碳/碳複合材料（Carbon/Carbon Composite，C/C）為碳纖維強化碳基材複合材料（carbon fiber-reinforced carbon matrix composite）的簡稱，其具有高比強度、質輕的特性。在適當的保護氣氛下，即使在高溫的使用環境仍能保有傑出的機械強度，且製成的零件重量遠比其他材料如鋼鐵、鈹合金等為輕(理論密度約2.2g/cm3)。因為這些獨特的性質，碳/碳複合材料被視為製作飛機煞車的最佳材料之一。

　　本研究藉由改變基材材料與加入添加物的方式製備碳/碳複合材料，討論不同基材與添加物經快速碳化製備之碳/碳複合材料的磨耗性質之影響。研究結果發現以乾粉酚醛樹脂為基材之磨耗量較液態酚醛樹脂為基材的碳/碳複合材料有大幅度的改善，其中又以加入添加物II5vol%兼具低磨耗量及較穩定的摩擦係數。

　　Carbon fiber-reinforement carbon matrix composite is called Carbon/Carbon composite(C/C) which has properties such as high ratio strength and low density。Under proper atmosphere，C/C has excellent mechanical strength even if using in high temperature and it’s much more light than sections made by steel and beryllium alloys(theoretical density=2.2g/cm3) 。For these unique properties，C/C is one of the best materials of aircraft brake disk。

　　The study discusses the influence of properties of wear with C/C fabricated by faster carbonization rate and by changing matrix and additions. The investigate concludes that the wear lost in novalac-type resin is less than in resol-type resin and the most improving is using 5vol% addition II.

1. Vohler, O. and Fiter, E. Jahrbuch der Wissenschaftlichen Grsrllschaft fur Luftfahrtt e.v. WGL, pp. 467~473,(1961)

2. D.L.Schmidt, Sampe J.8,9.(1972)

3. G. Savage, “Carbon-Carbon composites”, Chapman and Hall London,1993.

4. 許明發，碳/碳纖維/碳-碳複合材料之加工技術與應用，滄海書局，1997年.

5. E.FITZER, L.M.Manocha, “Carbon reinforcements and carbon/carbon composites”, 1997.

6. Christopher Byrne*, Zhiyuan Wang Influence of thermal propertoes on friction performance of carbon composites, Carbon 39 (2001) 1789-1801.

7. John D Buckley and Dan D. Edie, Carbon-Carbon Materials and Composites.

8. C.P.Ju, W.T.Tsai, “A Review on Microstructure and Interfaces of Carbon-Carbon Composites”,Chinese Journal of Materials Science Vol.22,No.2,(1990),98-111.

9. C.P.Ju, J.Don and P.Tlomak., “TEM study of 3-D PAN-Fiber-Mesophase Pitch matrix Carbon-Carbon Composite”,J.Mat.Sci,26,(1991),6753-6758.

10.Soo-Jin Park, Min-Seok Cho, “Effect of anti-oxidative filler on the interfacial mecganial properties of carbon-carbon composites measured at high temperature”, Carbon 38(2000)1053~1058.

11.Geroge Lubin, “Handbook of composite”,(1982)

12.J.D.H.Hughes, “Strength and Modulus of Current Carbon Fibers”, Carbon, vol.24, No.5,(1986)551~556.

13.稻桓道夫，大谷杉郎，大谷朝男 共着，賴耿陽 編著，”碳材料碳纖維工學”，復漢出版社印行，(1986)

14.S.C.Bennett and D.J.Johnson, “Electron-Microscope Studies of Structure Heterogeneity In PAN-Based Carbon Fibers”, Carbon, Vol.17, No.2, 25~39(1979)

15.Tse-Hao Ko and Tsu-Sheng Ma, “Effect of post-curing on
the mechanical properties of carbonized phenolic resins”, Polymer composites, 1998, vol. 19, No4.

16.Tse-Hao Ko, Ping-Chein Chen, Journal of materials science letters10, (1991)301-303.

17.Z.Lausevic and S. Marinkovic, Carbon vol. 24, No.5, pp. 575~580, 1986.

18.Jae-Do.Nam. and James C. Seferis*, Carbon. vol. 30, No.5, pp. 751~761, 1992.

19.Shinn-Shyong Tzeng*, Ya-Ga Chr, Materials chemistry and physics 73 (2002)162~169.

20.Y. Yamashita and K. Ouchi, Carbon 19, 89(1981).

21.Yasuda E, Tanabe Y, Manocha LM, Kimura S(1988) Carbon 26
p225

22.Effect of processing variables on the properties of carbon-carbon composites.

23.D.F.Moore,”Principles and Application of Tribology”,International Series on Material Science and Technology Volume14,(1975),3~4.

24.Kenneth G. Budinski,”Surface Engineering for Wear Resistance”, Prentice Hall. Englewood Cliffs, New Jersey,(1988).

25.N.P.Suh,”Tribophysics”, Prentice Hall ,Inc., Englewood Cliffs, New Jersey,(1986),1-3.

26.S. Awasthi, J.L. Wood, Adv. Ceram. Mater. 3 (1988) 449.

27.S. Awasthi, J.L. Wood,”C/C Composite Material for Aircraft Brakes”,Ceram. Eng. Sci. Proc. 9(1988) 553-560.

28.S. Kimura, E. Yasuda, N. Narita, J. JSLE. 28 (1983) 185.

29.S. Kimura, E. Yasuda, N. Narita, JSLE. Int. Ed. 5(1984)11-16.

30.K. J. Lee, H. H. Kuo, J. H. Chern Lin, C. P. Ju, Materials Chemistry and Physics 57 (1999) 244-252.

31.C. P. Ju, K. J. Lee, H. D. Wu, C.I. Chen, Carbon 32 (1994) 971.

32.J. D. Chen, C. P. Ju, Wear 174 (1994) 129.

33.J. D. Chen, C. P. Ju, Carbon 33 (1995) 57.

34. J. D. Chen, J. H. Chern Lin, C.P Ju, J. Mater. Sci. 31 (1996) 1221.

35.N. Muride, C. P. Ju, J. Don and F. A. Fortunato, Carbon 29 (1991), 335-342.

36.陳金多”碳/碳複合材料等速磨潤性質研究”，國立成功大學博士論文，(1995).