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研究生: 蔣承諭
Chiang, Cheng-Yu
論文名稱: 通電對6061鋁合金性質及微結構影響之研究
Effects of Current Stressing on the Properties and Microstructure of 6061 Aluminum Alloy
指導教授: 林光隆
Lin, Kwang-Lung
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2021
畢業學年度: 109
語文別: 中文
論文頁數: 141
中文關鍵詞: 6061鋁合金電遷移析出物差排密度
外文關鍵詞: 6061 aluminum alloy, Electromigration, Precipitates, Dislocation density
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  • 本研究透過觀察微結構及機電性質,探討通電對6061鋁合金性質變化的影響與機制。本實驗所使用的6061鋁合金是經過過時效處理之試片,以電流密度6400 A/cm2對其通電3-60分鐘,量測不同通電時間對材料微結構、維氏硬度及電阻率的變化,並結合微結構的變化和機、電性質,分析影響材料性質的機制。X光繞射分析顯示電流使材料內部產生應變,但並沒有發生相轉換。掃描式電子顯微鏡分析顯示通電前後析出物數量及尺寸的變化;穿透式電子顯微鏡觀察材料結晶面發現鋁基地相(111)面及(200)面差排密度隨通電時間不同有所增減。藉由電子背向散射繞射分析顯示材料在通電後,(101)為擇優取向;晶界取向差角的分析顯示,高低角度晶界比例變化不明顯,顯示再結晶及凝核等現象不明顯;晶粒尺寸亦無明顯變化。通電後微硬度變化受到差排密度變化影響,差排密度的變化推測是析出物造成的結果,電阻率也同樣與差排密度變化關聯性較大。

    This study investigated the variation of mechanical and electrical properties and microstructure of 6061 aluminum alloy after current stressing. The over-aged specimens were subjected to direct current stressing at 6400 A/cm2 for 3-60 minutes. After current stressing, the specimen was quenched with liquid nitrogen immediately to eliminate the residual joule heat on microstructure. The variation in microstructure, Vickers hardness and electrical resistivity were investigated with respect to current stressing time. The results of XRD investigation showed that strain was generated but no obvious phase transformation occurred. SEM images indicated that precipitates were found in the matrix. The results of TEM investigation showed that the lattice orientation and the dislocation densities in the matrix changed. EBSD results indicated that the preferred orientation was (101). The misorientation angle did not change a lot, grain size of matrix also changed little, indicating no obvious grain growth and recrystallization. The variation of microhardness and electrical resistivity was greatly related to the variation of dislocation density of (111).

    中文摘要 I Extended Abstract II 誌謝 XVII 表目錄 XX 圖目錄 XXI 第壹章、簡介 1 1.1 鋁合金介紹 1 1.1.1 6000系鋁合金介紹 3 1.1.2 6061鋁合金中微量元素之影響 5 1.1.3 6061鋁合金之析出強化機構 7 1.1.4 析出物析出順序 12 1.2 電遷移理論與效應 14 1.2.1 電遷移效應的驅動力 15 1.2.2 電遷移效應所致之焦耳熱效應 21 1.2.3 通電對材料微結構及性質之影響 22 1.3 傳統熱處理對6061鋁合金微結構及性質之影響 31 1.4 研究動機 36 第貳章、實驗方法與步驟 37 2.1 實驗構想 37 2.1.1 6061鋁合金試片 37 2.1.2 試片製備 37 2.1.3 通電裝置 39 2.1.4 通電方法 39 2.1.5 鑲埋試片製備 39 2.2 分析方法 42 2.2.1 X光繞射(X-Ray Diffraction, XRD) 分析 42 2.2.2 維氏硬度分析 43 2.2.3 電性分析 45 2.2.4 析出物分析 50 2.2.5 差排分析 50 2.2.6 電子背向散射繞射(EBSD)分析 53 第參章、實驗結果與討論 59 3.1通電前試片性質觀察 59 3.1.1 通電前之相組成 59 3.1.2 通電前之表面微結構觀察 59 3.1.3 通電前之晶格排列 60 3.1.4 通電前之晶粒取向與尺寸 60 3.2通電後試片觀察 70 3.2.1 XRD分析 70 3.2.2 SEM分析 74 3.2.3 硬度分析 87 3.2.4 電性分析 92 3.2.5 差排密度分析 95 3.2.6 晶粒取向與尺寸分析 99 3.3 通電導致合金性質變化之機制探討 114 3.3.1 影響微硬度之機制 114 3.3.2 影響電阻率變化之機制 127 第肆章、結論 136 參考文獻 137

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