| 研究生: |
簡浩倫 Chien, Hao-Lun |
|---|---|
| 論文名稱: |
鈦金屬氧化一系列芳香醇與相關探討 Titanium-Catalyzed Oxidation for a series of Benzyl Alcohols to Aldehydes |
| 指導教授: |
宋光生
Sung, Kuang-sen |
| 學位類別: |
碩士 Master |
| 系所名稱: |
理學院 - 化學系 Department of Chemistry |
| 論文出版年: | 2008 |
| 畢業學年度: | 96 |
| 語文別: | 中文 |
| 論文頁數: | 52 |
| 中文關鍵詞: | 醛類 、氧化反應 、鈦 |
| 外文關鍵詞: | titanium, oxidation, aldehyde |
| 相關次數: | 點閱:60 下載:1 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
在實驗當中我們發現使用催化量的TiCl4與tert-butyl hydrogen peroxide (TBHP)可使苯環旁的一級醇氧化成醛類,並且討論苯環上的取代基對於反應之Conversion(轉化率)以及Selectivity(選擇性)的影響。
We found that the combination of titanium-tetra chloride with tert-butyl hydrogen peroxide (TBHP) can oxidize the series of organic compounds with benzyl alcohol converse to aldehyde.
參考文獻
1.Woodard, S. S. ; Finn, M. G. ; Sharpless, K. B. J. Am.Chem. Soc. 1991, 113, 106.
2.Chun-Tin Shei, ; Hao-Lun Chien, ; Kuangsen Sung, Synlett. 2008, 1021-1026.
3.Subbarayan Velusamy, ; T. Punniyamurthy, Org. Lett., 2004, 6, No. 2, 217-219 .
4.Wai-Hong Fung, ; Wing-Yiu Yu, ; Chi-Ming Che, J. Org. Chem. 1998, 63, 2873-2877.
5.Suman L. Jain, ; Vishal B. Sharma, ; Bir Sain, Tetrahedron 2006, 62, 6841-6847.
6.Shouhai Gao, ; Wei Wang, ; Binghe Wang, Chemistry Letters 2001, 48-49.
7.(a) Takehiko Yamato, ; Naoki Shinoda, ; Tomomi Kanakogi, J. CHEM. RESEARCH (S), 2000, 522-523. (b) Takehiko Yamato, ; Naoki Shinoda, J. CHEM. RESEARCH (S), 2002, 400-402.
8.V. V. Krishnamurthy, ; G. K. Surya Prakash, ; Pradeep S. Iyer, ; George A. Olah. ; J. Am. Chem. SOC. 1984, 106, 7068-7073.
9.Nan Jiang, ; Arthur J. Ragauskas, J. Org. Chem. 2006, 71, 7087-7090.
10.Nidhi Jain, ; Anil Kumar, ; Shive M. S. Chauhan, Tetrahedron Letters 2005, 46, 2599-2602.
11.Renhua Liu, ; Chunyan Dong, ; Xinmiao Liang, ; Xiujuan Wang, ; Xinquan Hu, J. Org. Chem. 2005, 70, 729-731.
12.Kyoungsoo Lee, ; Robert E. Maleczka, Jr. Org. Lett., 2006, 8, No. 9, 1887-1888.
13.Takashi Mino, ; Yoshiaki Shirae, ; Masami Sakamoto, ; Tsutomu Fujita, J. Org. Chem. 2005, 70, 2191-2194.
14.Nan Jiang, ; Arthur J. Ragauskas, J. Org. Chem. 2007, 72, 7030-7033.
15.Huiming Jiang, ; Hongjie Sun, ; Shubiao Zhang, ; Ruinian Hua, ; Yingmei Xu, ; Shubin Jin, ; Haiyan Gong, ; Lin Li, Journal of Inclusion Phenomena and Macrocyclic Chemistry 2007, 58, 133-138.
16.John Harron, ; Robert A. McClelland, ; Chacko Thankachan, ; Thomas T. Tidwell, J. Org. Chem. 1981, 46, 903-910.
17.Atsushi KAWADA, ; Kayo YASUDA, ; Hitoshi ABE, ; Takashi HARAYAMA, Chem. Pharm. Bull. 2002, 50, No 3, 380-383.
18.(a)Helena Pettersson, ; Adolf Gogoll, ; Jan-E. Backvall, J. Org. Chem. 1992, 57,6025-6031.(b)Yun Gao, ; Robert M. Hanson, ; Janice M. Klunder, ; Soo Y. KO, ; Hiroko Masamune, ; K. Barry Sharpless, J. Am. Chem. SOC. 1987, 109, 5165-5180.
19.Mark R. Crimmin, ; Anthony G. M. Barrett, ; Michael S. Hill, ; Panayiotis A. Procopiou, Org. Lett., 2007, 9, No. 2, 331-333.
20.Masahiro Eikawa, ; Satoshi Sakaguchi, ; Yasutaka Ishii, J. Org. Chem. 1999, 64, 4676-4679.
21.Juha S. Knuutlnen ; Erkkl T. Kolehmainen, J. Chem. Eng. Data 1983, 28, 139-141.