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研究生: 洪毓傑
Hong, Yu-Jie
論文名稱: 鐵基軟磁材料 Fe-(B10-xCx)-Y-Nb 之感磁生熱研究
Study of Magnetic Induction Thermotherapy of Fe-(B10-xCx)-Y-Nb Soft Magnetic Material
指導教授: 陳引幹
Chen, In-Gann
共同指導教授: 郭瑞昭
Kuo, Jui-Chao
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2015
畢業學年度: 103
語文別: 中文
論文頁數: 66
中文關鍵詞: 鐵基金屬玻璃電磁熱療法感磁生熱鐵損
外文關鍵詞: iron-based metallic glass, electromagnetic thermotherapy, induction heating, core loss
相關次數: 點閱:111下載:5
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  • 長久以來,癌症的高致死率與高復發率一直是困擾著社會大眾以及醫療團隊的一大問題,電磁熱療法(Electromagnetic thermotherapy)有著短恢復期及微小傷口的優點,為現今新興的腫瘤(tumor)治療方式之一,其給予高頻的電流所產生的磁場來加熱軟磁性材料,藉此來殺死癌症或腫瘤細胞。過去許多研究是使用特殊藥物包覆軟磁物質的奈米顆粒,使其吸附在癌細胞的周圍來達到加熱的效果,但使用奈米顆粒的缺點是感磁質量太小,所能產生的熱量較少,無法達到所需的溫度。
    最近的研究中有人利用不鏽鋼針具代替奈米軟磁顆粒作為感磁物質,來解決在磁場下加熱能力不足的問題,而本研究將會以此為基礎,使用鐵基金屬玻璃Fe-(B10-xCx)-Y-Nb來做為針具前端的感磁材料,希望可以增強其在磁場下的加熱能力。鐵基金屬玻璃具有良好的軟磁性、機械性質以及抗腐蝕性,符合電磁熱療系統之針具所需條件,實驗將探討鐵基金屬玻璃成分改質,了解碳成分對磁性質之影響。
    為了解鐵基金屬玻璃Fe-(B10-xCx)-Y-Nb在磁場下的性質,我們將進行材料的電磁加熱實驗、電磁性質與微結構等分析,來對照試片在磁場下的升溫能力。隨著碳成分的添加,在微結構方面其對結晶棒材的晶粒有細化的影響;而在電磁性質方面,隨著碳成分的添加,試片的電阻由3.9×10-4ohm-cm下降至3×10-4ohm-cm,有較高的渦電流損;隨著碳成分的添加,試片的殘留磁力由987Oe上升至約1100Oe,有較高的磁滯損,因此添加碳可提升試片在磁場下的升溫能力。在同樣的電磁爐磁場加熱下,試片可從未添加碳(X=0)的44˚C提升至添加碳X=4的60˚C。

    另外,對試片進行熱處理,也有助於磁場下加熱溫度的提升。試片X=2未熱處理前電阻由原本的3.9×10-4ohm-cm下降至7×10-5ohm-cm,有較高的渦電流損;隨著熱處理time加,試片的殘留磁力由1093Oe上升至約1862Oe,有較高的磁滯損,因此熱處理可提升試片在磁場下的升溫能力。試片X=2未熱處理可從原本的56˚C提升至熱處理10hr的75˚C。
    此外,我們也發現利用家用電磁爐(20kHz、35Oe)進行電磁加熱實驗,可得到與高週波機台(60kHz、350Oe)下相同趨勢的結果,因此可利用家用電磁爐來取代高週波機台進行快速的定性實驗,以利於未來嘗試不同製程及不同材料的鑑定。

    Electromagnetic thermotherapy is a new modality for tumor treatment. It applies a magnetic field and heat up magnetic materials for treating targeted tumors. In this study, the iron-based metallic glass, Fe-(B10-xCx)-Y-Nb, was used for enhancing the heating capacity in electromagnetic thermotherapy. Iron-based metallic glass has good soft magnetization, mechanical properties and corrosion resistance for electromagnetic thermotherapy. This study will focus on the components modified of iron-based metallic glass to investigate the effects of carbon on magnetic properties. With the addition of carbon, the grains of Fe-(B10-xCx)-Y-Nb bars were refined and the eddy current loss increased. Therefore, the total core loss of Fe-(B10-xCx)-Y-Nb increased with the addition of carbon and thus the heating capacity of Fe-(B10-xCx)-Y-Nb can be enhanced.

    摘要 I Extended Abstract III 誌謝 VI 目錄 VIII 表目錄 XI 圖目錄 XII 第一章 緒論 1 前言 1 研究目的 2 第二章 文獻回顧及理論基礎 3 2-1 電磁熱療法介紹 3 2-2 軟磁材料介紹 3 2-2-1 金屬軟磁材料 4 2-2-2 鐵基非晶質合金介紹 5 2-3 鐵損理論及感磁生熱現象介紹 5 2-3-1 磁滯損失 5 2-3-2 渦電流損失 6 2-3-3 異常渦電流損失 6 2-4 熱影像原理介紹 6 2-5 DSC原理 7 第三章 實驗步驟流程及儀器介紹 10 3-1 原料製備及實驗藥品 10 3-1-1 原料製備 10 3-1-2 實驗藥品 10 3-2 實驗儀器及步驟 10 3-2-1 電弧爐實驗 10 3-2-2 非晶薄帶製作 11 3-2-3 電磁加熱實驗 11 3-3 實驗分析儀器 12 第四章 合金性質分析實驗結果 18 4-1 合金薄帶性質分析 18 4-1-1 熱性質分析(DSC) 18 4-1-2 微結構及成分分析 18 4-1-3 電磁性質分析 19 4-1-3-1 SQUID量測 19 4-1-3-2 電阻量測 20 4-2 合金棒材性質分析 20 4-2-1 相組成及成分分析 20 4-2-2 微結構及金相觀察 21 4-2-3 電磁性質分析 21 4-2-3-1 電阻量測 21 4-2-3-2 SQUID量測 21 4-3 合金試片之鐵損量測 22 4-3-1 環形合金試片鐵損量測 22 4-3-2 鐵損量測結果與磁性質分析結果比較 23 第五章 感磁生熱分析 47 5-1 高週波電磁加熱實驗 47 5-1-1 熱影像儀量測之試片發射率校正 47 5-1-2 棒材試片熱電偶量測 47 5-1-3 棒材試片熱影像分析 48 5-1-4 棒材試片升溫曲線分析 48 5-2 家用電磁爐加熱實驗 48 5-2-1 結晶棒材升溫量測 49 5-2-2 非晶環狀試片升溫量測 49 5-2-3 升溫曲線分析 49 5-3 電磁爐加熱實驗與鐵損推算之比較 50 第六章 結論 63 參考文獻 64

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