簡易檢索 / 詳目顯示

研究生: 王譔博
Wang, Chuan-Po
論文名稱: 單根或陣列式奈米碳管之定位成長
Positioning of Single or Arrays of Carbon Nanotubes Growth
指導教授: 高騏
Gau, Chie
學位類別: 碩士
Master
系所名稱: 工學院 - 航空太空工程學系
Department of Aeronautics & Astronautics
論文出版年: 2005
畢業學年度: 93
語文別: 中文
論文頁數: 49
中文關鍵詞: 熱回熔奈米碳管
外文關鍵詞: carbon nanotubes, thermal reflow
相關次數: 點閱:126下載:3
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  •   本研究提出一項製程技術,克服光學微影原有之限制,達到奈米尺度微影。此技術可以定義出相當於電子束微影或奈米壓印微影此兩項奈米微影技術所要求之特徵尺度,並且可以大幅的降低生產的成本達到量產的需求。其方法在於應用現有光學微影的技術定義光組圖形,藉由光阻熱回熔(Thermal reflow)特性將圖形線寬縮小至100奈米以下,再利用物理氣相沉積系統與Lift-off製程技術定義出成長奈米碳管或奈米線所需之催化劑(如鐵、鈷、鎳、金等)。

      藉此做為奈米碳管或其它奈米結構(如矽奈米線)之定位,藉此一技術控制奈米碳管或其它奈米結構的密度。並且達到低成本且具有量產潛能之目的。

      In this paper we provided a simple fabrication process to overcome the limit of the optical lithography and achieve nano-scale lithography. This process can make a nano-scale pattern like Electron-beam Lithography (EBL) or Nanoimprinting Lithography (NIL) does, but at much lower fabrication cost.

      This process is described as follows: fist, micro-scale circle array pattern was made on photoresist by using conventional g-line optical lithography. Then, thermal reflow process was adopted to reduce the size of the circle array to nano-scale. Different reflow temperatures and resist thickness were made to achieve a much smaller size of circle array which can be used to produce nanopartile array at desired locations. In the reflow process, the size of circle array can be reduced to less than 100 nm if proper thickness of resist and reflow temperature were selected. The reflow temperature varies from 160 t0 190oC and the thickness of the photoresist varies from 7 to 12μm. Finally, a thin film of Nikel was deposited on the patterned resist, and lift-off process was used to form anoparticles for growth of Carbon Nanotubes (CNTs).

      Using the method presented in this thesis, CNTs or other nano structures can be grown at desired locations, or the density of CNTs or other nano structures can be properly controlled.

    目 錄 授權書 簽署人須知 簽名頁 中文摘要 英文摘要 致謝 目錄...........................................Ⅰ 表目錄.........................................Ⅳ 圖目錄.........................................Ⅴ 第一章 導論 1.1. 研究動機...................................1 1.2. 文獻回顧 1.2.1. 光學微影.................................2 1.2.2. 非光學微影...............................3 1.2.3. 光阻熱回熔...............................6 1.2.4. 奈米碳管.................................7 第二章 實驗流程與參數設計 2.1. 實驗流程..................................11 2.2. 參數設計 2.2.1. 熱回熔光罩設計..........................12 2.2.2. 熱回熔實驗參數設計......................12 第三章 晶片製作與實驗步驟 3.1. 主要製程技術簡介 3.1.1. 晶圓表面之清潔..........................14 3.1.2. 微影....................................15 3.2. 製程設備 3.2.1.自動化光阻塗佈及顯影系統(Track).....17 3.2.2.光罩對準曝光系統(Mask aligner)......19 3.2.3.微波電漿化學氣相沉積系統(MPCVD).....20 3.3. 製程步驟..................................20 第四章 實驗結果與討論 4.1. 熱回熔實驗 4.1.1. 不同溫度對光阻流動長度之影響.......22 4.1.2. 熱回熔時間對光阻流動長度之影響.....22 4.2. 定義Ni金屬薄膜與成長奈米碳管..............24 4.3. 結論與未來展望............................24 參考文獻.......................................26 圖表...........................................27 自述...........................................48 著作權聲明.....................................49

    [1.]G. Feiertag et.al., Appl. Phys. Lett. Vol. 71, pp. 1441, 1997.
    [2.]S. Y. Chou, R. K. Peter and J. R. Preston, Appl. Phys. Lett., Vol. 67, No.21, pp. 3114-3116, 1995.
    [3.]Jung-In Han, Chul-Hi Han, IEEE Electron Device Letters, Vol. 20, No. 9, 1999.
    [4.]Che-Ping Lin, Hsiharng Yang and Ching-Kong Chao, J. Micromech. Microeng., Vol. 13, pp. 775-781, 2003.
    [5.]Hsiharng Yang, Ching-Kong Chao, Mau-Kuo Wei and Che-Ping Lin, J. Micromech. Microeng.,Vol. 14, pp. 1197-1204, 2004.
    [6.]S. H. Sow et.al., Appl. Phys. B, Vol. 78, pp. 705-709, 2004.
    [7.]S. W. Tan, W. T. Chen and W. S. Lour, Semicond. Sci. Technol., Vol. 19 pp. 167-171, 2004.
    [8.]S. Iijima, Nature, Vol. 354, pp. 56-58, 1991.
    [9.]P. Kim, L. Shi, A. Majumdar, and P. L. McEudn, Phys. Rev. Lett. Vol. 87, pp. 215502, 2001
    [10.]J. P. Smalla, L. Shib, and P. Kim, Solid State Commun. Vol. 127, pp. 181, 2003
    [11.]T. W. Ebbesen, P. M. Ajayan, Nature, Vol. 358, pp. 220-222, 1992.
    [12.]R. E. Smalley et.al., Science, Vol. 273, pp. 483-487, 1996.
    [13.]Hongjie Dai, Carbon Nanotube (Synthesis Structure Properties and pplications), pp. 32-35, 2001.
    [14.]J. Kong, A. M. Cassell, H. Dai, Chem. Phys. Lett., Vol. 292, pp. 567-574, 1998.
    [15.]J. Kong, H. Soh, A. Cassell, C. F. Quate, H. Dai, Nature, Vol. 395, pp. 878-879, 1998.
    [16.]邱燦賓,施敏,科學發展月刊,第28卷,第6期,2000.
    [17.]莊達人, “VLSI 製造技術,” 高立圖書

    下載圖示 校內:立即公開
    校外:2005-08-30公開
    QR CODE