簡易檢索 / 詳目顯示

研究生: 謝和諺
Hsieh, He-Yen
論文名稱: 高濃度藻類原水對複合濾料水質淨化系統之影響:氮系與顆粒物質之累積與轉化
The impact of high-concentration algal raw water on the multi-soil-layering system includes the accumulation and transformation of nitrogen species and particulate matter
指導教授: 張智華
Chang, Chih-Hua
學位類別: 碩士
Master
系所名稱: 工學院 - 環境工程學系
Department of Environmental Engineering
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 135
中文關鍵詞: 複合濾料水質淨化系統逐步集群分析法氮系物質顆粒物質
外文關鍵詞: MSL, SCA, nitrogen species, particulate matter
相關次數: 點閱:63下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 離島水庫的優養化程度高,相對的藻類濃度亦會高出不少,而金門的藻類濃度更是比其他離島高出五倍之多,金門的葉綠素平均濃度高達120μg/L,高藻類濃度的原水對水處理來說會造成很大的困難,不僅會造成處理成本的增加,也會使消毒副產物的生成風險增加,藻類的代謝物中藻毒會有影響民眾健康的疑慮,藻臭則會影響到適飲性的問題,因此,藻類濃度過高會對於民眾的飲水安全造成疑慮。
      複合濾料水質淨化系統(Multi-Soil-Layering, MSL)是一種源自於日本的土壤滲濾淨化系統,其將土壤與鐵、碳粉及有機質等複合濾料包覆在磚形土包內強化土壤的功能,並將土包以及經沸石所組成之透水層成層排列,目的在於改善傳統土壤滲濾容易造成阻塞的現象。相較於傳統之土壤滲濾系統,MSL能夠有著更高的水力負荷容忍度,且由於土包內之物質,能夠更有效的去除營養鹽,加強淨化之功能。本研究之MSL設立於金門小太湖旁,設有兩槽之MSL能夠分別以最大處理量6CMD進行操作,其進流水直接取自小太湖,經由MSL單元處理後再將出流水排入到小太湖中,以直接循環的方式操作。
      本研究在試驗期間對MSL採用不同的曝氣量以及水力負荷條件,再搭配上隨季節變化之環境條件,面對到高濃度藻類的原水進流,MSL系統能夠保持穩定的去除效果,但在各項水質數據原水濃度較高且沒有前處理的情況下,使得出流水質的濃度也會偏高。MSL在各季節當中對濁度及葉綠素濃度皆能有90%以上的去除效果,NPDOC濃度則受水力負荷及水溫的影響,但總體也有50%的去除率,至於氮系物質則有較明顯的變化,隨著試程的推進總氮的去除率越來越低,出流的濃度甚至高於進流濃度,為探討原因分別對有機氮、氨氮以及硝酸鹽氮進行分析,有機氮在各試程間皆有50%的去除率,而氨氮則是有著90%以上的去除效果,最後硝酸鹽氮則是明顯的有出流濃度大於進流濃度的狀況,因此硝酸鹽氮為導致總氮濃度增加的主因。
    本研究以逐步集群分析法(Stepwise Cluster Analysis, SCA)建立逐步集群推論模型(Stepwise Cluster Inference, SCI))探討導致硝酸鹽氮出流濃度增加的重要影響因子,選出重要因子依序為進流水葉綠素濃度、水力負荷、水溫、進流水pH及進流水硝酸鹽氮濃度,根據前述模式,本研究推測「大量藻類流入系統使過多含氮有機物、氨氮及硝酸鹽氮在系統累積;當水力負荷較大使停留時間縮短或水溫較低使生物活性降低時,系統脫硝作用趕不上硝酸鹽氮累積,導致出流水硝酸鹽氮濃度增加及pH降低」。情境分析結果顯示,在高負荷下,夏、冬季出流水硝酸鹽增加量為4.5及5.5 mg/L;在低負荷下,夏、冬季出流水硝酸鹽增加量為3.5及4.5 mg/L。
    研究發現小太湖大量藻體顆粒進入MSL系統會導致阻塞,阻塞發生時會明顯使葉綠素、濁度、NPDOC及TKN出流水質惡化。根據較高的出流水葉綠素與濁度,試程中可定義出兩次阻塞事件,並推測主要造成阻塞的原因為高水力負荷(>1000 L/m2/d)、高進流濁度(> 50 NTU)及高葉綠素(> 200 μg/L),當三種因素同時成立時可導致阻塞發生並使出流濁度大於25 NTU及出流葉綠素大於30 μg/L。本研究也發現,藻體造成的MSL阻塞可靠停止進流一段時間(停機操作)予以排除,停機1-2週後幾乎所有水質都可回復正常去除率,對出流水硝酸鹽氮增加的現象也有顯著改善,研判停機期間系統內可能有較強的脫硝作用處理累積的硝酸鹽氮。整體而言,本研究發現未經前處理之高藻類濃度原水會造成MSL氮系物質累積、有機顆粒阻塞並間接導致水質淨化效果下降,建議需監控出流水濁度與葉綠素濃度以調控水力負荷,並在每個水力負荷操作4個月後停機1-2週。

