鋁金屬在自然環境中容易氧化而形成穩定的化合物型態存在，其八面體結構如屏障般保護鋁離子不被輕易破壞而保持一定的穩定性。為利用鋁離子與其他物質鍵結而普遍穩定存在的特性，本研究透過有機物與無機物的分別添加，測試於水溶液系統中，鋁離子與測試物種的反應性。第一部分的研究使用反丁烯二酸有機物與其反應生成富馬酸氫氧化鋁(Aluminum fumarate, A520)，目標引入流體化床均質顆粒化技術生產富馬酸氫氧化鋁顆粒，在一流體化床反應器單元中完成產物的合成、脫水與顆粒化，企圖取代傳統批次反應器的繁冗階段操作程序。在流體化床操作參數定在CAl,in= 1,800 mg-Al/L, CFum,in= 7,744 mg-Fum/L, pH= 3.80±0.10, QAl= QFum= 2.9 mL/min, QR= 50-150 mL/min, U= 6.5-25.5 m hr-1, HRT= 747 min, R.T.的操作條件下，合成出粒徑0.8-2.5 mm的富馬酸氫氧化鋁顆粒並透過固體材料分析，比較不同溫度下批次合成粉材與室溫下流體化床合成顆粒型態產物的區別，從晶型與官能基特徵分析確認目標產物的合成，而相對結晶度隨反應溫度提升而增進(28℃, 67%；75℃, 97%)，至於兩種反應器同在室溫下合成相比，顆粒化產物因反應時間較長，而有較佳的相對結晶度表現(流體化床, 79%；批次反應器, 67%)。在氮氣吸脫附表現方面，由於高溫反應有助於產物的自組裝排列，雖然在不同合成溫度下皆有特徵微孔結構，但在比表面積表現以高溫條件(95℃, 770 m2/g；28℃, 465 m2/g)較為優異，而顆粒化產品比表面積為458 m2/g。第二部分的研究使用鹼土族金屬與硫酸鋁溶液反應生成礬石產物，試驗了鎂、鈣、鍶、鋇等四種氫氧化物，測試與鋁離子的反應性，結果以鈣系最佳，在pHi= 12.5時，反應物莫耳比設定在[SO42-]/[Al3+]= 1.5, [Ca2+]/[Al3+]= 3的參數條件下，系統的鋁消耗率可達96.8%以上(鈣消耗率90.8%、硫酸根消耗率60-70%)，並生成鈣礬石產物。研究推測中間產物的穩定性是影響鋁離子消耗的因素之一，硫酸鹽化合物的形成為關鍵要素，需要鹼土元素先行與硫酸根結合後，再與離子水合型態的鋁反應生成鋁硫酸鹽產物，從結果統整，鎂系試驗在第一階段產生硫酸鎂化合物不足而無法進行第二階段的礬石生成反應，至於鍶、鋇元素雖然可以生成硫酸鹽類化合物，但在各鹼性條件下，穩定性佳，而無法進行第二階段以生成鋁硫酸鹽產物。

Metal aluminum is easily oxidized in the natural environment to have a stable compound form. Al-octahedral structure acts as a barrier to protect aluminum ions from being easily destroyed and maintain a certain stability. In order to take advantage of the stable feature of aluminum ion bonding with other substances, this research focuses on the interaction with different species.First study used fumarate acid to produce aluminum fumarate (A520) and concluded the higher amount of heat supplied, the bet-ter performance of crystallinity and surface area. Moreover, in order to develop a new process to get the A520 granule, we introduced the fluidized bed homogeneous granulation technology which simplified the current batch synthesis process. With the products analysis by different instruments, the physical properties of crystal phase, functional groups and surface area are similar. Further, the relative crystallinity degree of granule A520 (79%) is better than powder one (67%). The second study used alkaline earth elements such as Mg, Ca, Sr and Ba to react with aluminum sulphate. Based on the jar test results, the calcium-based is the best one with 96.8% consumed of aluminum ion under the optimal condition of pHi 12.5 . The information of analysis results indicated that the unstable sulfates formed under alkaline condition would lead to the generation of alum which caused the consumption of aluminum ions. Therefore, the poor formation of MgSO4 or the stable existence of SrSO4 and BaSO4 are not suitable for alum produced.

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