從文獻得知聚N-乙烯甲醯胺（PNVF）與陽離子界面活性劑十六烷基三甲基溴化銨（CTAB）不具有交互作用力，而為了使PNVF能與陽離子型界面活性劑產生交互作用力，本研究利用少量的丙烯酸（AA）單體，其帶有負電荷的性質作為高分子鏈中吸附CTAB的位置，而合成不同NVF/AA比例的PNVF-co-PAA無規共聚物，探討此共聚物與CTAB之間的吸附機制與相行為變化。
本研究先利用螢光光譜探討PNVF-co-PAA/CTAB系統，發現僅需添加3 mol%的AA單元於此共聚物中即可偵測到明顯的交互作用力產生，再進一步以2D NOSEY NMR實驗了解此系統的聚集行為；另一方面，以濁度實驗觀察不同比例的PNVF-co-PAA/CTAB系統之相行為變化，再以界面活性劑電位測定法獲得PNVF-co-PAA開始吸附CTAB的濃度與形成游離微胞的濃度。綜合以上結果推測其吸附機制對相行為變化的影響。

Poly(N-vinylformamide) (PNVF) has no interaction with the cationic surfactant, hexadecyltrimethylammonium bromide (CTAB). In order to establish the interaction between PNVF and cationic surfactants, in this study we have synthesized statistical poly(N-vinylformamide-co-acrylic acid) (PNVF-co-PAA) copolymers with different ratios of NVF/AA. The anionic nature of AA units in the copolymer provides the interaction site toward to the cationic surfactant.
In our work, we found by pyrene fluorescences that only the AA unit is more than 3 mol% in the copolymer, there is a detectable interaction between the copolymer and surfactant. Furthermore, 2D NOSEY experiments gave informations about the aggregation behavior in the PNVF-co-PAA/CTAB system. On the other hand, the phase behavior of the system could be investigated by turbidity measurements. Finally, we used the EMF measurements with a surfactant selective electrode to detect that the onset of binding and the occurrence of free micelles.
We have summarized the results to speculate the binding mechanism and to interpret the phase behavior of the PNVF-co-PAA/CTAB system.

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