簡易檢索 / 詳目顯示

研究生: 程友賢
Cheng, Yu-Hsien
論文名稱: 積層陶瓷電容脫膠固化製程之熱流場與製程進展計算
Calculation of the Thermofluid Fields and Binder Removal Progress in the Curing Process for Multilayer Ceramic Capacitor Manufacturing
指導教授: 楊天祥
Yang, Tian-Shiang
學位類別: 碩士
Master
系所名稱: 工學院 - 機械工程學系
Department of Mechanical Engineering
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 137
中文關鍵詞: 計算流體力學 、熱流場 、積層陶瓷電容 、Curing製程 、銅膏黏著劑燒除
外文關鍵詞: Computational Fluid Dynamics, Thermal Fluid Field, Multilayer Ceramic Capacitors, Curing Process, BBO
相關次數: 點閱:295  下載:0 
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 在現今的電子產品中,小型化、高性能和低電耗趨勢日益重要,而在這些電子設備中,積層陶瓷電容 (Multilayer Ceramic Capacitor; MLCC)作為重要的被動元件之一,對其發展也是相當重要。因此本研究將針對MLCC的脫膠固化製程(Curing Process)製程做進一步的研究,目的為透過計算流體力學之數值分析,以減少在製造MLCC時所需之時間與能源的消耗,並且希望透過此研究,有效了解烤爐內部熱流場情形,將其流場可視化以觀察爐內氮氣濃度能否有效阻絕環境中之氧氣進入烤爐內,防止電容在燃燒時所產生的氧化反應,並針對端電極黏著劑燒除進行分析,觀察黏著劑移除率與溫度之間的關係、氣體產物經由表面擴散的濃度通量、以及熱降解所產生的內部中心壓力,並與實驗數據及文獻結果相互比對,以優化其製程為目的。期望能使MLCC之產品品質有所提升,以即將MLCC熱製程進行整合,以開發一套能一次完成MLCC製造的烤爐,以降低能源的損耗及成本的開銷。
    在目前的結果中,已經成功建立出能與實驗溫度數據趨勢相同之曲線,並以此模型作為基準,對烤爐進行氣體濃度場之分析,藉由此分析可得,在多久的時間下可使其達到製程環境標準,以利於能源的節省。另外在Curing製程的BBO反應中,藉由所模擬出之熱流場,將其結果套用到MLCC的邊界條件中,並針對單一顆電容進行BBO反應計算,利用反應速率方程與Arrhenius方程所描述的一級降解反應,與多孔介質進行耦合。由目前模擬結果可得銅膏黏著劑與溫度之間的關係、黏著劑經熱降解由表面擴散的平均濃度通量、以及經降解後於MLCC內部產生的中心壓力,將其模擬結果與文獻、實驗進行比較,所得之趨勢都大致相同。
    透過以上分析之方法,來驗證模型的可靠性,期望透過此模型建立一套完整的架構,並以此模型最為基準,調整相關參數,來觀察MLCC的內部變化,以幫助我們有效優化製程,達到最佳化之目的。
    關鍵字:計算流體力學、熱流場、積層陶瓷電容、Curing製程、銅膏黏著劑燒除

    Miniaturization, high performance, and low power consumption are becoming more and more crucial for today's electronic products, and multilayer ceramic capacitors (MLCCs) are one of the most crucial passive parts in electronic devices. Aiming to help reduce time and energy consumption in the manufacturing of MLCCs, in this study we have carried out a systematic study on the binder burn-out (BBO) and curing processes for MLCC manufacturing. Technically, by incorporating a first-order BBO kinetics model with the standard mass, momentum, and energy balance equations, a computational model is constructed in this study. By using this model, we successfully obtain numerical results for the temporal variations of the product gas concentrations and MLCC ambient temperature that compare favorably with experimental data. Using the temporally varying MLCC ambient temperature as the boundary condition, the BBO progress in the terminal electrodes of a single capacitor can then be calculated, by treating the capacitor as a porous dielectric and the aforementioned first-order kinetics model, with the reaction rate constant dependent upon temperature through the Arrhenius equation. Through a systematic parameter study, we determined how long it would take to ‘warm up’ the oven and complete the BBO process, which is helpful for energy conservation. It is arguable that through this study useful insights into the thermal and flow fields inside the MLCC curing oven have been gained. And the computational model constructed here can be used to help optimize the equipment and process parameter setting for MLCC manufacturing.

