簡易檢索 / 詳目顯示

研究生: 張力仁
Chang, Li-Jen
論文名稱: 二氧化鉿基鐵電場效電晶體中鐵電切換與電荷去捕獲活化能之溫度相依性分析
Temperature-Dependent Activation Energy Analysis of Ferroelectric Switching and Detrapping in HfO2-Based FeFETs
指導教授: 高國興
Kao, Kuo-Hsing
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 微電子工程研究所
Institute of Microelectronics Engineering
論文出版年: 2026
畢業學年度: 115
語文別: 英文
論文頁數: 59
中文關鍵詞: HfO2基FeFET 、鐵電切換 、電荷去捕獲 、活化能 、低溫特性 、PUND量測
外文關鍵詞: HfO2-based FeFET, Ferroelectric Switching, Charge Detrapping, Activation Energy, Cryogenic Temperature, PUND Measurement
相關次數: 點閱:12  下載:0 
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 本研究針對 HfO2 基鐵電場效電晶體(FeFET)於低溫環境下之鐵電切換(ferroelectric switching)與電荷去捕獲(detrapping)機制進行研究,探討 300 K 至 8 K 溫度範圍內之元件特性變化,並比較兩種物理機制之活化能差異。研究元件採用具有 0.4 nm SiO2 介面層之 HfO2 基 FeFET,以分析介面層對元件切換與可靠度之影響。
    本研究利用 Positive-Up-Negative-Down(PUND)量測分析鐵電極化切換行為,並透過 Fast-IV 量測觀察臨界電壓隨時間之鬆弛特性,以分別萃取鐵電切換時間與電荷去捕獲時間常數。進一步利用 Arrhenius 分析建立溫度與時間常數之關係,計算鐵電切換活化能與電荷去捕獲活化能,並比較不同溫度區間之載子傳輸與極化切換機制。
    實驗結果顯示,鐵電切換與電荷去捕獲皆具有明顯的溫度相依性。鐵電切換活化能顯示低溫下極化切換更容易發生,而電荷去捕獲活化能則反映高溫與低溫區間具有不同的載子釋放機制。透過比較兩種活化能,可進一步釐清 FeFET 中鐵電極化與電荷陷阱之物理機制,並提供 HfO2 基 FeFET 於低溫記憶體及低功耗運算應用之設計與可靠度分析依據。

    Ferroelectric field-effect transistors (FeFETs) based on HfO2 have emerged as promising candidates for next-generation non-volatile memory due to their compatibility with CMOS technology, low power consumption, fast switching speed, and potential for in-memory computing applications. However, the physical mechanisms governing ferroelectric polarization switching and charge detrapping under cryogenic operation remain insufficiently understood, limiting the optimization of device reliability and performance.
    In this work, the temperature-dependent switching and detrapping characteristics of HfO2-based FeFETs with an ultra-thin 0.4 nm SiO2 interfacial layer were systematically investigated over a temperature range from 300 K to 8 K. Polarization switching behavior was characterized using the Positive-Up-Negative-Down (PUND) measurement technique, while charge detrapping was analyzed through fast current-voltage (Fast-IV) measurements. The characteristic switching time and detrapping time were extracted from the experimental data, and the corresponding activation energies were determined using Arrhenius analysis.
    The experimental results show that both polarization switching and charge detrapping exhibit pronounced temperature dependence. The extracted switching activation energy indicates that polarization reversal becomes more favorable at lower temperatures, whereas the detrapping activation energy reveals different carrier emission mechanisms in the high- and cryogenic-temperature regions. Furthermore, a comparison between the switching and detrapping activation energies provides insight into the distinct physical processes governing ferroelectric domain dynamics and charge trapping behavior. These findings improve the understanding of low-temperature operation in HfO2-based FeFETs and provide valuable guidelines for the design and optimization of reliable ferroelectric memory devices for future low-power and cryogenic computing applications.

