本文以螯合性高分子模板作為製備硫化鋅奈米微粒的成長基板，其高分子模板係利用無乳化劑乳化共聚合法(emulsion-free polymerization)合成乳液後，再將其成膜而得到高分子薄膜基板。其特徵在於高分子基板表面具有強螯合金屬離子的官能基，在高分子基板螯合金屬離子後，可用二次水清洗多餘未螯合之金屬離子，並利用液相或氣相還原法製備硫化鋅奈米結構於高分子基材上。
　　本研究以縮水甘油甲基丙烯酸酯(GMA)和亞胺乙二酸(IDA)反應得到側鏈具螯合官能基的乙烯系單體，簡稱為GMA-IDA，並使之與丙烯酸正丁酯(BA)及縮水甘油甲基丙烯酸酯(GMA)進行無乳化劑乳化共聚合反應製備得到Poly(BA-co-GMA-co-GMA-IDA) (PBGG-I)高分子乳液，再將乳液成膜製得高分子PBGG-I薄膜基板。PBGG-I薄膜螯合Zn2+離子後，以二次水清洗薄膜上未螯合金屬離子，分別以液相法(Na2S)及氣相法(H2S)製備得到PBGG-I-ZnS奈米複合薄膜材料。探討不同螯合基含量和不同還原方法對於硫化鋅奈米結構的影響。利用SEM可觀察到液相法可製備出不同長度的硫化鋅奈米棒或成束狀的奈米棒；氣相法則可以得到硫化新的奈米粒或奈米棒。

A simple synthetic route for preparation of luminescent and magnetic nanocomposite materials is disclosed. This method comprises providing chelating group-containing polymer templates, and producing nanoparticles on the surface of said polymer template. Various kinds of nanoparticles can be synthesized on polymer templates with electroless plating, ultraviolet irradiation, gas phase and liquid phase chemical precipitation methods. This approach is suitable not only for the preparation of semiconductor nanoparticles but also other nanoparticles, especially those that can be prepared from the reduction of an appropriate metal ion-polymer complex.
In this study, ZnS nanostructures were prepared by using poly(BA-co- GMA-co-GMA-IDA) (PBGG-I) copolymer membranes as template. PBGG-I membranes were synthesized by soap-free emulsion copolymerization of n-butylacrylate (BA), glycidyl methacrylate (GMA) and 2-methacrylic acid 3-(bis-carboxymethylamino)-2-hydroxy-propyl ester (GMA-IDA). GMA-IDA chelating groups within the copolymer were the coordination sites for chelating Zn2+, at which nanosized ZnS nanocrystals were grown by the wet method (Na2S) and the dry method (H2S). The morphology of ZnS nanocrystals were observed by SEM. By the wet method, ZnS nanorods or nanorod-bundles were prepared. On the other hand, ZnS nanoparticles or nanorods were observed by using the dry method.

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