本實驗室多年來研究以自蔓延高溫燃燒合成法(簡稱SHS，又稱燃燒合成法)製備氮化鋁，此方法合成氮化鋁之可行性及難易度取決於鋁粉的粉坯體密度。先前本實驗室使用之原料主要為具特定大小之片狀鋁粉，片狀鋁粉具有較低之粉坯體密度與高孔隙度，在此條件下燃燒合成反應易於進行，且生成之產物具有高轉化率，在此之上並能更進一步發展量產技術。但此片狀鋁粉價格高、來源少，易有被壟斷之問題，因而認定其非為工業生產之首選。多數其他形狀之鋁粉，來源廣，價格亦較低廉，但是，大多數這些鋁粉粉坯體密度高、氮氣難以進入反應物內部，以致不易進行燃燒合成反應，也因此亦不易獲得高轉化率產物及建立量產技術。本研究以開發使用低價位鋁粉燃燒合成氮化鋁之技術為目標，透過混和價格低廉之片狀鋁粉與不規則形鋁粉能夠克服粉胚體密度高所導致燃燒合成不易進行之問題。吾人選用不規則形鋁粉與低價位片狀鋁粉為燃燒合成製備氮化鋁之原料，經由調整其混和比，探討其對燃燒反應狀況及產物轉化率的影響，藉此尋找最佳反應條件，並更近一步探討影響燃燒合成反應之因素，針對現有製程進一步改善。此外，吾人使用不同片狀鋁粉依不同比例混合探討對反應速度、產物形貌、粒徑及顏色的影響。

For many years, our laboratory has studied the preparation of aluminum nitride by self-propagating high-temperature combustion synthesis method (abbreviated as SHS, also known as combustion synthesis method). The feasibility and difficulty of synthesizing aluminum nitride by this method depend on the green density of aluminum powder. Previously, the raw materials used in this laboratory were mainly flaked aluminum powder with a specific size. The flaked aluminum powder has a lower powder green density and high porosity. Under these conditions, the combustion synthesis reaction is easy to proceed with, and the resulting product has a high conversion rate, above which mass production technology can be further developed. However, most of these aluminum powders have high green density, and difficult for nitrogen to enter the inside of the reactants, so that it is not easy to carry out combustion synthesis reactions, and therefore it is not easy to obtain a product with high conversion rates and establish the mass-production technology. This research aims to develop the technology of using low-cost aluminum powder to burn and synthesize aluminum nitride. By mixing low-cost flaked aluminum powder and irregular aluminum powder, it can overcome the problem that the high green density of the powder makes combustion synthesis difficult. We selected irregular-shaped aluminum powder and flaked aluminum powder as raw materials for the combustion synthesis of aluminum nitride, adjusted the mixing ratio, discussed the combustion reaction status and product conversion rate, and found the best reaction conditions. And further, study the factors that affect the reaction of combustion synthesis. In addition, we used different flaked aluminum powders mixed in different proportions to study the effect on reaction rate, product morphology, particle size, and color.

1. 林政曉. 燃燒合成氮化鋁粉體新方法與量產技術開發. 1999.

2. 蔡秉夆. 氮化鋁燃燒合成及後續製程開發. 國立成功大學碩士倫文 2020.

3. Robert. 使用球形鋁粉燃燒合成及量產氮化鋁製程開發 國立成功大學碩士論文 2019.

4. 汪建民. 陶瓷技術手冊Ceramic technology handbook 1994.

5. Sander HK. ”High-tech Ceramics”. C＆E News 1984.

6. 吳朗. 電子陶瓷-入門 1992: 1-2.

7. Sheppard LM. Aluminum nitride: a versatile bun challenging material. Am Ceram Soc Bull 1990, 69: 1801-1812.

8. Zakorzhevskii V, Borovinskaya I, Sachkova N. Combustion synthesis of aluminium nitride. Neorganicheskie Materialy 2002, 38(11): 1340-1350.

9. CRC Handbook of Chemistry and Physics 2016, 97th Edition: 4-45.

10. Morkoç H. Aluminum, Gallium, and Indium Nitrides. 2001: 121-126.

11. 周和平, 劉耀誠, 吴音. 氮化鋁陶瓷的研究與應用. 1998.

12. Elagin A, Beketov A, Baranov M, Shishkin R. Aluminum nitride. Preparation methods. Refractories and industrial ceramics 2013, 53(6): 395-403.

13. Watari T, Akizuki T, Ikeda H, Torikai T, Matsuda O. Shape of AlN Powders Prepared by Vapor Phase Reaction of AlCl3⋅ NH3-NH3-N2 System. Journal of the Ceramic Society of Japan 1989, 97(1128): 864-867.

14. Nickel KG, Riedel R, Petzow G. Thermodynamic and experimental study of high‐purity aluminum nitride formation from aluminum chloride by chemical vapor deposition. Journal of the American Ceramic Society 1989, 72(10): 1804-1810.

15. Riedel R, Gaudl KU. Formation and characterization of amorphous aluminum nitride powder and transparent aluminum nitride film by chemical vapor deposition. Journal of the American Ceramic Society 1991, 74(6): 1331-1334.

16. Maya L. Synthetic approaches to aluminum nitride via pyrolysis of a precursor. Adv Ceram Mater 1986, 1(2): 150-153.

17. Okada T, Toriyama M, Kanzaki S. Synthesis of aluminum nitride sintered bodies using the direct nitridation of Al compacts. Journal of the European Ceramic Society 2000, 20(6): 783-787.

