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研究生: 黃傑治
Huang, Chich-Chih
論文名稱: 船舶奈米塗料於防污減阻與物性之研究
Study of ship nano coating for anti-fouling to decrease resistance and physics property
指導教授: 方銘川
Fang, Ming-Chung
學位類別: 碩士
Master
系所名稱: 工學院 - 系統及船舶機電工程學系
Department of Systems and Naval Mechatronic Engineering
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 114
中文關鍵詞: 奈米防污塗料接觸角摩擦阻力
外文關鍵詞: nano antifouling coating, contact angle, friction resistance
相關次數: 點閱:99下載:10
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  • 由於船舶減阻通常有兩種,其一是藉由改變外型而達到減少興波阻力,另一即藉由船殼表面之處理來減少摩擦阻力,本文主要研究即以後者為主,擬以蓮花效應之構想,開發出具有高接觸角之奈米塗料,來減低船舶表面之摩擦阻力,並藉以提高其防污能力。
    本研究主要是利用含氟的矽烷進行SiO2奈米粉末改質,成為容易被甲苯潤濕之粉末,並利用不同基材架構與氧化亞銅(Cu2O)調製成奈米塗料,進行接觸角、硬度、附著力、鹽水噴霧、生物毒性、漁船船模與翼板阻力、海洋曝露等各種實驗。其中以Silicone為基材的高接觸角奈米塗料,經海洋曝露實驗與迴流水槽沖擊實驗下發現可使海生物附著不易,並且與市面船舶防污面漆經翼板阻力實驗比較下,在中低速航行之船舶,平均可減低阻力達11.5%;經漁船船模阻力實驗比較下,平均可減低阻力達13.8%。

    There are two kinds of ship resistance. One is that changing the appearance would result in the decrease of wave-making resistance. Another is to change the coating surface of the ship resulting in a decrease of friction resistance. Our research is to investigate the latter. The idea of the lotus-effect leads to the development of a high contact angle of nano coating which reduces friction resistance on the surface of the ship and elevates the surface to prevent pollution.
    In the present study, we mainly used silane containing fluorine elements to change the quality of SiO2 nano powder which was wetted by toluene. Furthermore, using different structure of based materials was formulated with oxidize copper (Cu2O) to form the nano coating which was performed on the experiments of hardness, adhesive force, contact angle, salt solution spraying, biological toxicity, ship mould resistance and exposure to ocean, etc. On the other hand, ship at mid low rate(or speed) would reduce by average a resistance of 11.5% through the experiment of resistance of foil. Again, it would reduce the resistance by 13.8% through experiment of fishing boat block mould.

    目 錄 中文摘要 I 英文摘要 II 致謝 III 目錄 IV 表目錄 VIII 圖目錄 IX 符號說明 XIV 第一章 緒論 1 1-1 引言 1 1-2 研究背景與目的 2 1-3 文獻回顧 4 第二章 實驗儀器設備與模型 8 2-1 分析儀器與設備 8 2-2 實驗模型 12 第三章 船舶奈米塗料 15 3-1 奈米尺寸定義 15 3-2 奈米材料 17 3-2-1 奈米材料定義 17 3-2-2 奈米材料的基本性質 17 3-2-3 奈米材料與分散體系 17 3-3 奈米防汙塗料製作 18 3-4 實驗藥品 18 3-5 奈米防汙塗料簡介 19 3-6 耦合劑種類對接觸角影響 23 3-7 不同塗料基材對接觸角影響 25 3-8 殺菌劑Cu2O對接觸角影響 27 第四章 塗料物理性質及生物毒性實驗步驟與方法 31 4-1 實驗方法 31 4-2 鉛筆硬度試驗步驟 33 4-3 接觸角量測儀試驗步驟 33 4-4 附著力測試機試驗步驟 34 4-5 鹽水噴霧試驗 35 4-6 生物毒性試驗-吳郭魚試驗法 37 4-6-1 方法概要與目的 38 4-6-2 生物實驗干擾 38 4-6-3 吳郭魚之馴養 39 4-6-4銅(Cu) 42 4-6-5魚介類中銅含量檢測方法 42 4-6-6 水溶液含銅量實驗 43 第五章 阻力實驗 45 5-1 船舶剩餘阻力與摩擦阻力 45 5-2 實驗方法 46 5-3 翼板阻力實驗步驟 49 5-4 漁船船模阻力實驗步驟 50 第六章 奈米塗料海洋曝露實驗 52 6-1 海洋環境 52 6-2 常見海生物種類 53 6-3 海生物附著原理 55 6-4 研究方法與實驗過程 57 6-4-1 研究工作與目標 57 6-4-2 實驗地點與投海鋼板規劃製作 57 6-5 迴流水槽沖擊實驗 63 第七章 結果與討論 65 7-1 船舶奈米塗料與市面防汙面漆分析 65 7-2 塗料物理性質及生物毒性實驗分析 66 7-3 阻力實驗結果分析 68 7-4 海洋曝露實驗 71 第八章 結論與未來展望 106 參考文獻 110 自述 114