    Addressing the issue of water resources in remote islands, it is crucial to note that the high level of eutrophication in island reservoirs makes them unreliable as stable water sources. To tackle this problem, the Multi-Soil-Layering (MSL) technique has been adopted as a water purification system. MSL is a cost-effective and easily maintainable natural method. Leveraging the advantages of on-site demonstration fields, which effectively address seasonal variations in raw water quality, a comprehensive analysis of the MSL system's removal efficiency under different environmental conditions is conducted. The collected data is then subjected to Stepwise Cluster Analysis (SCA) to establish a model for identifying the factors contributing to variations of nitrogen species and particulate matter in outflow water concentrations. Based on the analysis results, the following operational recommendations can be provided.

    摘要 I 致謝 VI 目錄 VII 表目錄 XI 圖目錄 XIII 第1章 前言 1 1.1 研究動機 1 1.2 研究目的 4 1.3 論文架構 5 第2章 文獻回顧 6 2.1 離島水庫高濃度藻類原水 6 2.1.1 高濃度藻類原水造成之影響 7 2.1.2 高濃度藻類原水之解決辦法 9 2.2 土壤滲濾淨化系統 11 2.2.1 MSL工法、原理及機制 12 2.2.2 MSL與傳統土壤滲濾系統之比較 16 2.3 高濃度藻類原水對MSL去除效率及放流水質可能影響 17 2.3.1 藻體物理性阻塞 18 2.3.2 藻體有機物質累積 20 2.3.3 藻體造成之影響 22 2.3.4 微囊藻與柱胞藻及其代謝物 28 2.4 篩選重要因子之集群分析法 30 2.4.1 階層式集群分析法 31 2.4.2 逐步集群分析法 32 第3章 研究方法 33 3.1 研究地點 33 3.1.1 金門太湖水庫簡介 33 3.1.2 太湖水庫水質 34 3.2 MSL試驗模場 37 3.2.1 MSL試驗模場系統流程 38 3.2.2 模場結構 39 3.2.3 試程條件 42 3.3 藻毒及藻臭分析 44 3.3.1 酵素連結免疫吸附分析法(Enzyme-linked Immunosorbent Assay, ELISA) 44 3.3.2 藻臭分析方法 49 3.4 基本水質分析 52 3.5 逐步集群分析法 53 第4章 結果與討論 57 4.1 MSL模場水質淨化效果 57 4.1.1 金門小太湖原水水質 58 4.1.2 MSL各試程之水質變化 65 4.1.3 有機物質於MSL系統之變化 66 4.1.4 藻體顆粒於MSL之變化 68 4.1.5 氮系物質與溶氧於MSL之變化與影響 76 4.1.6 金門小太湖與澎湖成功水庫水質及去除效果之比較 86 4.1.7 小結 90 4.2 氮系物質出流水濃度預測模型建立 91 4.2.1 氮系物質決定因素 91 4.2.2 硝酸鹽氮SCI模型建立 92 4.2.3 情境分析 97 4.2.4 MSL操作條件與環境因子對硝酸鹽氮之影響 99 4.3 藻體阻塞對MSL系統之影響 100 4.3.1 阻塞期間MSL系統出流水質變化 102 4.3.2 小太湖MSL系統阻塞之因素 106 4.3.3 阻塞期間及停機後對氮系物質之影響 110 4.4 金門小太湖MSL系統操作建議 113 第5章 結論與建議 115 5.1 結論 115 5.2 建議 119 第6章 參考文獻 120 附錄 130 附錄一 小太湖原水水質數據 131 附錄二 MSL出流水質彙整 132 附錄三 MSL出流水質去除率彙整 134

    Adhurya, S., Das, S., & Ray, S. (2022). Nitrogen and phosphorous loading by aquatic avifauna in a shallow eutrophic freshwater lake. Energy, Ecology and Environment, 1-19.
