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研究生: 凃昇廷
Tu, Sheng-Ting
論文名稱: 超疏水性微結構的製造與應用
Manufacture and Application of a Hydrophobic Structure
指導教授: 李森墉
Lee, Sen-Yung
學位類別: 碩士
Master
系所名稱: 工學院 - 機械工程學系
Department of Mechanical Engineering
論文出版年: 2016
畢業學年度: 104
語文別: 中文
論文頁數: 110
中文關鍵詞: PDMS空氣彈簧蓮花效應仿生結構超疏水性太陽能電池
外文關鍵詞: PDMS, Air spring, Lotus effect, bionic structure, Super-hydrophobic, Solar cell
相關次數: 點閱:120下載:11
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  • 蓮花之仿生技術研究已經發展了許多年頭,現今長應用於衛浴用品、交通工具,以及玻璃清潔等等。其中研究者最常將微結構設計為凸柱狀,此類結構之接觸角以可達150°以上,已具有超疏水性,然而一直存在著耐久性差與不易大量生產之問題;奈米超疏水塗料亦長久存在著容易因摩擦而脫落之問題。
    本研究所設計出之具格狀半封閉微結構,藉由結構將空氣封閉住,以達空氣彈簧之效果,接觸角達160°以上,滑動角小於10°,具有極佳之自潔能力,並搭配材料之選擇使得結構強度大大提升。
    透過創新之母模具製造方式,使得小尺寸之模具能夠輕鬆且快速擴板至大尺寸,對於未來量產上大量模具之需求與降低成本有極大的幫助,得以走上大量生產之階段。
    本研究也將所設計之微結構樣本黏貼於太陽能電池,其介於空氣與電池間之折射率及結構捕光提升了太陽能電池之效率,高接觸角與低滑動角更讓太陽能電池有了一層抗汙層,避免灰塵堆積導致發電效率下降。

    The research of the lotus bionics has been developed several years and it has been applied to toiletries, transportation, and glasses cleaning nowadays. One of the structure usually designed in the form of pillar by researchers can reach over 150° of contact angle and featured super-hydrophobic. However, the bad permanence of the structure and the difficulty of producing have been problems for a long time. Furthermore, Nano-super hydrophobic coating is easy to peel off because of friction which is also a problem of the structure.

    The research designs the lattice semi-mural micro-structure, which can produce air spring by trapping air in the mural structure, and it has over 160° of contact angle, less than 10° of sliding angle, and the ability of self-cleaning. The materials we choose has strongly strengthened the structure.

    Through the innovative manufacturing method, the mold can be easily extended to the big size. It’s very helpful to deal with the requirement of large quantity of molds and reduce the cost which can lead to the mass production.

    This research also put the sample on the solar cell. It increases the efficiency of the solar cell by replenishing the light and index of refraction between air and solar cell. The high contact angle and low sliding angle let the solar cell has a protection of the pollution, preventing the solar cell become low efficiency from the accumulation of dust.

    摘要I 誌謝VI 目錄VII 表目錄XI 圖目錄XIII 符號XVIII 第一章 緒論1 1.1 前言 1 1.2 文獻回顧4 1.3 緒論總結9 第二章 基本理論與探討10 2.1 接觸角10 2.1.1 楊氏接觸角或本質接觸角12 2.1.2前進角與後退角12 2.1.3 滑動角14 2.1.4 接觸角遲滯值14 2.2 非理想表面之接觸角16 2.2.1 The Wenzel Model17 2.2.2 The Cassie-Baxter Model18 2.2.3 過渡狀態19 2.3 動態效應20 2.3.1 液滴撞擊的液滴形態的變化20 2.3.2 水滴撞擊微結構24 2.3.3 水滴撞擊微結構修正式 28 2.4 太陽能電池工作原理31 2.4.1 太陽光的頻譜照度31 2.4.2 太陽能電池電路模型32 第三章 實驗材料與方法35 3.1 實驗材料35 3.1.1 聚二甲基矽氧烷(PDMS)35 3.1.2 PET膜36 3.1.3 OCA膠36 3.2 實驗儀器37 3.2.1 接觸角量測儀37 3.2.2 影像高速攝影機38 3.2.3 UV-vis光譜儀39 3.2.4 太陽光模擬器40 3.2.5 平行曝光燈41 3.2.6 太陽能電池41 3.3 實驗方法43 3.3.1 實驗樣本製作43 3.3.2 靜態接觸角量測實驗53 3.3.3 前進角、後退角與滑動角量測實驗57 3.3.4 水滴撞擊樣本表面之動態量測實驗57 3.3.5 水滴撞擊樣本表面後之殘餘量量測實驗58 第四章 實驗結果與探討61 4.1 實驗樣本介紹 61 4.2 靜態接觸角、前進角、後退角量測實驗66 4.3 水滴撞擊樣本表面之動態量測實驗 73 4.3.1 水滴撞擊水平樣本表面73 4.3.2 水滴撞擊傾斜樣本表面81 4.3.3 水滴殘留量量測實驗84 4.4 光電效率量測 88 4.4.1多晶矽太陽能電池效率量測88 4.4.2染料敏化太陽能電池效率量測102 第五章 總結104 參考文獻106

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