr時間,去磷效率高達96%。而時間效應方面,操作參數的檢選要能貼近污染處理系統,我們單用蒙脫土濃度12 ppm當吸附劑,攪拌選用較慢速的150 rpm,溫度選用接近室溫的300 T(K),pH=4。時間在180 min為限的操作下,去磷效率仍可達到91%。

    The purpose for this study is to adsorb the simulated phosphate wastewater by using montmorillonite (bentonite). The operational parameters are montmorillonite, TiO2, agitation, temperature, pH, and reaction time. From the laboratory investigation, the efficiencies are different according to operating levels. We selected better parameters for laboratory scale of montmorillonite with UV/TiO2 combination system to remove phosphate. To a 1000 μg P/L wastewater, the efficiency is almost 96% in an hour reaction under the condition of 8 ppm bentonite and TiO2 each, with agitation 250 rpm, at 330 T(K) temperature and pH=4. The time effect according the parameters is more approach to a real condition. Therefore we took 12 ppm bentonite sorbent only, with agitation 150 rpm, at 300 T(K) temperature and pH=4. After 180 minutes operation, we still can achieve as high as 91% efficiency.

    摘要 I ABSTRACT II 誌謝 III 總目錄 IV 表目錄 VII 圖目錄 VIII 第一章 緒 論 1 1-1 研究背景 1 1-2 研究動機 3 1-3 研究目的 4 第二章 理論基礎與文獻回顧 5 2-1 膨潤性蒙脫石 5 2-1-1 黏土礦物 5 2-1-2 蒙脫土 8 2-2 吸附機制學 12 2-3 光化學機制 18 第三章 實驗方法與設備 20 3-1 樣品試劑 20 3-2 檢測分析 21 3-2-1 檢測儀器 21 3-2-2 分析方法 24 3-3 操作參數 25 第四章 結果與討論 27 4-1 劑量效應 27 4-2 攪拌效應 32 4-3 溫度效應 34 4-4 pH效應 36 4-5蒙脫土與TIO2之組合系統 38 4-6 時間效應 40 第五章 結論與未來議題 42 5-1 結論 42 5-2 未來議題 44 REFERENCES 47 自述 60

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