    中文摘要 I Abstract II Contents IV 表目錄 VI 圖目錄 VII Chapter1 Introduction 1 1-1. Background 1 1-2. HfO2-Based FeFETs and Reliability Challenges 3 1-3. Research Motivation 6 1-4. Thesis Objectives 8 Chapter2 Physical Theory 10 2-1. Ferroelectric Switching Mechanism 10 2-1.1 Nucleation Limited Switching(NLS) Model 12 2-2. Thermally Activated Switching 14 2-3. Charge Trapping and Detrapping 15 2-4. Cryogenic Characterization 17 2-5. Summary 18 Chapter3 Experiment SetUp 19 3-1. Device Structure 19 3-2. Experimental Setup 21 3-3. Measurement Procedures 23 3-3.1 NLS Measurement 24 3-3.2 Fast I-V Measurement 25 3-4. Extraction of Characteristic Time Constants 26 3-5. Extraction of Activation Energy 27 Chapter4 Results and Discussion 28 4-1. Ferroelectric Switching Characteristics and Activation Energy 28 4-1.1 Ferroelectric Switching Characteristics 28 4-1.2 Switching Activation Energy Analysis 32 4-2. Detrapping Characteristics and Activation Energy 35 4-2.1 Detrapping Characteristics 35 4-2.2 Detrapping Activation Energy Analysis 39 4-3. Comparison Between Switching and Detrapping Activation Energies 41 Chapter5 Conclusion and Future Work 44 5-1. Conclusion 44 5-2. FutureWork 45 參考文獻 47

