簡易檢索 / 詳目顯示

研究生: 簡浩倫
Chien, Hao-Lun
論文名稱: 鈦金屬氧化一系列芳香醇與相關探討
Titanium-Catalyzed Oxidation for a series of Benzyl Alcohols to Aldehydes
指導教授: 宋光生
Sung, Kuang-sen
學位類別: 碩士
Master
系所名稱: 理學院 - 化學系
Department of Chemistry
論文出版年: 2008
畢業學年度: 96
語文別: 中文
論文頁數: 52
中文關鍵詞: 醛類氧化反應
外文關鍵詞: titanium, oxidation, aldehyde
相關次數: 點閱:60下載:1
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 在實驗當中我們發現使用催化量的TiCl4與tert-butyl hydrogen peroxide (TBHP)可使苯環旁的一級醇氧化成醛類,並且討論苯環上的取代基對於反應之Conversion(轉化率)以及Selectivity(選擇性)的影響。

    We found that the combination of titanium-tetra chloride with tert-butyl hydrogen peroxide (TBHP) can oxidize the series of organic compounds with benzyl alcohol converse to aldehyde.

    目錄 中文摘要------------------------------------------3 英文摘要------------------------------------------4 第一章 序論-------------------------------------5 第二章 結果與討論------------------------------15 2.1 實驗步驟與監測方式------------------15 2.2 實驗數據----------------------------17 2.3 結果討論----------------------------22 第三章 產物資料--------------------------------42 參考文獻-----------------------------------------51

    參考文獻
    1.Woodard, S. S. ; Finn, M. G. ; Sharpless, K. B. J. Am.Chem. Soc. 1991, 113, 106.
    2.Chun-Tin Shei, ; Hao-Lun Chien, ; Kuangsen Sung, Synlett. 2008, 1021-1026.
    3.Subbarayan Velusamy, ; T. Punniyamurthy, Org. Lett., 2004, 6, No. 2, 217-219 .
    4.Wai-Hong Fung, ; Wing-Yiu Yu, ; Chi-Ming Che, J. Org. Chem. 1998, 63, 2873-2877.
    5.Suman L. Jain, ; Vishal B. Sharma, ; Bir Sain, Tetrahedron 2006, 62, 6841-6847.
    6.Shouhai Gao, ; Wei Wang, ; Binghe Wang, Chemistry Letters 2001, 48-49.
    7.(a) Takehiko Yamato, ; Naoki Shinoda, ; Tomomi Kanakogi, J. CHEM. RESEARCH (S), 2000, 522-523. (b) Takehiko Yamato, ; Naoki Shinoda, J. CHEM. RESEARCH (S), 2002, 400-402.
    8.V. V. Krishnamurthy, ; G. K. Surya Prakash, ; Pradeep S. Iyer, ; George A. Olah. ; J. Am. Chem. SOC. 1984, 106, 7068-7073.
    9.Nan Jiang, ; Arthur J. Ragauskas, J. Org. Chem. 2006, 71, 7087-7090.
    10.Nidhi Jain, ; Anil Kumar, ; Shive M. S. Chauhan, Tetrahedron Letters 2005, 46, 2599-2602.
    11.Renhua Liu, ; Chunyan Dong, ; Xinmiao Liang, ; Xiujuan Wang, ; Xinquan Hu, J. Org. Chem. 2005, 70, 729-731.
    12.Kyoungsoo Lee, ; Robert E. Maleczka, Jr. Org. Lett., 2006, 8, No. 9, 1887-1888.
    13.Takashi Mino, ; Yoshiaki Shirae, ; Masami Sakamoto, ; Tsutomu Fujita, J. Org. Chem. 2005, 70, 2191-2194.
    14.Nan Jiang, ; Arthur J. Ragauskas, J. Org. Chem. 2007, 72, 7030-7033.
    15.Huiming Jiang, ; Hongjie Sun, ; Shubiao Zhang, ; Ruinian Hua, ; Yingmei Xu, ; Shubin Jin, ; Haiyan Gong, ; Lin Li, Journal of Inclusion Phenomena and Macrocyclic Chemistry 2007, 58, 133-138.
    16.John Harron, ; Robert A. McClelland, ; Chacko Thankachan, ; Thomas T. Tidwell, J. Org. Chem. 1981, 46, 903-910.
    17.Atsushi KAWADA, ; Kayo YASUDA, ; Hitoshi ABE, ; Takashi HARAYAMA, Chem. Pharm. Bull. 2002, 50, No 3, 380-383.
    18.(a)Helena Pettersson, ; Adolf Gogoll, ; Jan-E. Backvall, J. Org. Chem. 1992, 57,6025-6031.(b)Yun Gao, ; Robert M. Hanson, ; Janice M. Klunder, ; Soo Y. KO, ; Hiroko Masamune, ; K. Barry Sharpless, J. Am. Chem. SOC. 1987, 109, 5165-5180.
    19.Mark R. Crimmin, ; Anthony G. M. Barrett, ; Michael S. Hill, ; Panayiotis A. Procopiou, Org. Lett., 2007, 9, No. 2, 331-333.
    20.Masahiro Eikawa, ; Satoshi Sakaguchi, ; Yasutaka Ishii, J. Org. Chem. 1999, 64, 4676-4679.
    21.Juha S. Knuutlnen ; Erkkl T. Kolehmainen, J. Chem. Eng. Data 1983, 28, 139-141.

    下載圖示 校內:2009-06-23公開
    校外:2009-06-23公開
    QR CODE