    Attanandana, T., Luanmanee, S., Saitthiti, B., Panichajakul, C., & Wakatsuki, T. (2000). A Comparative study of zeolite with other materials as the components of the multi-soil-layering system for wastewater treatment. Soil science and plant nutrition, 2(2), 1-11.
    Bláha, L., Babica, P., & Marsálek, B. (2009). Toxins produced in cyanobacterial water blooms-toxicity and risks. Interdisciplinary toxicology, 2(2), 36.
    Bormans, M., Lengronne, M., Brient, L., & Duval, C. (2014). Cylindrospermopsin accumulation and release by the benthic cyanobacterium Oscillatoria sp. PCC 6506 under different light conditions and growth phases. Bulletin of environmental contamination and toxicology, 92, 243-247.
    Bouwer, E. J., Rijnaarts, H. H., Cunningham, A. B., & Gerlach, R. (2000). Biofilms in porous media. In.
    Carrera, J., Vicent, T., & Lafuente, J. (2004). Effect of influent COD/N ratio on biological nitrogen removal (BNR) from high-strength ammonium industrial wastewater. Process Biochemistry, 39(12), 2035-2041.
    Chen, X., Luo, A. C., Sato, K., Wakatsuki, T., & Masunaga, T. (2009). An introduction of a multi‐soil‐layering system: A novel green technology for wastewater treatment in rural areas. Water and Environment Journal, 23(4), 255-262.
    Chen, X., Sato, K., Wakatsuki, T., & Masunaga, T. (2007). Effect of aeration and material composition in soil mixture block on the removal of colored substances and chemical oxygen demand in livestock wastewater using multi-soil-layering systems. Soil science and plant nutrition, 53(4), 509-516.
    Chen, Y., Yu, S., Yang, J., Lin, Y., Hu, L., Xu, M., Shen, W., Chen, C., & Wei, G. (2002). Microcystins in drinking water and cancer mortality in a city along Taihu Lake. China, Oncology, 12, 485-488.
    Chiswell, R. K., Shaw, G. R., Eaglesham, G., Smith, M. J., Norris, R. L., Seawright, A. A., & Moore, M. R. (1999). Stability of cylindrospermopsin, the toxin from the cyanobacterium, Cylindrospermopsis raciborskii: Effect of pH, temperature, and sunlight on decomposition. Environmental Toxicology: An International Journal, 14(1), 155-161.
    Chorus, I., Falconer, I. R., Salas, H. J., & Bartram, J. (2000). Health risks caused by freshwater cyanobacteria in recreational waters. Journal of Toxicology and Environmental Health Part B: Critical Reviews, 3(4), 323-347.
    Chorus, I., Fastner, J., & Welker, M. (2021). Cyanobacteria and cyanotoxins in a changing environment: Concepts, controversies, challenges. Water, 13(18), 2463.
    Cooley, W., & Lohnes, B. (1971). PR Multivariate data analysis. Hoboken: Wiley.
    Downing, J. A., Watson, S. B., & McCauley, E. (2001). Predicting cyanobacteria dominance in lakes. Canadian Journal of Fisheries and Aquatic Sciences, 58(10), 1905-1908.
    Falconer, I., Bartram, J., Chorus, I., Kuiper-Goodman, T., Utkilen, H., Burch, M., & Codd, G. (1999). Safe levels and safe practices. Toxic cyanobacteria in water, 155-178.
    Falconer, I. R. (1996). Potential impact on human health of toxic cyanobacteria. Phycologia, 35(sup6), 6-11.
    Gülagiz, F. K., & Sahin, S. (2017). Comparison of hierarchical and non-hierarchical clustering algorithms. International Journal of Computer Engineering and Information Technology, 9(1), 6.
    Greeson, P. E. (1969). LAKE EUTROPHICATION–A NATURAL PROCESS 1. JAWRA Journal of the American Water Resources Association, 5(4), 16-30.
    Guan, Y., Zhang, Y., Zhong, C.-N., Huang, X.-F., Fu, J., & Zhao, D. (2015). Effect of operating factors on the contaminants removal of a soil filter: multi-soil-layering system. Environmental Earth Sciences, 74(3), 2679-2686. https://doi.org/10.1007/s12665-015-4288-8
    Hand, D. J. (2007). Principles of data mining. Drug safety, 30, 621-622.
