研究生: |
吳中涵 Wu, Zhong-han |
---|---|
論文名稱: |
利用聚苯乙烯小球粗化垂直結構氮化鎵發光二極體表面以提升光輸出之研究 Surface Roughening using Polystyrene Spheres to Improve the Light Output of Vertical GaN-Based Light-Emitting Diodes |
指導教授: |
王水進
Wang, Shui-jinn |
學位類別: |
碩士 Master |
系所名稱: |
電機資訊學院 - 微電子工程研究所 Institute of Microelectronics |
論文出版年: | 2008 |
畢業學年度: | 96 |
語文別: | 中文 |
論文頁數: | 69 |
中文關鍵詞: | 聚苯乙烯小球 、氮化鎵發光二極體 |
外文關鍵詞: | GaN-Based Light-Emitting Diodes, polystyrene spheres |
相關次數: | 點閱:54 下載:1 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
為更進一步提升垂直結構氮化鎵系列發光二極體(LED)之發光效率,採用聚苯乙烯小球(Polystyrene spheres, PSs)鋪排於元件表面當作奈米等級的蝕刻光罩,再透過乾蝕刻的方式將圖樣轉移至n-GaN表面達到粗化的目的。實驗結果顯示,利用此一技術LED之光輸出功率(Light output power, LOP)於電流350 mA下可獲得36.82%之提升。
此外,本研究亦提出製作圖樣式銦鋅氧化物(patterned IZO)透明導電層之垂直結構LED。在先前實驗室已成功研製出具IZO透明導電層之高功率大面積垂直結構GaN-based LED,在光電特性上都有一定程度的改善,為了更進一步提升發光效率,製作出具有Patterned IZO透明導電層之垂直結構LED,同樣利用PSs當作奈米遮罩,沉積出凹凸狀的 IZO薄膜,由於凹凸狀的薄膜,使得光受到元件內部全反射機會減少,而與整面IZO透明導電層之垂直結構LED相比,光輸出功率增加19.4%。
Devices with a vertical structure would allow a much large power handling capability due to the immune of current crowding effect. In this study, Vertical-conducting Metal-substrate GaN-based Light-Emitting Diodes (VM-LEDs) were fabricated by using of nickel electroplating substrate transformation in conjunction with laser lift-off (LLO) technique. To further improve light output power of VM-LEDs, a cost-effective and efficient surface roughening technology using polystyrene spheres (PSs) as an etching mask was proposed and demonstrated. Experimental results revealed that the proposed structure could effectively enhance extraction for VM-LEDs. As compare to VM-LEDs of the same size (1000×1000 µm2), electrical characteristics of the fabricated devices are similar, but with an enhancement in light output power by 36.82% at 350 mA.
To further improve light output power of LEDs, an IZO layer with a patterned surface was also formed atop the LEDs by using the proposed PSs nano-mask process. As compare to VM-LEDs with IZO TCL but without PS patterning, typical improvement in light output power under an injection current of 350 mA by about 19.4% has been obtained.
1.Nick Holonyak, Jr. and S. F. Bevacqua, “COHERENT (VISIBLE) LIGHT EMISSION FROM Ga(As1–xPx) JUNCTIONS”, Appl. Phys. Lett., vol. 1, no. 82, Dec. 1962.
2.李季達,”北京奧運引發LED照明商機”,光連雙月刊,38期,2002。
3.J. K. Sheu, C. M. Tsai, M. L. Lee, S. C. Shei, and W. C. Lai, "InGaN light-emitting diodes with naturally formed truncated micropyramids on top surface", Appl. Phys. Letts., 88, pp. 113505-113507, 2006.
4.E. H. Park, I. T. Ferguson, S. K. Jeon, J. S. Park, T. K. Yoo, "InGaN-light emitting diode with high density truncated hexagonal pyramid shaped p-GaN hillocks on the emission surface", Appl. Phys. Letts, 89, pp. 251106-251108, 2006.
5.T. V. Cuong, H. S. Cheong, H. G. Kim, H. Y. Kim, C. H. Hong, E. K. Suh, H. K. Cho, and B. H. Kong, "Enhanced light output from aligned micropit InGaN-based light emitting diodes using wet-etch sapphire substrate patterning", Appl. Phys. Letts, 90, pp. 131107-131109, 2007.
6.C. H. Kuo, H. C. Feng, C. W. Kuo, C. M. Chen, L. W. Wu, and G. C. Chi, "Nitride-based near-ultraviolet light emitting diodes with meshed p-GaN", Appl. Phys. Letts, 90, pp. 142115-142117, 2007.
