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研究生： 阮停遵
Nguyen, Dinh Tuan
論文名稱： QCM作為石墨烯氫氣吸附的直接量測方法
QCM for Direct Measurement of Graphene-based Hydrogen Storage
指導教授： 謝馬利歐
Mario Hofmann
學位類別： 碩士
Master
系所名稱： 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年： 2015
畢業學年度： 103
語文別： 英文
論文頁數： 50
外文關鍵詞： graphene, hydrogen storage, microbalance, QCM
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    • Hydrogen fuel cells are expected to power a new generation of clean, efficient vehicles in the future. One of the major technical obstacles that currently inhibits the popularization of these vehicles is the hydrogen storage problem. Among the candidates for hydrogen storage material, graphene stands out with its superior properties (e.g. huge surface area, stability, decreasing price...). Research into the potential of graphene-based hydrogen storage, however, is limited by our inability to make accurate measurement of hydrogen adsorption in graphene since it only exists in tiny quantities. In this project, we examine the possibility of using a quartz crystal microbalance (QCM) for a direct and simple, yet precise and inexpensive method to monitor hydrogen storage in graphene and similar materials.

    ACKNOWLEDGEMENTS I ABSTRACT III TABLE OF CONTENTS V LIST OF FIGURES VII LIST OF TABLES IX CHAPTER 1 INTRODUCTION 1 1.1 Hydrogen fuel cells 1 1.2 Hydrogen storage 2 1.2.1 Compressing and liquefaction 4 1.2.2 Metal hydrides 4 1.2.3 Complex and non-metal hydrides: 5 1.2.4 Adsorbents 6 1.2.5 Graphene 7 1.3 Motivation 9 1.3.1 Challenge in measurement of hydrogen storage: 9 1.3.2 Quartz crystal microbalance for hydrogen storage measurement 10 CHAPTER 2 BACKGROUND AND METHODS 12 2.1 Principle of quartz crystal microbalance 12 2.1.1 Basics of quartz crystal 12 2.1.2 Quartz crystal as a microbalance: 15 2.1.3 QC used in the project: 17 2.2 Quartz crystal treatment 18 2.2.1 PMMA spin coating 18 2.2.2 Parylene deposition 20 2.3 Characterization instruments 21 2.3.1 Digital multimeter 21 2.3.2 Function generator 22 2.3.3 Oscilloscope 22 CHAPTER 3 MEASUREMENT SETUP 24 3.1 Frequency measurement by DMM 24 3.2 Characterization of QCM impedance by DMM 25 3.3 Characterization of QCM impedance by LCR meter 27 3.3.1 Measurement setup 27 3.3.2 Data processing 28 CHAPTER 4 RESULTS AND DISCUSSION 30 4.1 Characterization of QCM impedance 30 4.1.1 Modeling QCM impedance 30 4.1.2 Frequency response in DMM setup with PMMA-coated QC 31 4.1.3 Impedance in LCR meter setup with PMMA-coated QC: 32 4.2 Mass loading determination 33 4.2.1 With DMM setup 34 4.2.2 With LCR meter 35 4.3 Factors affecting measurement reliability 37 4.4 Initial demonstration in graphene-coated QC 38 4.5 On the operation of DMM and LCR meter 41 CHAPTER 5 OUTLOOK 44 5.1 Suggestions for improvement by current methods 44 5.2 Future work 44 5.3 Conclusion 46 REFERENCES 47

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