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研究生: 姚智鈞
Mandal, Pramod Kumar
論文名稱: 羥丙基甲基纖維素生物薄膜之機械性質研究
Mechanical Properties of Biopolymer Hydroxypropyl Methylcellulose (HPMC) Films
指導教授: 施士塵
Shi, Shih-Chen
學位類別: 碩士
Master
系所名稱: 工學院 - 機械工程學系
Department of Mechanical Engineering
論文出版年: 2017
畢業學年度: 105
語文別: 英文
論文頁數: 106
外文關鍵詞: HPMC, Aluminum nanoparticles, Molybdenum disulphide, Stearic acid, Tensile strength, Water vapor permeability, FTIR
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  • Here hydroxypropyl methylcellulose(HPMC) films prepared, and incorporated with additives materials (i.e. stearic acid (SA), aluminum nanoparticles (Al) and molybdenum disulphide (MoS2). which enhance its mechanical properties and water vapor permeability resistant. For HPMC 606 added with stearic acid, the maximum rise in tensile strength was at 0.15 wt.% to 34 % of the pure HPMC 606, similarly for Al nanoparticles at 0.25 wt.% increased to 24 % and for molybdenum disulphide at 1 wt.% increased to 33 %. Further increased in additives concentration level, resulted in drops of mechanical properties of the respective films. When additives concentration increased above these values, forms long grains boundaries inside the matrix and it leads to increase brittle behavior of the films. There was decreased in the water vapor permeability’s of the films added with incorporative materials.
    Similarly, there was increased in mechanical properties and decreased in water vapor permeability for the HPMC 645 and HPMC 615, when incorporative materials used. Incorporation of additives into the HPMC films were capable of improving the tensile strength and Young’s modulus of HPMC, but it decreases after certain level because further addition of additives causes formation of granules inside the matrix and it leads to increase films brittleness. Which results in decreased percent elongation of the HPMC films. Among these three HPMC types, HPMC 615 shows good mechanical properties as compare to other two HPMC. Thus HPMC 615 with additives have excellent mechanical properties. This type of hybrid films with superior properties is expected to be useful in eco-friendly food packaging applications, pharmaceutical companies and in various industrial used.

    Table of content Chapter 1 INTRODUCTION 1 1.1 Research Motivation 5 1.2 Objectives 6 Chapter 2 LITERATURE REVIEW 7 2.1 Plasticizer effects on mechanical properties of solvent cast soluplus® films 7 2.2 Effect of Stearic Acid Level on the Physical Properties of Natural Rubber Valcanisate 9 2.3 Lipid Particle Size Effect on Mechanical Properties of Whey Protein/Beeswax Emulsion films 10 2.4 Mechanical properties of tapioca-starch edible films containing sorbates 11 2.5 Effect of ZnO Nanoparticles on Structural and Mechanical Properties of HPMC Polymer Films 12 2.6 Investigation on Nanosized CuO Incorporated Hydroxypropyl Methylcellulose Polymer Nanocomposite Films 13 2.7 Physical and mechanical properties of agar based edible film with glycerol plasticizer 15 2.8 Relationship between morphologies and mechanical properties hydroxypropyl methylcellulose/hydroxypropyl starch blends 17 2.9 Effects of lipids on mechanical and moisture barrier properties of edible gellan film 20 2.10 Preparation and Characterization of Silk Fibroin/HPMC Blend Film 21 Chapter 3 MATERIALS AND METHODOLOGY 23 3.1 Materials 23 3.2 Film Preparation 23 3.3 Water vapor permeability (WVP) 30 3.4 Mechanical properties 31 3.5 Brittleness flick test 35 3.6 Fourier Transform Infrared Spectroscopy (FTIR) 36 Chapter 4 EXPERIMENT AND RESULTS 38 4.1 HPMC 606 38 4.1.1 Water Vapor Permeability (WVP) 38 4.1.2 Mechanical Properties 40 4.1.3 Brittleness Flick Test for HPMC 606 43 4.1.3 FTIR Analysis 44 4.2 HPMC 645 49 4.2.1 Water Vapor Permeability 49 4.2.2 Mechanical Properties 52 4.2.3 Brittleness Flick Test for HPMC 645 55 4.2.3 FTIR Analysis 56 4.3 HPMC 615 60 4.3.1 Water Vapor Permeability 60 4.3.2 Mechanical Properties 63 4.3.3 Brittleness Flick Test for HPMC 615 66 4.3.3 FTIR Analysis 67 Chapter 5 72 5.1 Comparison between HPMC types and its tensile strength 72 5.2 Effect of viscosity and molecular weight 73 Chapter 6 Conclusion 76 Chapter 7 References 78 Chapter 8 Appendix 84

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