7.J. K. Sheu, Y. S. Lu, M. L. Lee, W. C. Lai, C. H. Kuo, and C, J. Tun, "Enhanced efficiency of GaN-based light-emitting diodes with periodic textured Ga-doped ZnO transparent contact layer", Appl. Phys. Letts, 90, pp. 263511-263513, 2007.
8.R. H. Horng, C. C. Yang, J. Y. Wu, S. H. Huang, C. E. Lee, and D. S. Wuu, "GaN-based light-emitting diodes with indium tin oxide texturing window layers using natural lithgraphy", Appl. Phys. Letts, 86, pp. 221101-221103, 2005.
9.C. H. Chan, C. C. Chen, C. K. Huang, W. H. Weng, H. S. Wei, H. Chen, H. T. Lin, H. S. Chang, W. Y. Chen, W. H. Chang, and T. M. Hsu, "Self-assembly free-standing photonic crystals ", Nanotechnology, 16, pp. 1440-1444, 2005.
10.李偉吉,”具IZO透明導電層之高功率大面積垂直結構GaN-基LEDs之研製”,國立成功大學微電子工程研究所碩士論文,2006。
11.楊於錚,”準分子雷射剝離技術應用於具鍍鎳金屬基板高功率垂直結構GaN基LEDs之研究”,國立成功大學微電子工程研究所碩士論文,2005。
12.W. S. Wong, T. Sands, and N. W. Cheung, “Damage-free separation of GaN thin films from sapphire substrates”, Appl. Phy. Letts, no. 5, Feb 2, pp. 599-601, 1998.
13.N. G. Basov, V. A. Danilychev, Y. M. Popov, and D. D. Khodkevich, “Laser operating in the vacuum region of the spectrum by excitation of liquid xenon with an electron beam”, J. of Experimental and Theoretical Physic Letters, Vol. 12, p.329, 1970.
14.S. Searles, G. Hart, “Stimulated emission at 281.8 nm from XeBr”, Appl. Phy. Letts, Vol. 27, p.243, 1975.
15.李永春,”準分子雷射細微加工機一般使用者訓練教材”,國立成功大學機械工程系,2004。
16.S. J. Wang, “Building Better LEDs from the Bottom up”, Photonics Spectra, p.109, Sep. 2005.
17.N. D. Denkov, O. D. Velev, P. A. Kralchevsky, I. B. Ivanov,H. Yoshimura and K. Nagayama; Langmuir 1992, 8, 3183-3190.
18.Takashi YAMASAKI, and Tetsuo TSUTSUI; Jpn. J. Appl. Phys. Vol.38(1999)pp. 5916-5921 Part 1, No. 10, October 1999.
19.Yadong Yin, Yu Lu, Byron Gates, and Younan Xia; J. Am. Chem.Soc. 2001, 123, 8718-8729.
20.Yadong Yin, Yu Lu, and Younan Xia; J. Am. Chem. Soc. 2001, 123,771-772.
21.J. Rybczynski, U. Ebels; Colloids and Surfaces A: Physicochem.Eng. Aspects 219 (2003) 1-6.
22.H. W. Choi, C. W. Jeon, and M. D. Dawson, “Tapered sidewall dry etching process for GaN and its applications in device fabrication”, J. Vac. Sci. Technol. B 23, Jan. 2005.
23.W. S. Wong, J. Krüger, Y. Cho, B. P. Linder, E. R. Weber, N. W. Cheung, and T. Sands, “Selective UV-laser processing for lift-off of GaN thin films from sapphire substrates”, in Proc. Symp. on Light Emitting Devices for Optoelectronic Applications and State-of-the-Art Program on Compound Semiconductors XXVIII, vol. 98-2, pp. 377-384, 1998.
24.楊忠諺、葉源益,”乾式蝕刻於矽微加工及微機電方面之應用”,毫微米通訊,8卷4期:11~17,2001。
25.吳晉坤,”銦鋅氧化物透明導電薄膜應用於高功率GaN基LED之研究”,國立成功大學微電子工程研究所碩士論文,2004。
26.A. Motayed, M. Jah, A. Sharma, W. T. Anderson,C. W. Litton, S. N. Mohammad, “Two-step surface treatment technique: Realization of nonalloyed low-resistance Ti/Al/Ti/Au ohmic contact to n-GaN”, Journal of Vacuum Science Technology, vol. 22, no. 2, Mar/Apr, pp. 663-667, 2004.
27.M. G. Craford, “Nanoscience and Solid State Lighting”, presented at Department of Energy Nanosummit, Washington D.C., 2004.