    Hand, V. L., Lloyd, J. R., Vaughan, D. J., Wilkins, M. J., & Boult, S. (2008). Experimental studies of the influence of grain size, oxygen availability and organic carbon availability on bioclogging in porous media. Environmental science & technology, 42(5), 1485-1491.
    Hawkins, P. R., Runnegar, M. T., Jackson, A., & Falconer, I. (1985). Severe hepatotoxicity caused by the tropical cyanobacterium (blue-green alga) Cylindrospermopsis raciborskii (Woloszynska) Seenaya and Subba Raju isolated from a domestic water supply reservoir. Applied and environmental microbiology, 50(5), 1292-1295.
    He, X., de la Cruz, A. A., & Dionysiou, D. D. (2013). Destruction of cyanobacterial toxin cylindrospermopsin by hydroxyl radicals and sulfate radicals using UV-254 nm activation of hydrogen peroxide, persulfate and peroxymonosulfate. Journal of Photochemistry and Photobiology A: Chemistry, 251, 160-166.
    Healy, M. G., Rodgers, M., & Mulqueen, J. (2007). Treatment of dairy wastewater using constructed wetlands and intermittent sand filters. Bioresource technology, 98(12), 2268-2281.
    Ho, C.-C., & Wang, P.-H. (2015). Efficiency of a multi-soil-layering system on wastewater treatment using environment-friendly filter materials. International Journal of Environmental Research and Public Health, 12(3), 3362-3380.
    Hong, Y., Huang, G., An, C., Song, P., Xin, X., Chen, X., Zhang, P., Zhao, Y., & Zheng, R. (2019). Enhanced nitrogen removal in the treatment of rural domestic sewage using vertical-flow multi-soil-layering systems: Experimental and modeling insights. Journal of environmental management, 240, 273-284.
    Hou, C.-r., Hu, W., Jia, R.-B., & Liu, P.-Q. (2008). The mechanism of cyanobacterium (M. aeruginosa) microcystins releasing by chemical oxidation in drinking water treatment. 2008 2nd International Conference on Bioinformatics and Biomedical Engineering,
    Huang, G. (1992). A stepwise cluster analysis method for predicting air quality in an urban environment. Atmospheric Environment. Part B. Urban Atmosphere, 26(3), 349-357.
    Huang, G., Huang, Y., Wang, G., & Xiao, H. (2006). Development of a forecasting system for supporting remediation design and process control based on NAPL‐biodegradation simulation and stepwise‐cluster analysis. Water resources research, 42(6).
    Jacoby, J., Lynch, D., Welch, E., & Perkins, M. (1982). Internal phosphorus loading in a shallow eutrophic lake. Water Research, 16(6), 911-919.
    Jenssen, P., & Siegrist, R. (1990). Technology assessment of wastewater treatment by soil infiltration systems. Water Science and Technology, 22(3-4), 83-92.
    Jones, M. R., Pinto, E., Torres, M. A., Dörr, F., Mazur-Marzec, H., Szubert, K., Tartaglione, L., Dell'Aversano, C., Miles, C. O., & Beach, D. G. (2021). CyanoMetDB, a comprehensive public database of secondary metabolites from cyanobacteria. Water Research, 196, 117017.
    Juttner, F., & Watson, S. B. (2007). Biochemical and ecological control of geosmin and 2-methylisoborneol in source waters. Applied and environmental microbiology, 73(14), 4395-4406.
    Kanarek, A., & Michail, M. (1996). Groundwater recharge with municipal effluent: Dan region reclamation project, Israel. Water Science and Technology, 34(11), 227-233.
    Kemppainen, B. W., Reifenrath, W. G., Stafford, R. G., & Mehta, M. (1991). Methods for in vitro skin absorption studies of a lipophilic toxin produced by red tide. Toxicology, 66(1), 1-17.
    Khan, F. A., & Ansari, A. A. (2005). Eutrophication: an ecological vision. The botanical review, 71(4), 449-482.
    Knowles, P., Dotro, G., Nivala, J., & García, J. (2011). Clogging in subsurface-flow treatment wetlands: occurrence and contributing factors. Ecological Engineering, 37(2), 99-112.
