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研究生: 吳尚沅
Wu, Shang-Yuan
論文名稱: AlxCoCrFeNi高熵合金環形盤之熱挫曲研究
Research on the Thermal Buckling of AlxCoCrFeNi High-Entropy Alloy Annular Disk
指導教授: 李旺龍
Li, Wang-Long
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2026
畢業學年度: 114
語文別: 中文
論文頁數: 143
中文關鍵詞: 高熵合金 、熱挫曲 、邊界條件 、溫度相依性 、有限元素分析
外文關鍵詞: High-Entropy Alloys, Thermal Buckling, Boundary Conditions, Temperature Dependence, Finite Element Analysis
相關次數: 點閱:134  下載:4 
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  • 本研究主要探討AlxCoCrFeNi高熵合金(High-Entropy Alloys, HEAs)在不同鋁元素比例下之熱挫曲行為。研究透過考量材料參數的溫度相依性,分析環形盤在Clamped- Free、Free- Free與Free- Clamped的三種邊界條件的熱挫曲特徵值差異,並獨立分析各材料參數對挫曲特徵值之具體影響。
    研究結果表明,邊界條件是決定熱挫曲模態與結構抗挫曲能力的主導因素。在「內環自由、外環固定(Free-Clamped)」條件下,結構呈現,展現最佳抗挫曲能力;反之,「完全無拘束(Free-Free)」條件則呈極易發生熱挫曲。在材料參數方面,熱膨脹係數的溫度相依性是造成熱挫曲特徵值下降的主因;然而,楊氏模數可提供部分正向補償作用以減緩穩定性衰退。值得注意的是,熱傳導率的影響則具備高度的邊界條件依賴特性,當外部邊界受拘束時,熱傳導率與熱膨脹係數會產生顯著的類疊加效應,導致特徵值隨溫度上升而下降。
    在合金成分的探討中,則發現尤以鋁元素比例x=1.25之高熵合金展現出最佳的高溫穩定性。此優勢源於其熱膨脹係數隨溫度上升的增幅較小,因此在各類邊界條件下皆具備優異的抗挫曲表現。幾何部分,透過不同軸向厚度的比較證實,在薄板範疇內,特徵值與環形盤厚度呈平方正比關係。而最後,內環基礎溫度的提升則將降低外環的臨界挫曲溫度,不過x=1.25仍然在Free- Clamped與Clamped- Free展現較高的外徑臨界挫曲溫度。

    This study investigates the thermal buckling behavior of High-Entropy Alloys (HEAs) with varying aluminum elemental ratios. By considering the temperature dependence of material properties, this research analyzes the differences in thermal buckling eigenvalues of annular discs under three boundary conditions—Clamped-Free, Free-Free, and Free-Clamped—and independently evaluates the specific impact of each material parameter on the buckling eigenvalues.
    The results indicate that boundary conditions are the dominant factor dictating the thermal buckling modes and structural resistance to buckling. Under the Free-Clampedcondition, the structure exhibits a mode 3 buckling shape and yields the highest eigenvalue, demonstrating optimal buckling resistance. Conversely, the fully unrestrained Free-Free condition presents a mode 2 (potato-chip-like) buckling shape, rendering it highly susceptible to thermal buckling. Regarding material parameters, the temperature dependence of the coefficient of thermal expansion (CTE) is the primary cause of the degradation in thermal buckling eigenvalues. However, Young's modulus provides a partial positive compensation effect, mitigating the decline in structural stability. Notably, the influence of thermal conductivity exhibits a strong dependency on boundary conditions. When the outer boundary is constrained, the thermal conductivity and CTE produce a significant pseudo-superposition effect, leading to a drastic decrease in eigenvalues as the temperature rises.
    In the evaluation of alloy compositions, the HEA with an aluminum ratio of x=1.25 exhibits optimal high-temperature stability. This advantage stems from the relatively small increment in its CTE with rising temperatures, thereby demonstrating excellent buckling resistance across all evaluated boundary conditions. Geometrically, comparisons of varying axial thicknesses confirm that within the thin-plate regime, the buckling eigenvalue is directly proportional to the square of the annular disc's thickness. Finally, an elevation in the base temperature of the inner ring lowers the critical buckling temperature of the outer ring. Nevertheless, the x=1.25 alloy maintains a higher outer critical buckling temperature under both Free-Clamped and Clamped-Free conditions.

    摘要 I Extended Abstract II 表目錄 XIII 圖目錄 XIII 符號總表 XVI 第一章、緒論 1 1.1 前言 1 1.2 高熵合金 4 1.2.1 AlCoCrFeNi五元高熵合金 9 1.2.2 AlxCoCrFeNi五元高熵合金的製備 10 1.2.3 高熵合金的應用 12 1.3 研究動機與目的 12 1.4 研究架構 13 第二章、研究理論 16 2.1 簡介 16 2.2 力學場基本理論 16 2.2.1 力學場方程式 16 2.2.2 熱膨脹方程式 20 2.2.3 環形盤薄板之熱彈性應力應變關係 21 2.3 挫曲(buckling) 25 2.3.1 板理論(Plate theory) 25 2.3.2 2D板理論熱挫曲 27 2.3.3 熱挫曲特徵值問題求解 41 第三章、數值模擬 47 3.1 有限元素法 47 3.1.1 Galerkin法 48 3.1.2 離散化 48 3.1.3 Newton-Raphson演算法 48 3.2 數值解分析求解流程 49 3.3 模型介紹 50 3.4 AlCoCrFeNi合金環形盤的量測參數引用 51 3.4.1 熱膨脹係數 52 3.4.2 熱傳導係數 53 3.4.3 楊氏模數 54 3.4.4 熱容量 55 3.4.5 密度 56 3.4.6 蒲松比 57 3.5 鋁元素比例對高熵合金溫度相依材料參數之影響 58 3.6 網格測試 63 第四章、結果與討論 66 4.1 三種邊界條件下的AlxCoCrFeNi高熵合金環形盤 66 4.2 AlxCoCrFeNi高熵合金的溫度相依材料參數獨立比較 73 4.3 AlxCoCrFeNi高熵合金環形盤的厚度參數探討 84 4.4 內徑溫度與邊界條件對高熵合金環形盤臨界挫曲溫度的影響 87 第五章、結論 89 參考文獻 91 附錄A 環形盤之熱挫曲公式推導 96 A.1.1 自由邊界(Free- Free)之關係 96 A.1.2 邊界條件(Fixed-Free)之關係 101 A.1.3 邊界條件(Free- Fixed)之關係 101 附錄B 鋁鈷鉻鐵鎳合金材料參數量測 103 B.1 均質化合金試片製備與熱膨脹係數量測 103 B.2 熱示差掃描(DSC)分析量測與熱傳導率量測 104 B.3 分子動力學模擬線性預測楊氏模數 104 附錄C 鋁鈷鉻鐵鎳合金溫度相依性特徵值比較 106 附錄D 鋁鈷鉻鐵鎳合金環形盤於不同厚度之特徵值 122

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