金屬有機骨架（Metal−organic frameworks, MOFs）是一系列由金屬節點和有機連接器組成的奈米孔洞材料，其高比表面積與規律孔洞的特性能夠增加單位體積的電化學活性位點，進而提升電化學表現。然而大部分MOF缺乏水穩定性且幾乎是電的絕緣體，限制了MOF在水溶液中的電化學應用，透過安裝具氧化還原活性金屬離子在擁有水穩定性的MOF中，使其能應用於水相電化學。
因此，在本研究中，使用溶劑熱沉積法安裝具氧化還原活性鈷位點在以鋯為基底的金屬有機骨架-MOF-808，分散在MOF骨架中的鈷活性位點能以氧化還原躍遷的形式在骨架內傳遞電荷，藉此提升電化學表現並進行電化學感測過氧化氫，此外，以鈷為基底的材料也常被應用於電化學儲能，藉由滴落塗佈法最佳化工作電極上的薄膜厚度，得到最佳的儲能表現。分別對電化學感測過氧化氫以及儲能進行薄膜厚度的最佳化，結果顯示薄膜過厚不利於感測，層數過低不適合用於儲能。

In this thesis, a water-stable zirconium-based metal−organic frameworks (MOF), MOF-808, is utilized to immobilize the spatially separated redox-active cobalt sites by using a self-limiting solvothermal deposition in MOFs (SIM) technique in order to render the electronic transport during the electrochemical reactions through redox hopping. The redox-active cobalt sites installed within the Zr-MOF can not only facilitate charge transport in the framework, but also act as the active sites for the electrochemical H2O2 sensors and the active material for electrochemical energy storage in aqueous electrolytes. The cobalt-decorated MOF-808 (Co-MOF-808) thin films with various thicknesses were then fabricated, and the effects of thin-film thickness on both the performances in electrochemical sensors and energy storage are investigated. The high thin-film thickness with increased redox-active cobalt sites is more appropriate for electrochemical energy storage, but it may hinder the diffusion of the analyte, making it unsuitable for electrochemical sensing. The findings here suggest that the thin-film thickness affects significantly for achieving desired performances in certain electrochemical applications.

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