    Kokociński, M., Gągała, I., Jasser, I., Karosienė, J., Kasperovičienė, J., Kobos, J., Koreivienė, J., Soininen, J., Szczurowska, A., & Woszczyk, M. (2017). Distribution of invasive Cylindrospermopsis raciborskii in the East-Central Europe is driven by climatic and local environmental variables. FEMS microbiology ecology, 93(4), fix035.
    Li, W., Liang, C., Dong, L., Zhao, X., & Wu, H. (2021). Accumulation and characteristics of fluorescent dissolved organic matter in loess soil-based subsurface wastewater infiltration system with aeration and biochar addition. Environmental Pollution, 269, 116100.
    Lin, J.-L., Hua, L.-C., Hung, S. K., & Huang, C. (2018). Algal removal from cyanobacteria-rich waters by preoxidation-assisted coagulation–flotation: effect of algogenic organic matter release on algal removal and trihalomethane formation. Journal of Environmental Sciences, 63, 147-155.
    Liu, Y., & Wang, Y. (1979). Application of stepwise cluster analysis in medical research. Scientia Sinica, 22(9), 1082-1094.
    Lu, C., Huang, G., Wang, X., & Liu, L. (2021). Ensemble projection of city-level temperature extremes with stepwise cluster analysis. Climate Dynamics, 56, 3313-3335.
    Luanmanee, S., Attanandana, T., Masunaga, T., & Wakatsuki, T. (2001). The efficiency of a multi-soil-layering system on domestic wastewater treatment during the ninth and tenth years of operation. Ecological Engineering, 18(2), 185-199.
    Luanmanee, S., Boonsook, P., Attanandana, T., Saitthiti, B., Panichajakul, C., & Wakatsuki, T. (2002). Effect of intermittent aeration regulation of a multi-soil-layering system on domestic wastewater treatment in Thailand. Ecological Engineering, 18(4), 415-428.
    Luanmanee, S., Boonsook, P., Attanandana, T., & Wakatsuki, T. (2002). Effect of organic components and aeration regimes on the efficiency of a multi-soil-layering system for domestic wastewater treatment. Soil science and plant nutrition, 48(2), 125-134.
    Masunaga, T., Sato, K., Zennami, T., Fujii, S., & Wakatsuki, T. (2003). Direct treatment of polluted river water by the multi-soil-layering method. Journal of Water and Environment Technology, 1(1), 97-104.
    Mays, D. C., & Hunt, J. R. (2007). Hydrodynamic and chemical factors in clogging by montmorillonite in porous media. Environmental science & technology, 41(16), 5666-5671.
    Mur, R., Skulberg, O. M., & Utkilen, H. (1999). CYANOBACTERIA IN THE ENVIRONMENT.
    Nie, J., Zhu, N., Zhao, K., Wu, L., & Hu, Y. (2011). Analysis of the bacterial community changes in soil for septic tank effluent treatment in response to bio-clogging. Water Science and Technology, 63(7), 1412-1417.
    Niu, Z.-G., Hu, X.-P., Zhang, Y., & Sun, Y.-Y. (2017). Effect of chlorine dosage in prechlorination on trihalomethanes and haloacetic acids during water treatment process. Environmental Science and Pollution Research, 24, 5068-5077.
    Pestana, C. J., Lawton, L. A., & Kaloudis, T. (2020). Removal and/or destruction of cyanobacterial taste and odour compounds by conventional and advanced oxidation processes. Water treatment for purification from Cyanobacteria and cyanotoxins, 207-230.
    Rao, C. R. (1952). Advanced statistical methods in biometric research.
    Rastogi, R. P., Sinha, R. P., & Incharoensakdi, A. (2014). The cyanotoxin-microcystins: current overview. Reviews in Environmental Science and Bio/Technology, 13, 215-249.
    Remesan, R., Bray, M., & Mathew, J. (2018). Application of PCA and Clustering Methods in Input Selection of Hybrid Runoff Models. Journal of Environmental Informatics, 31(2).
    Revelle, W. (1979). Hierarchical cluster analysis and the internal structure of tests. Multivariate Behavioral Research, 14(1), 57-74.
    Sander, J., Qin, X., Lu, Z., Niu, N., & Kovarsky, A. (2003). Automatic extraction of clusters from hierarchical clustering representations. Advances in Knowledge Discovery and Data Mining: 7th Pacific-Asia Conference, PAKDD 2003, Seoul, Korea, April 30–May 2, 2003 Proceedings 7,
    Sato, K., Iwashima, N., Wakatsuki, T., & Masunaga, T. (2011). Quantitative evaluation of treatment processes and mechanisms of organic matter, phosphorus, and nitrogen removal in a multi-soil-layering system. Soil science and plant nutrition, 57(3), 475-486.
