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研究生: 呂東璇
LU, TUNG-HSUAN
論文名稱: 還原碴產製功能建材之研究
Transformation of Steel Ladle Slags to Functional Construction Materials
指導教授: 張智華
Chang, Chih-Hua
共同指導教授: 張祖恩
Chang, Juu-En
學位類別: 博士
Doctor
系所名稱: 工學院 - 環境工程學系
Department of Environmental Engineering
論文出版年: 2024
畢業學年度: 112
語文別: 英文
論文頁數: 136
中文關鍵詞: 還原碴鹼活化隔熱材料防火材料
外文關鍵詞: Steel ladle slag, Alkali activated slag, Heat controlled materials
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  • 還原碴在OPC砂漿中的使用可能導致由游離CaO和游離MgO引起的體積不稳定性。鹼活化技術可以加速水化反應,解决游離CaO和游離MgO延遲水化反應問題。儘管還原碴會降低OPC砂漿的抗壓强度,但鹼活化技術可以通過水化反應将其强度提高達105%。這項技術還可以提高水泥材料的耐高温性能,在高達800°C的温度下,鹼活化水泥和鹼活化還原碴水泥的抗壓强度分别提高了超過5%,分别達到了3.2 MPa和4.9 MPa。此外本研究發現,應用ASTM C114-30量測f-CaO含量時,評估水泥材料的體積膨脹和耐久性問题時,被低估了高達20%的DCaO含量。鹼活化還原碴水泥技術可將游離CaO轉化為鈣矽水化物,防止Ca(OH)2的膨脹,此外,應用鹼活化發泡技術,可以生產密度可控(1.2〜2.4 kg/m3)、低熱傳導係數(U值,0.18〜0.28 W/m2K)、及高抗壓强度(300〜350 kgf/cm2)、高抗弯强度(38〜70 kgf/cm2)的制热材料,使其與市場上现有的隔熱建材具有很高競争力。本研究以煉鋼爐還原碴作為原料,開發兼具提升循環資源附加價值及創造低碳永續價值的功能建材產品,同時提供鋼鐵產業針對煉鋼爐石精煉碴的創新解決方案。

    The use of Steel Ladle Slag in OPC mortar can lead to volume instability due to free-CaO and free-MgO. Alkali-activated technology can accelerate hydration and address delayed hydration issues. Although Steel Ladle Slag may reduce compressive strength in OPC mortar, alkali-activated technology can enhance its strength by up to 105% through accelerated hydration. This technology also improves the high-temperature resistance of cement materials, increasing compressive strengths by more than 5% at temperatures up to 800 °C to 3.2 MPa and 4.9 MPa for AAS and AASLS. Additionally, there was uncertainty with ASTM C114-30 in assessing the potential for volume expansion and poor durability of cementitious materials when the content of undetected f-CaO was neglected, underestimated DCaO content by up to 20%. The AALS technique converts free-CaO into calcium silicate hydrate, preventing expansion of Ca(OH)2. Furthermore, AALS could produce heat controlled materials with adjustable density (1.2~2.4 kg/m3), exhibited low thermal conductance (U value, 0.18~0.28 W/m2K), and high compressive strength (300~350 kgf/cm2), high bending strength (38~70 kgf/cm2), making them highly competitive with existing insulation materials on the market.

    Transformation of Steel Ladle Slags to Functional Construction Materials I 還原碴產製功能建材之研究 II Table of Contents III List of Tables VII List of Figures IX 1.Introduction 1 1-1 Research motivation 1 1-2 Research purpose 2 2. Literature Review 3 2-1 Electric Arc Furnace EAF ladle slag (EAF Ladle Slag) 3 2-2 Recycling of EAF ladle slag 4 2-3 Expansion mechanism of cementitious materials 4 2-4 Alkali-Activated EAF ladle Slag 6 2-5 Aerated concrete 8 2-6 Green construction materials 10 3. Experimental Methodology 13 3-1 Research profile 13 3-2 Materials 19 3-3 Experimental Methods 21 3-4 Laboratory Equipment and Instruments 25 4. Results and Discussions 29 4-1 The Engineering Properties and Volume Stability of Cementitious and Alkali Activated Slag Mortars Using Steel Ladle Slag Fines. 29 4-1-1 EAF Ladle Slag Mortar 29 (1) EAF Ladle Slag Fines 29 4-1-2 BOF Slag Mortars 36 (1) BOF Slag Fines 36 (2) Properties of the OPC and AAS Mortars Produced with BOF Slag Fines 40 4-1-3 Properties of the OPC and AAS Mortars at High Temperature 49 4-1-4 Conclusions 53 4-2 The Effect of CO for Volume Stability of Cementitious and Alkali Activated Slag Mortars[116] 55 4-2-1 The Clacinated CO Reactivity 55 4-2-2 The Effect of CO on Volume Stability 58 4-2-3 Volume Stability of Mortars Using Steel Ladle Slag and Fly Ash 62 4-2-5 Conclusions 68 4-3 Applying alkali-activated ladle slag foaming technology to produce heat controlled materials 69 4-3-1 Alkali-activated ladle slag foaming technology 69 (1) The effects of water-binder ratio (W/B) for the foaming properties. 69 (1-1) The influence of W/B on flowability 69 (1-2) The influence of W/B on pore structure 70 (1-3) The influence of W/B on compressive strength and density 74 (2) The effects of alkali modulus ratio (Ms) for the foaming properties. 76 (2-1) Influence of Alkali Modulus Ratio on Fluidity 76 (2-2) The impact of alkali modulus on gas generation reactions 77 (2-3) The impact of alkali modulus ratio on pore structure 79 (2-4) The impact of alkali modulus ratio on compressive strength and density 82 (3) The effects of alkaline equivalent (Na2O%) for the foaming properties. 84 (3-1) The impact of alkalinity equivalent on fluidity 84 (3-2) Influence of alkali content on pore structure 85 (3-3) Influence of alkali content on compressive strength and density 88 (4) The effects of the type of foaming stabilizer for the foaming properties. 89 (4-1) Influence of stabilizers on pore structure 89 (4-2) 7% alkaline equivalent on compressive strength and density 93 (4-3) The effect of stable foaming agent with 4% alkali equivalent on pore structure 95 (4-4) the effect of stable foaming agent against compressive strength and density under 4% alkali content equivalence. 99 4-3-2 Functional characteristics of thermal engineering materials 101 (1) The compressive strength and water absorption characteristics of heat-insulating engineering materials 101 (2) Thermal insulation properties of heating engineering materials 102 (3) The fire resistance capability of thermal engineering materials. 103 (4) The sound insulation properties of thermal engineering materials. 106 5. Conclusions 110 Reference 112

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