    摘要 i Abstract ii 致謝 xxii 目錄 xxiii 圖目錄 xxvii 表目錄 xxxiv 符號說明 xxxvi Chapter 1. 緒論 1 1-1 研究背景 2 1-2 MLCC介紹與應用 4 1-3 製程介紹 7 1-4 研究動機與目的 10 1-5 研究流程 13 1-6研究架構 14 Chapter 2. 文獻回顧 16 2-1 BBO計算模型 16 2-2 BBO實驗 29 2-3 Curing相關文獻 33 2-4 氣泡的形成 37 2-5本章小結 41 Chapter 3. 機台設備與計算模型 42 3-1 烤爐構造與簡化計算模型 44 1.子膛區域 46 2.氣幕區 49 3.BBO_1 51 4.BBO_2 52 5.BBO_3 53 6.T型管與水冷區 54 3-2估算管路終端溫度 57 3-3材料參數 61 3-4 參數表示式 68 3-5本章小節 70 Chapter 4. 統御方程式與邊界條件 71 4-1 流道區域之統御方程 73 4-2邊界條件與初始狀態 75 1.前方氣幕區(1)與後方氣幕區(11)之邊界條件 76 2.BBO區域之邊界條件(包括BBO_1、BBO_2、BBO_3) 76 3.開放式烤爐入口(8)與出口(12)之邊界條件 77 4.燒結T型管(9)與冷卻T型管(10)之邊界條件 77 5.烤爐壁面(13)之邊界條件 78 6.烤爐環境之初始條件 78 4-3 MLCC端電極內部區域 79 4-3-1多孔介質與降解反應 79 4-3-2端電極材料參數 83 4-3-3等效材料性質 85 4-4本章小結 86 Chapter 5. 結果與討論 87 5-1熱流場分析 90 5-1-1網格獨立性分析 90 5-1-2加入鋼板並調整相關參數 96 5-2氮氣與氧氣濃度場 101 5-3 端電極BBO反應 102 5-3-1黏著劑與孔隙率之體積分率隨溫度之變化 105 5-3-2黏著劑之正規化 108 5-3-3黏著劑降解經由端電極與陶瓷本體表面之擴散濃度通量 109 5-3-4 MLCC內部中心壓力 115 5-4本章小結 117 Chapter 6. 製程參數分析 118 6-1改變抽氣區域流量條件 120 6-2材料參數分析 122 6-2-1陶瓷本體孔隙率比較 123 6-2-2端電極黏著劑於不同初始體積分率下的比較 125 6-3不同參數下MLCC的內部壓力 127 6-4本章小結 129 Chapter 7. 結論與未來工作 130 7-1結論 130 7-2本文貢獻 131 7-3未來工作 132 參考文獻 133

    [1] K. Hiroshi, Y. Mizuno, and H. Chazono "Base-metal electrode-multilayer ceramic capacitors: past, present and future perspectives." Japanese journal of applied physics 42.1R (2003): 1.
    [2] K. Nong, TH Lee, JM Suh, SH Yoon, HW Jang "Perspectives and challenges in multilayer ceramic capacitors for next generation electronics." Journal of Materials Chemistry C 7.32 (2019): 9782-9802.
    [3] M.J. Pan,, and C.A. Randall "A brief introduction to ceramic capacitors." IEEE electrical insulation magazine 26.3 (2010): 44-50
    [4] Y.C. Lee, C.T. Lee, S. Wang, F,S, Shieu "A study of ceramic addition in end termination of multilayer ceramics capacitors with cofiring process." Materials chemistry and physics 100.2-3 (2006): 355-360.
    [5] P. Calvert, and M. Cima "Theoretical models for binder burnout." Journal of the American Ceramic Society 73.3 (1990): 575-579.
    [6] J.A. Lewis. "Binder removal from ceramics." Annual Review of Materials Science 27.1 (1997): 147-173.