18. Kuang J, Zhang C, Zhou X, Wang S. Synthesis of high thermal conductivity nano-scale aluminum nitride by a new carbothermal reduction method from combustion precursor. Journal of crystal growth 2003, 256(3-4): 288-291.

19. Bradshaw SM, Spicer JL. Combustion synthesis of aluminum nitride particles and whiskers. Journal of the American Ceramic Society 1999, 82(9): 2293-2300.

20. Chung S-L, Yu W-L, Lin C-N. A self-propagating high-temperature synthesis method for synthesis of AlN powder. Journal of materials research 1999, 14(5): 1928-1933.

21. Dunmead SD, Moore, W. G., Howard, K. E. & Morse, K. C. Google Patents 1997.

22. Merzhanov A, Borovinskaya I. Self-spreading high-temperature synthesis of refractory inorganic compounds. Doklady Akademii Nauk SSSR, Seriya Khimiya 1972, 204(2): 366-369.

23. Merzhanov AG. Self-propagating high-temperature synthesis: twenty years of search and findings. Combustion and plasma synthesis of high-temperature materials 1990: 1-53.

24. Khaikin B, Merzhanov A. Theory of thermal propagation of a chemical reaction front. Combustion, Explosion and Shock Waves 1966, 2: 22-27.

25. Gregorski SJ. High green density metal parts by vibrational compaction of dry powder in the three-dimensional printing process. 1996.

26. 康新婷, 蔣紀麟, 劉素英. 自蔓延高溫合成(SHS) TiN粉末的研究. 自蔓延高溫合成技術研究進展, 武漢工業大學出版社 1994.

27. 張學軍, 鄭永挺, 韓傑才, 周立娟. 稀釋劑含量對自蔓延高溫合成Si3N4-SiC-TiN 陶瓷的影響. 2006.

28. 江國健, 莊漢銳, 李文蘭, 鄔鳳英, 張寶林. 高壓氮氣中燃燒合成氮化鋁的機理研究 (1). 材料科學與工程學報 2000: 237-240.

29. Karpiński J, Porowski S. High pressure thermodynamics of GaN. Journal of crystal growth 1984, 66(1): 11-20.

30. Lee W-C, Tu C-L, Weng C-Y, Chung S-L. A novel process for combustion synthesis of AlN powder. Journal of materials research 1995, 10(3): 774-778.

31. Mukas' yan A, Martynenko V, Merzhanov A, Borovinskaya I, Blinov MY. Mechanism and principles of silicon combustion in nitrogen. Combustion, Explosion and Shock Waves 1986, 22(5): 534-540.

32. Munir ZA, Holt JB. The combustion synthesis of refractory nitrides. Journal of materials science 1987, 22(2): 710-714.

33. Merzhanov A, Borovinskaya I, Volodin YE. Combustion of porous metal samples in nitrogen: Inst. of Physical Chemistry, Moscow; 1972.

34. Eslamloo‐Grami M, Munir ZA. Effect of nitrogen pressure and diluent content on the combustion synthesis of titanium nitride. Journal of the American Ceramic Society 1990, 73(8): 2222-2227.

35. Pityulin A, Shcherbakov V, Borovinskaya I, Merzhanov A. Laws and mechanism of diffusional surface burning of metals. Combustion, Explosion and Shock Waves 1979, 15(4): 432-437.

36. Марков ЮМ, Латухин ЕИ. СВС нитрида алюминия с использованием активирующих добавок. Современные материалы, техника и технологии 2019(5 (26)).

37. Sheppard LM. Powders That" Explode" Into Materials. Adv Mater Process 1986, 2(2): 25-32.

38. Holt JB. Exothermic process yields refractory nitride materials. Ind Res Dev 1983, 25(4): 88.

39. Dunmead SD, Munir ZA, Holt JB. Gas-solid reactions under a self-propagating combustion mode. Solid State Ionics 1989, 32: 474-481.

40. Costantino M, Firpo C. High pressure combustion synthesis of aluminum nitride. Journal of materials research 1991, 6(11): 2397-2402.

41. 林俊男. 燃燒合成氮化鋁之製程開發. 國立成功大學博士論文 2001.

42. 張智偉. 燃燒法合成氮化鋁粉體之新製程開發. 國立成功大學碩士論文 2003.

43. 羅宇麟. 氮化鋁燃燒合成製程開發. 國立成功大學碩士倫文 2020.

44. 王唯侖. 氮化鋁/環氧樹脂複合材料之流變性及熱傳導性質探討. 國立成功大學碩士論文 2019.

45. Kasori M, Shinozaki K, Anzai K, Tsuge A, Imagawa H, Takano T, et al. Aluminum nitride sintered body, US5001089A. Google Patents 1989.

46. Long G, Foster L. Aluminum Nitride, a Refractory for Aluminum to 2000° C. Journal of the American Ceramic Society 1959, 42(2): 53-59.

47. Lihrmann JM, Zambetakis T, Daire M. High‐temperature behavior of the aluminum oxycarbide Al2OC in the system Al2O3–Al4C3 and with additions of aluminum nitride. Journal of the American Ceramic Society 1989, 72(9): 1704-1709.