    Sato, K., Masunaga, T., & Wakatsuki, T. (2005a). Characterization of treatment processes and mechanisms of COD, phosphorus and nitrogen removal in a multi‐soil‐layering system. Soil Science & Plant Nutrition, 51(2), 213-221.
    Sato, K., Masunaga, T., & Wakatsuki, T. (2005b). Water movement characteristics in a multi‐soil‐layering system. Soil Science & Plant Nutrition, 51(1), 75-82.
    Sato, K., Wakatsuki, T., Iwashima, N., & Masunaga, T. (2019). Evaluation of long-term wastewater treatment performances in multi-soil-layering systems in small rural communities. Applied and Environmental Soil Science, 2019.
    Sbahi, S., Ouazzani, N., Hejjaj, A., & Mandi, L. (2021). Nitrogen modeling and performance of multi-soil-layering (MSL) bioreactor treating domestic wastewater in rural community. Journal of Water Process Engineering, 44, 102389.
    Schopf, J. W. (1993). Microfossils of the Early Archean Apex chert: new evidence of the antiquity of life. Science, 260(5108), 640-646.
    Schwager, A., & Boller, M. (1997). Transport phenomena in intermittent filters. Water Science and Technology, 35(6), 13-20.
    Shrestha, S., & Kazama, F. (2007). Assessment of surface water quality using multivariate statistical techniques: A case study of the Fuji river basin, Japan. Environmental Modelling & Software, 22(4), 464-475.
    Siegrist, R. L. (1987). Soil clogging during subsurface wastewater infiltration as affected by effluent composition and loading rate (0047-2425).
    Siegrist, R. L., & Boyle, W. C. (1987). Wastewater-induced soil clogging development. Journal of environmental engineering, 113(3), 550-566.
    Smith, J. L., Boyer, G. L., & Zimba, P. V. (2008). A review of cyanobacterial odorous and bioactive metabolites: Impacts and management alternatives in aquaculture. Aquaculture, 280(1-4), 5-20.
    Song, P., Huang, G., Hong, Y., An, C., Xin, X., & Zhang, P. (2020). A biophysiological perspective on enhanced nitrate removal from decentralized domestic sewage using gravitational-flow multi-soil-layering systems. Chemosphere, 240, 124868.
    Stanier, R. Y., & Van Niel, C. (1962). The concept of a bacterium. Archiv für Mikrobiologie, 42, 17-35.
    Sun, W., Huang, G. H., Zeng, G., Qin, X., & Sun, X. (2009). A stepwise-cluster microbial biomass inference model in food waste composting. Waste management, 29(12), 2956-2968.
    Thurman, E. M. (2012). Organic geochemistry of natural waters (Vol. 2). Springer Science & Business Media.
    Van Apeldoorn, M. E., Van Egmond, H. P., Speijers, G. J., & Bakker, G. J. (2007). Toxins of cyanobacteria. Molecular nutrition & food research, 51(1), 7-60.
    Van Cuyk, S., Siegrist, R., Logan, A., Masson, S., Fischer, E., & Figueroa, L. (2001). Hydraulic and purification behaviors and their interactions during wastewater treatment in soil infiltration systems. Water Research, 35(4), 953-964.
    Wakatsuki, T., Esumi, H., & Omura, S. (1993). High performance and N & P-removable on-site domestic waste water treatment system by multi-soil-layering method. Water Science and Technology, 27(1), 31-40.
    Wang, X., Huang, G., Lin, Q., Nie, X., Cheng, G., Fan, Y., Li, Z., Yao, Y., & Suo, M. (2013). A stepwise cluster analysis approach for downscaled climate projection–A Canadian case study. Environmental Modelling & Software, 49, 141-151.
    Wang, X., Huang, G., Zhao, S., & Guo, J. (2015). An open-source software package for multivariate modeling and clustering: applications to air quality management. Environmental Science and Pollution Research, 22, 14220-14233.
    Wang, Y., Cai, Z., Sheng, S., Pan, F., Chen, F., & Fu, J. (2020). Comprehensive evaluation of substrate materials for contaminants removal in constructed wetlands. Science of The Total Environment, 701, 134736.