    [7] G.C. Stangle, and I.A. Aksay "Simultaneous momentum, heat and mass transfer with chemical reaction in a disordered porous medium: application to binder removal from a ceramic green body." Chemical engineering science 45.7 (1990): 1719-1731.
    [8] A.V. Luikov "Systems of differential equations of heat and mass transfer in capillary-porous bodies." International Journal of Heat and mass transfer 18.1 (1975): 1-14.
    [9] R.V. Shende, J.L. Stephen "Determination of binder decomposition kinetics for specifying heating parameters in binder burnout cycles." Journal of the American Ceramic Society 85.4 (2002): 780-786.
    [10] Wu "Termination of BME–MLCC Using Copper–Nickel Bimetallic Powder as Electrode Material." IEEE Transactions on Components and Packaging Technologies 29.4 (2006): 827-832.
    [11] L. Zhu , X. Xu , N. Song , X. Tang "Optical, rheological, and thermal properties of hollow glass bead filled isotactic polypropylene." Polymer composites 30.10 (2009): 1371-1377.
    [12] F.P. Incropera , D.P. Dewitt , A.S. Lavine , Theodore L. Bergman "Fundamentals of Heat and Mass Transfer , 7th Edition" Wiley : (April 12 , 2011)
    [13] R. Gan, J.Li, X Cao, J Huang, L Qian "Mixed Solvents in MLCC Electronic Paste and Their Effects on the Properties of Organic Vehicle" Polymers 14.4 (2022): 685.
    [14] D.A. Nield, and A. Bejan. "Convection in porous media." Vol. 3. New York: springer, 2006.
    [15] C.T. Cheng , M. Lanagan , B. Jones "Crystallization Kinetics and Phase Development of PbO–BaO–SrO–Nb2O5–B2O3–SiO2‐Based Glass–Ceramics." Journal of the American Ceramic Society 88.11 (2005): 3037-3042.
    [16] E.P. Gorzkowski , M.J. Pan , B. Bender "Glass-ceramics of barium strontium titanate for high energy density capacitors." Journal of electroceramics 18 (2007): 269-276.
    [17] 梁文恆(2000)。"國內外電容器市場之現況與未來"。工業技術研究院產業經濟與趨勢研究中心IEK產業報告。
    [18] 董宗霖;蔡政賢。"黏著劑對薄層化積層陶瓷電容生胚層裂之研究"。高雄應用科技大學工程科技學刊.3(2):pp.81-88,2017
    [19] Detlev FK. Hennings "Dielectric materials for sintering in reducing atmospheres." Journal of the european ceramic society 21.10-11 (2001): 1637-1642.
    [20] N. Halder , D. Chattopadhyay , A.D. Sharma , D. Saha "Effect of sintering atmosphere on the dielectric properties of barium titanate based capacitors." Materials research bulletin 36.5-6 (2001): 905-913.
    [21] K. E. Hrdina , J.W. Halloran , M. Kaviany "Defect formation during binder removal in ethylene vinyl acetate filled system." Journal of materials science 34 (1999): 3281-3290.
    [22] J. R. G Evans , M. J. Edirisinghe , J. K. Wright , J. Crank "On the removal of organic vehicle from moulded ceramic bodies." Proceedings of the Royal Society of London. Series A: Mathematical and Physical Sciences 432.1885 (1991): 321-340.
    [23] K.E. Hrdina , J.W. Halloran , A. Oliveria "Chemistry of removal of ethylene vinyl acetate binders." Journal of materials science 33 (1998): 2795-2803.
    [24] M. Alessandro, T. Faravelli, and E. Ranzi. "Detailed kinetic modeling of the thermal degradation of vinyl polymers." Journal of analytical and applied pyrolysis 78.2 (2007): 343-362.
    [25] R. J. Koopmans, R. Van der Linden, and E. F. Vansant. "Quantitative determination of the vinylacetate content in ethylene vinyl‐acetate copolymers—a critical review." Polymer Engineering & Science 22.14 (1982): 878-882.
    [26] I. M. Salin, and J. C. Seferis. "Kinetic analysis of high‐resolution TGA variable heating rate data." Journal of applied polymer science 47.5 (1993): 847-856.