    參考文獻
    1.A.Abbott, P.D.Abel, D.W.Arnold, A. Milne,“Cost–benefit analysis of the use of TBT: the case for a treatment approach”Sci. Total Environ., Vol.258, pp.5-19 (2000)
    2.Axiak VM, Sammut M, Chircop P, Vella A, Mintoff B “Laboratory and field investigations on the effects of organotin(tributyltin) on the oyster (Ostrea edulis.)”Sci. total Environ., Vol.171, pp.117-120 (1995)
    3.Barthlott W. and C.Neinhuis“Purity of the sacred lotus, or escape form contamination in biological surfaces”, Planta, Vol.202, pp.1-8 (1997)
    4.C.D.Anderson, J.E.Hunter, NAV2000 Conference Proceedings, Venice, September (2000)
    5.Clotiled Bertin and Alain C.M.Bourg, “Trends in the Heavy Metal Content (Cd, Pb, Zn)of River Sediments in the Orainage Basin of Smelting Activity”, Wat. Res., Vol.29, No.7, pp.1729-1736 (1995)
    6.D.M.Yebra, S.Kiil, K.D.Johansen, “Antifouling technology-past, present and future steps towards efficient and environmentally friendly antifouling coatings.”, Progress in Organics Coatings, Vol.50, No.2, pp.75-104 (2004)
    7.E.C. de Oliveira-Filho, R.M.Lopes, F.J.R.Paumgartten.,“Comparative study on the susceptibility of freshwater species to copper-based pesticides.”Chemosphere, Vol.56 pp.369-374 (2004)
    8.E.C.M.Parsons, “Trace metal pollution in Hong Kong:Implication for the health of Kong’s Indo-Pacific hump-backed dophins”, the Science of the Total Environment Vol.214, pp.175-184 (1998)
    9.Hwang.D.P.,“A Proof of Concept Experiment for Reducing Skin Friction by Using a Micro-Blowing Technique”, NASA Technical Memorandum 107315, AIAA pp.97-0546 (1997)
    10.IMO (International Convention on the Control of Harmful Anti-fouling Systems on Ships)(2001.10)
    11.S.Abarzua, S.Jakubowsky, Mar. Ecol. Prog. Ser., Vol.123, pp.301-312 (1995)
    12.Kazuo T.Suzki, Sanae Kanno, Shogo Misawa, Tasunobu Aoki,“Copper metabolism leading to and following acute hepatitis in LEC rats.”, Toxicology, Vol.97, pp.81-92. (1995)
    13.Lo, C.C., and M.H. Ho.,“Determination of ethylene oxide in surfactants.”.Fourth International Symposium on Adjuvants for Agrochemicals Proc., Melbourne, Australis, pp37-41 (1995)
    14.Lo, C.C. and M.H.Ho.,“Determination of imidazolidine-2-thione (Ethylenethiourea) in ethylenebisdithiocarbamate formulations.”, Pesticide Science, Vol.37, pp.247-251 (1993)
    15.M.A. Champ,“A review of organotin regulatory strategies, pending actions, related costs and benefits ”Sci. Total Environ., Vol.258, pp.21-71 (2000)
    16.M.E.Callow, R.L.Fletcher, Int.Biodeter., Biodegr., Vol.34, pp.333-348 (1994)
    17.N.Voulvoulis, M.D.Scrimshaw and J.N.Lester“Review Alternative Antifouling Biocides.”, Appl. Organometal. Chem. Vol.13, pp.135-143 (1999)
    18.S.Abarzua, S.Jakubowsky, Mar. Ecol. Prog. Ser., Vol.123, pp.301-312 (1995)
    19.“sea surface temperature(SST)”Real-time, global, sea surface temperature analyses, http://polar.ncep.noaa.gov/sst/.
    20.Takahashi.T., “Drag Reduction Experimental by Means of Micro Air Bubbles Using a Ship Model With a Flat Bottom”, 66th General Meeting of SRI (1995)
    21.Tolosa.I., J.W.Readman, A.Blaevoet, S.Ghilini, J.Bartocci, and M.Horvat,“Contamination of Mediterranean coastal waters by organotins and Irgarol 1051 used in antifouling paints.”, Mar.Pollut.Bull, Vol.32, No.4, pp.335-341(1996)
    22.Woods Hole Oceanographic Institution(WHOI), US Naval Institute, Annapolis, Iselin, COD, (1952)
    23.“魚介類中鎘、鉻、銅、鎳、鉛及鋅含量檢測方法-電熱式原子吸收光譜法”,中華民國90年10月9日(90)環署檢字第63429號公告。(2002)
    24.李世光、林世明、張培仁,“奈米科學與技術導論”,經濟部工業局印行 (2002)。
    25.張立德、牟季美,“奈米材料和奈米結構”,滄海書局印行 (2002)。
    26.徐世昌,“蓮花的自潔功能與奈米科技的應用”,科學發展, Vol.354, 60-63,(2002)。
    27.邵廣昭、邱郁文,海洋生物入侵種之現況及管理。入侵種生物管理研討會論文集, pp.103-110,(2003)。
    28.行政院農業委員會農糧字第0920020073號公告,民國92年1月14日。(2003)
    29.田耀仁,“自由液面下板殼塗裝減阻研究”國防大學中正理工學院造船工程研究所碩士論文,民國九十二年五月十九日。(2003)
    30.馬遠榮,“低微奈米材料”科學發展,382期,73-75頁,(2004)。
    31.鹽水噴霧試驗(Methods of salt spray testing),中國國家標準CNS-8886,中華民國94年印行,(2005)。
    32.蘇一哲、黃元昌、溫佳玲、沈永清,“低表面能之自潔性塗料發展”,化工資訊與商情,22期,38-45頁,(2005)。

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