簡易檢索 / 詳目顯示

研究生: 卡穆仁
Kamran Raza
論文名稱: 應用大氣常壓非熱電漿去除乾燥菊花殘留之農藥
Mitigation of agrochemical residues from the dried Chrysanthemum morifolium using atmospheric pressure non-thermal plasma.
指導教授: 陳秀玲
Chen, Hsiu-Ling
學位類別: 碩士
Master
系所名稱: 醫學院 - 食品安全衛生暨風險管理研究所
Department of Food Safety / Hygiene and Risk Management
論文出版年: 2021
畢業學年度: 109
語文別: 英文
論文頁數: 90
中文關鍵詞: 乾燥菊花非熱電漿電漿活化水農藥減少
外文關鍵詞: Dry Chrysanthemum, Nonthermal Plasma, Plasma activated water, agrochemicals, mitigation
相關次數: 點閱:34下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 乾燥菊花是一種非常受歡迎的傳統藥物和著名的藥草茶。然而,由於其氣候不耐受和香氣,它很容易受到真菌和昆蟲的侵襲。因此,為了減少損害,農民有時會使用農藥。因此,這些農藥的殘留不僅會危害消費者,還會危害環境。電漿活化水(plasma activated water, PAW) 已被證實是一種能在不影響樣品品質的情況下降解特定農用化學品殘留物的新方法,在本研究中,使用PAW與非熱大氣空氣等離子體 (Non-thermal plasma, NTP) 直接處理兩種方法,處理受滅必(metribuzin)和畢達本(pyridaben)兩種農藥之乾菊花,目的是盡量減少其在菊花產品上的殘留。在經過PAW分別處理2、3和4分鐘後,滅必淨分別減少了11、13和 19%,而畢達本則減少8、11和15%,此兩種農藥之降解效率皆低於前人的研究;此外,如同先前的研究結果,NTP直接在200W下處理菊花5和10分鐘後,依然無法達到農用化學品去除之目的。PAW的pH值低於RO水,但它們的導電度 (Electrical conductivity, EC)和氧化還原值 (Oxidation Reduction Potential, ORP)數值更高。最後,本研究發現兩種 NTP處理方式(PAW 和直接處理)後之菊花的總酚含量(Total Phenolic content, TPC)、總黃酮含量(Total Flavonoid content, TFC)和抗氧化能力沒有顯著變化,但是經過PAW 處理後,菊花花瓣的顏色稍有變化。非熱電漿(NTP) 處理(PAW 或直接處理)皆不會對菊花品質產生負面影響,結果顯示整體而言,雖然效果並不顯著,PAW依然能夠降解兩種農藥,反之,非熱電漿(NTP)直接處理則無法有效使農藥降解。

    Dry Chrysanthemum is a very popular traditional medicine and famous herbal tea. However, due to its climate intolerance and aroma, it is vulnerable to fungus and insect attacks. Thus, to reduce damages, farmers sometimes use agrochemicals (pesticides). Therefore, the residues of these agrochemicals harm not only consumers but also the environment. Non-thermal Plasma treatment (PAW treatment & Direct treatment with NTP) been demonstrated to be a novel method for the degradation of these agrochemical residues without compromising the quality of the treated samples. In this research, metribuzin and pyridaben contaminated dry Chrysanthemum were treated with nonthermal plasma (NTP) such as PAW and direct treatment with the goal of minimizing their residues on Chrysanthemum. The findings revealed that the degradation efficiency of both pesticides was very low or not achieved compared to prior research. After 120, 180, and 240 second of PAW treatment, metribuzin reductions (%) were 11, 13, and 19%, respectively, whereas pyridaben reductions (%) were 8%, 11%, and 15%. The NTP direct treatment of Chrysanthemum at 200W for 5 and 10 minutes did not result in any pesticide reduction, as previously shown in investigations. PAWs had a lower pH than RO water, but their EC and ORP were higher. Finally, the TPC, TFC, and antioxidant capabilities of Chrysanthemum following both NTP treatments (PAW & direct) did not reveal any significant changes. However, after the PAW treatment, the colour of the flowers changed slightly. Overall, PAW treatment was able to degrade both pesticide residues even at lower levels, whereas direct NTP treatment did not degrade either pesticide residue. Furthermore, neither NTP treatments (PAW nor Direct treatment) had a negative effect on Chrysanthemum quality.