    [1] S. Yu, “Neuro-Inspired Computing With Emerging Nonvolatile Memories,”Proceedings of the IEEE, vol. 106, no. 2, pp. 260–285, 2018.
    [2] A.Sebastian,M.LeGallo,R.Khaddam-Aljameh,andE.Eleftheriou, “MemoryDevices andApplicationsforIn-MemoryComputing,” NatureNanotechnology,vol.15,pp.529 544, 2020.
    [3] D. Ielmini and H.-S. P. Wong, “In-Memory Computing With Resistive Switching Devices,” Nature Electronics, vol. 1, no. 6, pp. 333–343, 2018.
    [4] International Roadmap for Devices and Systems (IRDS), 2023 International Roadmap for Devices and Systems, IEEE, 2023.
    [5] T. S. Böscke, J. Müller, D. Bräuhaus, U. Schröder, and U. Böttger, “Ferroelectricity in Hafnium Oxide Thin Films,”Applied Physics Letters, vol. 99, no. 10, Art. no. 102903, 2011.
    [6] J. Müller, T. S. Böscke, U. Schröder, et al., “Ferroelectricity in Simple Binary ZrO2 and HfO2,” Nano Letters, vol. 12, no. 8, pp. 4318–4323, 2012.
    [7] M. H. Park, H. J. Kim, Y. J. Kim, et al., “Ferroelectricity and Antiferroelectricity of Doped Thin HfO2-Based Films,” Advanced Materials, vol. 27, no. 11, pp. 1811–1831, 2015.
    [8] T. Mikolajick, S. Slesazeck, H. Mulaosmanovic, et al., “Next Generation Ferroelectric Materials for Semiconductor Process Integration and Their Applications,” IEDM Technical Digest, 2019.
    [9] M. Hoffmann, U. Schroeder, C. S. Hsu, et al., “Ferroelectric HfO2 for Ferroelectric Memory Applications,” Advanced Electronic Materials, vol. 5, no. 12, 2019.
    [10] U. Schroeder, M. H. Park, C. S. Hsu, et al., “Ferroelectricity of Hafnium Oxide Based Materials: Current Status and Future Prospects From Physical Mechanisms to Device Applications,” Journal of Semiconductors, vol. 44, no. 5, 2023.
    [11] S. Dünkel, S. Beyer, J. Müller, et al., “A FeFET Based Super-Low-Power Ultra-Fast Embedded NVM Technology for 22 nm FDSOI and Beyond,” IEDM Technical Digest, 2017.
    [12] H.Mulaosmanovic,J.Ocker, S.Dünkel, etal.“NovelFerroelectricFETBasedSynapse for Neuromorphic Systems,” Symposium on VLSI Technology, 2017.
    [13] A.Agarwal,A.M.Walke,N.Ronchi,K.-H.Kao,andJ.VanHoudt, “StudyofEndurance Performance of SiO2 Interfacial Layer Scaling Through O Scavenging in Si Channel n-FeFET With Si:HfO2 Ferroelectric Layer,” IEEE Transactions on Electron Devices, vol. 71, no. 8, pp. 4619–4625, Aug. 2024. doi:10.1109/TED.2024.3409204.
    [14] A. K. Tagantsev, D. O. Alikin, A. I. Rudskoy, et al., “The Origin of the Nucleation Limited Switching Kinetics in Ferroelectric Thin Films,” Nature Communications, vol. 4, Art. no. 2229, 2013.
    [15] J. Y. Jo, S. H. Kim, T. W. Noh, et al., “Domain Switching Kinetics in Disordered Ferroelectric Thin Films,” Nano Letters, vol. 9, no. 1, pp. 496–500, 2009.
    [16] E. Yurchuk, J. Müller, S. Müller, et al., “Charge-Trapping Phenomena in HfO2-Based Ferroelectric Field-Effect Transistors,” IEEE Transactions on Electron Devices, vol. 61, no. 11, pp. 3699–3706, 2014.
    [17] A. J. Tan, Y.-H. Liao, L.-C. Wang, J.-H. Bae, C. Hu, and S. Salahuddin, “Ferro electric HfO2 Memory Transistors with High-𝜅 Interfacial Layer and Write Endurance Exceeding 1010 Cycles,” IEEE Electron Device Letters, vol. 42, no. 7, pp. 994–997, 2021.
    [18] T. Mikolajick, U. Schroeder, and S. Slesazeck, “The Past, the Present, and the Future of Ferroelectric Memories,” npj Electronics Materials, 2022.
    [19] U. Schroeder, M. H. Park, T. Mikolajick, and C. S. Hsu, “The Fundamentals and Applications of Ferroelectric HfO2,” Nature Reviews Materials, vol. 7, pp. 653–671, 2022.
    [20] M. Lederer, S. Starschich, U. Böttger, and T. Mikolajick, “Reliability of HfO2-Based Ferroelectric Thin Films and Field-Effect Transistors,” in HfO2-Based Ferroelectric Materials, Wiley-VCH, 2025.
    [21] U. Schroeder, S. Slesazeck, and T. Mikolajick, “Ferroelectric HfO2-Based Materials and Devices: Physics and Applications,” Journal of Semiconductors, vol. 44, no. 5, 2023.
    [22] S. Starschich, D. Griesche, T. Schneller, R. Waser, and U. Böttger, “Chemical and Structural Origin of Ferroelectricity in HfO2-Based Thin Films,” Applied Physics Letters, vol. 104, no. 20, Art. no. 202903, 2014.
    [23] U. Schroeder, C. S. Hwang, and H. Funakubo, Ferroelectricity in Doped Hafnium Oxide: Materials, Properties and Devices, Woodhead Publishing, 2019.
    [24] A. K. Tagantsev, I. Stolichnov, N. Setter, J. S. Cross, and M. Tsukada, “Non Kolmogorov–Avrami Switching Kinetics in Ferroelectric Thin Films,” Physical Review B, vol. 66, no. 21, Art. no. 214109, 2002.
    [25] E.KondratyukandA.Chouprik, “Polarization Switching Kinetics in Thin Ferroelectric Hf0.5Zr0.5O2 Films,” Nanomaterials, vol. 12, no. 6, Art. no. 1035, 2022.
    [26] J. F. Scott, Ferroelectric Memories, Springer, Berlin, Germany, 2000.
    [27] M. H. Park, Y. H. Lee, H. J. Kim, et al., “Review and Perspective on Ferroelectric HfO2-Based Thin Films for Memory Applications,” MRS Communications, vol. 8, no. 3, pp. 795–808, 2018.
    [28] J. Robertson, “High Dielectric Constant Oxides,” European Physical Journal–Applied Physics, vol. 28, no. 3, pp. 265–291, 2004.
    [29] G. D. Wilk, R. M. Wallace, and J. M. Anthony, “High-𝜅 Gate Dielectrics: Current Status and Materials Properties Considerations,” Journal of Applied Physics, vol. 89, no. 10, pp. 5243–5275, 2001.
    [30] H. Mulaosmanovic, E. T. Breyer, S. Dünkel, S. Beyer, T. Mikolajick, and S.Slesazeck,“Switching Kinetics in Nanoscale HfO2-Based Ferroelectric Field-Effect Transistors,”ACS Applied Materials & Interfaces, vol. 10, no. 43, pp. 37985–37989, 2018.

    QR CODE