    Watson, S., Charlton, M., Rao, Y., Howell, T., Ridal, J., Brownlee, B., Marvin, C., & Millard, S. (2007). Off flavours in large waterbodies: physics, chemistry and biology in synchrony. Water Science and Technology, 55(5), 1-8.
    Watson, S. B. (2004). Aquatic taste and odor: a primary signal of drinking-water integrity. Journal of Toxicology and Environmental Health, Part A, 67(20-22), 1779-1795.
    Widrig, D. L., Gray, K. A., & McAuliffe, K. S. (1996). Removal of algal-derived organic material by preozonation and coagulation: monitoring changes in organic quality by pyrolysis-GC-MS. Water Research, 30(11), 2621-2632.
    Wiegand, C., & Pflugmacher, S. (2005). Ecotoxicological effects of selected cyanobacterial secondary metabolites a short review. Toxicology and applied pharmacology, 203(3), 201-218.
    Wilks, S. S. (1964). Mathematical statistics.
    Yang, Y., Yu, G., Chen, Y., Jia, N., & Li, R. (2021). Four decades of progress in cylindrospermopsin research: The ins and outs of a potent cyanotoxin. Journal of hazardous materials, 406, 124653.
    Yidong, G., Xin, C., Shuai, Z., & Ancheng, L. (2012). Performance of multi-soil-layering system (MSL) treating leachate from rural unsanitary landfills. Science of The Total Environment, 420, 183-190.
    Zhang, Y., Cheng, Y., Yang, C., Luo, W., Zeng, G., & Lu, L. (2015). Performance of system consisting of vertical flow trickling filter and horizontal flow multi-soil-layering reactor for treatment of rural wastewater. Bioresource technology, 193, 424-432.
    Zhong, C., Miao, D., & Fränti, P. (2011). Minimum spanning tree based split-and-merge: A hierarchical clustering method. Information Sciences, 181(16), 3397-3410.
    Zhou, X., Chen, Z., Li, Z., & Wu, H. (2020). Impacts of aeration and biochar addition on extracellular polymeric substances and microbial communities in constructed wetlands for low C/N wastewater treatment: Implications for clogging. Chemical Engineering Journal, 396, 125349.
    台灣行政院環保署. (1997). 飲用水水源水質標準.
    行政院環保署. (2022). 改善外島地區地面水體計畫-金門縣多層複合濾料(MSL)水質淨化試驗模場建置計畫書.
    邱鉑彥. (2019). 金門太湖淨水場奈濾(NF)薄膜處理成效.
    金門縣自來水廠. (2005). 94年度飲用水湖庫水體水質改善實場效能測試試驗計畫.
    金門縣環保局. (2008). 金門太湖、榮湖水庫污染整治規劃與初步設計計畫.
    郭上禎. (2021). 以複合濾料水質淨化系統現地處理優養化水庫總有機碳: 模場效能, 操作條件與淨化機制之研究
    黃志彬. (2012). 淨水場供水水質改善最適對策評估研究-以金門自來水廠為例.
    經濟部水利署. (2012). 淨水場供水水質改善最適對策評估研究-以金門自來水廠為例.
    劉峰瑋. (2022). 以複合濾料水質淨化系統現地處理優養化水庫水質: 淨水程序中的微生物組成與多樣性分析
    澎湖縣政府環境保護局. (2020). 澎湖縣環保統計通報. https://www.penghu.gov.tw/userfiles/146/files/108%E5%B9%B4%E5%BA%A6%E6%BE%8E%E6%B9%96%E7%B8%A3%E9%A3%B2%E7%94%A8%E6%B0%B4%E6%B0%B4%E8%B3%AA%E6%8A%BD%E9%A9%97%E6%A6%82%E6%B3%81.pdf
    澎湖縣環保局. (2017). 澎湖縣水庫水質治理方案.
    澎湖縣環保局. (2019a). 澎湖縣水庫水質治理方案.
    澎湖縣環保局. (2019b). 澎湖縣水質改善監測計畫期末報告.
    環境資訊中心(TEIA). (2011). 2011年9月25日聯合報金門報導:自來水有紅蟲,金門開戰2週應變. https://e-info.org.tw/node/70470

    無法下載圖示 校內:2028-08-10公開
    校外:2028-08-10公開
    電子論文尚未授權公開,紙本請查館藏目錄
    QR CODE