    ABSTRACT (摘要) I ABSTRACT II ACKNOWLEDGEMENT III TABLE OF CONTENTS IV LIST OF FIGURES VI LIST OF TABLES VII LIST OF SYMBOLS & ABBREVIATION VIII CHAPTER: 1 INTRODUCTION 1 1.1 RESEARCH BACKGROUND 1 1.2 RESEARCH MOTIVATION AND OBJECTIVES 2 CHAPTER: 2 REVIEW OF LITERATURE 3 2.1 CHRYSANTHEMUM MORIFOLIUM RAMAT 4 2.1.1 General 4 2.1.2 CMR cultivation in Taiwan and China 5 2.1.3 Dietary usage and TCM application 6 2.1.4 Agrochemicals application during CMR Farming 7 2.1.5 Quality and safety issue of Chrysanthemum Tea 8 2.2 AGROCHEMICALS: THEIR USES AND POTENTIAL HEALTH RISKS 9 2.3 CONVENTIONAL AND NON-CONVENTIONAL METHODS OF PESTICIDES REMOVAL 11 2.4 INTRODUCTION TO PLASMA CHEMISTRY: SOURCES AND TYPES 18 2.5 NON-THERMAL PLASMA: APPLICATION IN AGRICULTURE AND FOOD PROCESSING INDUSTRY 19 2.6 PESTICIDE DEGRADATION BY NONTHERMAL PLASMA 20 2.7 MECHANISM OF ACTION OF NONTHERMAL PLASMA 22 2.8 FACTORS INFLUENCING THE PESTICIDES DEGRADATION ACTIVITY OF NONTHERMAL PLASMA 31 2.8.1 Nonthermal Plasma: Processing equipment and conditions 31 2.8.2 Characteristics of Food products 35 2.8.3 Characteristics of pesticides 36 2.8.4 Pesticide contamination level 37 2.9 IMPACT OF NON-THERMAL PLASMA ON FOOD PRODUCTS 38 2.9.1 Physical Qualities 39 2.9.2 Chemical Qualities 41 2.10 POSSIBLE HARM CAUSED BY NTP TO THE HUMAN HEALTH 46 2.11 NTP APPLICATION CHALLENGES FOR PESTICIDE REMOVAL FROM FOODSTUFFS 47 2.12 CONCLUSION AND FUTURE SCOPE 48 CHAPTER: 3 MATERIALS AND METHODS 49 REAGENT AND MATERIALS 51 3.1 EXPOSURE OF DRY CHRYSANTHEMUM TO PESTICIDES 51 3.2 GENERATION OF PAW AND PAW TREATMENT 52 3.3 NONTHERMAL PLASMA DEVICE AND DIRECT TREATMENT 54 3.4 EXTRACTION PROCEDURE FOR PESTICIDE RESIDUES ANALYSIS 54 3.5 UPLC-MS ANALYSIS OF PESTICIDES 55 3.6 MATRIX MATCHED CALIBRATION CURVE 56 3.7 QUALITY ASSURANCE (QA) & QUALITY CONTROL (QC) 57 3.8 PESTICIDE REMOVAL EFFICIENCY 58 3.9 TPC AND TFC, DETERMINATION 59 (a) Extraction 59 (b) Total Phenolic Content (TPC) 59 (c) Total Flavonoids Content (TFC) 59 3.10 ANTIOXIDANT ACTIVITY DETERMINATION 60 3.10.1 DPPH Scavenging Power 60 3.10.2 Metal Chelating Ability 60 CHAPTER: 4 RESULTS AND DISCUSSION 61 4.1 PESTICIDE IDENTIFICATION 61 4.2 PHYSICOCHEMICAL PROPERTIES OF PAW 64 4.3 REMOVAL EFFICIENCY OF AGROCHEMICAL RESIDUES 67 4.4 EFFECT OF NONTHERMAL PLASMA ON THE CHRYSANTHEMUM QUALITIES 72 4.5 DISCUSSION 78 CHAPTER: 5 CONCLUSION AND FUTURE WORK 80 5.1 CONCLUSION 80 5.2 SUGGESTION 81 5.3 LIMITATION 81 CHAPTER: 6 REFERENCES 83 CHAPTER: 7 APPENDIX 90 APPENDIX-I: DRIED CHRYSANTHEMUM FLOWER BEFORE(A) AND AFTER (B) THE PESTICIDES SPIKE. 90 APPENDIX-II: DIRECT TREATMENT OF DRIED CHRYSANTHEMUM FLOWER NTP. 90

    Acoglu B, Omeroglu PY. Effectiveness of different type of washing agents on reduction of pesticide residues in orange (citrus sinensis), LWT 147:111690, 2021.
    Ali M, Cheng J-H, Sun D-W. Effect of plasma activated water and buffer solution on fungicide degradation from tomato (solanum lycopersicum) fruit, Food Chemistry 350:129195, 2021a.
    Ali M, Cheng JH, Sun DW. Effects of dielectric barrier discharge cold plasma treatments on degradation of anilazine fungicide and quality of tomato (lycopersicon esculentum mill) juice, International Journal of Food Science & Technology 56:69-75, 2021b.
    Anderson N. Reclassifications of the genus chrysanthemum l, HortScience (USA), 1987.
    Bai Y, Chen J, Mu H, Zhang C, Li B. Reduction of dichlorvos and omethoate residues by o2 plasma treatment, Journal of agricultural and food chemistry 57:6238-6245, 2009.
    Bai Y, Chen J, Yang Y, Guo L, Zhang C. Degradation of organophosphorus pesticide induced by oxygen plasma: Effects of operating parameters and reaction mechanisms, Chemosphere 81:408-414, 2010.
    Baudry J, Assmann KE, Touvier M, Allès B, Seconda L, Latino-Martel P, et al. Association of frequency of organic food consumption with cancer risk: Findings from the nutrinet-santé prospective cohort study, JAMA internal medicine 178:1597-1606, 2018.