    [27] M.S. Plesset, and A. Prosperetti. "Bubble dynamics and cavitation." Annual review of fluid mechanics 9.1 (1977): 145-185.
    [28] I.S. Wichman. "A model describing the steady-state gasification of bubble-forming thermoplastics in response to an incident heat flux." Combustion and Flame 63.1-2 (1986): 217-229.
    [29] C. Dong, and H.K. Bowen. "Hot‐Stage Study of Bubble Formation During Binder Burnout." Journal of the American Ceramic Society 72.6 (1989): 1082-1087.
    [30] I.M. Somasundram , A.Cendrowicz , D.I. Wilson. "Phenomenological study and modelling of wick debinding." Chemical engineering science 63.14 (2008): 3802-3809.
    [31] A.K. De , S.M. Khopkar, and R.A. Chalmers. "SOLVENT EXTRACTION OF METALS." (1970).
    [32] M.E. Paulaitis , V.J. Krukonis , R.T Kurnik "SUPERCRITICAL FLUID EXTRACTION." Reviews in Chemical Engineering 1.2 (1983): 179-250.
    [33] Z. Shi , Z. X. Guo, and J. H. Song. "A diffusion-controlled kinetic model for binder burnout in a powder compact." Acta Materialia 50.8 (2002): 1937-1950.
    [34] A.C. West, and S.J. Lombardo. "The role of thermal and transport properties on the binder burnout of injection-molded ceramic components." Chemical Engineering Journal 71.3 (1998): 243-252.
    [35] S.J. Lombardo, and Z.C. Feng. "Determination of the minimum time for binder removal and optimum geometry for three‐dimensional porous green bodies." Journal of the American Ceramic Society 86.12 (2003): 2087-2092.
    [36] C. Chicone , S. J. Lombardo, and D.G. Retzloff. "Modeling, approximation, and time optimal temperature control for binder removal from ceramics." Discrete and Continuous Dynamical Systems-B 27.1 (2021): 103-140.
    [37] H. Xie , J. Jiang , X. Yang , Q. He , Z. Zhou "Theory and practice of rapid and safe thermal debinding in ceramic injection molding." International Journal of Applied Ceramic Technology 17.3 (2020): 1098-1107.
    [38] U. Paik , K.M. Kang , Y.G. Jung , J. Kim. "Binder removal and microstructure with burnout conditions in BaTiO3 based Ni-MLCCs." Ceramics international 29.8 (2003): 939-946.
    [39] Y. Kinemuchi , T. Tsugoshi , K. Watari. "Binder burnout from layers of alumina ceramics under centrifugal force." Journal of the American Ceramic Society 89.3 (2006): 805-809.
    [40] T. Nakamura , M. Wada , K. Hayashi "Development of rapid debinding treatment using superheated steam and debinding behavior for alumina molded bodies." Journal of the Japan Society of Powder and Powder Metallurgy 66.6 (2019): 275-281.
    [41] M. Akhtar, and R.M. Anklekar. "Characterization of copper pastes for end termination application of base metal electrode MLCCs." Microelectronics international 21.2 (2004): 36-40.
    [42] T. Sakaue , and K. Yoshimaru. "Copper powder for termination electrode in MLCC." Journal of the Japan Society of Powder and Powder Metallurgy 50.11 (2003): 908-911.
    [43] U. Kumar. "A development methodology for copper end termination paste—part 1: origin of green defects." Active and passive electronic components 25 (2002): 169-179.

    [44] R.C. Lin, Calculation of the thermofluid fields and binder removal progress in the binder burn-out process for MLCC manufacturing: A numerical Study, Master’s thesis, Department of Mechanical Engineering, National Cheng Kung University, 2022.
    [45] 被動元件產業https://statementdog.com/taiex/31-passive-component-industry
    [46] MLCC的基本原理與分類https://www.researchmfg.com/2013/10/mlcc/
    [47] 鋁質電解電容https://www.moneydj.com/kmdj/wiki/wikiviewer.aspx?keyid=7179ed20-1b4c-4605-b9df-bd64161f710e
    [48] 鉭電容優點與缺點http://www.proan.com.hk/zh-cn/newshow.php?id=473

    下載圖示
    2026-07-26公開
    QR CODE