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研究生： 陳昱汎
Chen, Yu-Fan
論文名稱： 不同粉末製程與其前驅物對富鎳811單晶正極之結構與電化學性質之影響
Influence of Different Powder Processing and Precursors on Structural and Electrochemical Properties of Ni-rich 811 Single-Crystal Cathode
指導教授： 方冠榮
Fung, Kuan-Zong
學位類別： 碩士
Master
系所名稱： 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年： 2025
畢業學年度： 113
語文別： 英文
論文頁數： 65
中文關鍵詞： 鋰離子電池 、正極材料 、高鎳層狀結構 、固相反應法 、共沉法
外文關鍵詞： lithium ion battery, nickel-rich layered oxides, solid-state method, co-precipitation, crystallinity
相關次數： 點閱：6  下載：0 
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    • 中文摘要 I Abstract III Table of contents V List of figures VII List of Tables IX Chapter 1 Introduction 1 Chapter 2 Literature Review 3 2-1 Introduction to lithium-ion battery cathode materials 3 2-2 Traditional synthesis of nickel-rich layered oxides – Co-precipitation 4 2-3 LiNi0.8Co0.1Mn0.1O2 lithium nickel cobalt manganese oxides 10 2-4 The challenges for Ni-rich layered oxides 11 2-5 Single-crystal NMC and its importance 13 Chapter 3 Motivation and Objectives 15 Chapter 4 Experiment Procedures 17 4-1 Preparations of Ni-rich layered oxides 17 4-1-1 Poly-crystalline layered oxides using Co-precipitation 17 4-1-2 Single-crystalline layered oxides using Solid-state reaction 19 4-2 Characterization of Materials 20 4-2-1 X-ray diffraction analysis 20 4-2-2 X-ray photoelectron spectroscopy analysis 20 4-2-3 Scanning electron microscope analysis 20 4-3 Electrochemical characterization 21 4-3-1 Preparation of electrodes 21 4-3-2 Coin cell assembly 21 4-3-3 Galvanostatic charge-discharge test 22 Chapter 5 Results and discussion 23 5-1 Effect of synthesis route on Ni-rich layered oxides 23 5-1-1 Impact of different precursor on the crystallinity 23 5-1-2 Grain growth behavior within various synthesis route 26 5-1-3 Impact of calcination temperature on crystallinity 31 5-1-4 Charge-discharge Test 36 5-1-5 Summary 39 5-2 Influence of processing parameters with fixed grain size 40 5-2-1 Impact of processing parameters on microstructure 40 5-2-2 The differences on crystallinity within the fixed grain size 42 5-2-3 Charge-discharge analysis 44 5-2-4 Summary 46 Chapter 6 Conclusion 47 Reference 48

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