    Bhilwadikar T, Pounraj S, Manivannan S, Rastogi N, Negi P. Decontamination of microorganisms and pesticides from fresh fruits and vegetables: A comprehensive review from common household processes to modern techniques, Comprehensive reviews in food science and food safety 18:1003-1038, 2019.
    Boehm D, Heslin C, Cullen PJ, Bourke P. Cytotoxic and mutagenic potential of solutions exposed to cold atmospheric plasma, Scientific reports 6:1-14, 2016.
    Bourke P, Ziuzina D, Boehm D, Cullen PJ, Keener K. The potential of cold plasma for safe and sustainable food production, Trends in biotechnology 36:615-626, 2018.
    Bußler S. Cold atmospheric pressure plasma treatment of food matrices: Tailored modification of product properties along value-added chains of plant and animal related products:Leibniz-Institut für Agrartechnik und Bioökonomie eV, 2017.
    Calvo H, Redondo D, Remón S, Venturini ME, Arias E. Efficacy of electrolyzed water, chlorine dioxide and photocatalysis for disinfection and removal of pesticide residues from stone fruit, Postharvest biology and technology 148:22-31, 2019.
    Cengiz MF, Başlar M, Basançelebi O, Kılıçlı M. Reduction of pesticide residues from tomatoes by low intensity electrical current and ultrasound applications, Food chemistry 267:60-66, 2018.
    Chen F, Zeng L, Zhang Y, Liao X, Ge Y, Hu X, et al. Degradation behaviour of methamidophos and chlorpyrifos in apple juice treated with pulsed electric fields, Food Chemistry 112:956-961, 2009.
    Chen L, Kotani A, Kusu F, Wang Z, Zhu J, Hakamata H. Quantitative comparison of caffeoylquinic acids and flavonoids in chrysanthemum morifolium flowers and their sulfur-fumigated products by three-channel liquid chromatography with electrochemical detection, Chemical and Pharmaceutical Bulletin 63:25-32, 2015.
    Choi JH, Han I, Baik HK, Lee MH, Han D-W, Park J-C, et al. Analysis of sterilization effect by pulsed dielectric barrier discharge, Journal of electrostatics 64:17-22, 2006.
    Chowdhury M, Jahan I, Karim N, Alam MK, Rahman MA, Moniruzzaman M, et al. Determination of carbamate and organophosphorus pesticides in vegetable samples and the efficiency of gamma-radiation in their removal, BioMed Research International 2014, 2014.
    Chu Q, Fu L, Guan Y, Ye J. Determination and differentiation of flos chrysanthemum based on characteristic electrochemical profiles by capillary electrophoresis with electrochemical detection, Journal of agricultural and food chemistry 52:7828-7833, 2004.
    Ciarrocchi IR, Mendes KF, Pimpinato RF, Spoto MHF, Tornisielo VL. The effect of radiation in the degradation of carbendazim and azoxystrobin in strawberry, Radiation Physics and Chemistry 179:109269, 2021.
    Commission CP. Pharmacopoeia of the people’s republic of china, vol. 1, Chinese Medical Science and Technology Press, Beijing, China:292, 2010.
    Cong L, Huang M, Zhang J, Yan W. Effect of dielectric barrier discharge plasma on the degradation of malathion and chlorpyrifos on lettuce, Journal of the Science of Food and Agriculture 101:424-432, 2021.
    de Souza LP, Faroni LRDA, Heleno FF, Pinto FG, de Queiroz MELR, Prates LHF. Ozone treatment for pesticide removal from carrots: Optimization by response surface methodology, Food chemistry 243:435-441, 2018.
    Domonkos M, Tichá P, Trejbal J, Demo P. Applications of cold atmospheric pressure plasma technology in medicine, agriculture and food industry, Applied Sciences 11:4809, 2021.
    Dorraki N, Mahdavi V, Ghomi H, Ghasempour A. Elimination of diazinon insecticide from cucumber surface by atmospheric pressure air-dielectric barrier discharge plasma, Biointerphases 11:041007, 2016.
    EPA. Exposure assessment tools by chemical classes - pesticides. Available: https://www.epa.gov/expobox/exposure-assessment-tools-chemical-classes-pesticides, 2021.
    Estarabadi H, Atyabi SA, Tavakkoli S, Noormohammadi Z, Gholami MR, Ghiaseddin A, et al. Cold atmospheric plasma induced genotoxicity and cytotoxicity in esophageal cancer cells, Molecular biology reports 48:1323-1333, 2021.
    Feng X, Ma X, Liu H, Xie J, He C, Fan R. Argon plasma effects on maize: Pesticide degradation and quality changes, Journal of the Science of Food and Agriculture 99:5491-5498, 2019.
    Fridman A. Plasma chemistry. In: Plasma chemistry:Cambridge university press, 1-7, 2008.
    Gavahian M, Chu Y-H, Khaneghah AM, Barba FJ, Misra N. A critical analysis of the cold plasma induced lipid oxidation in foods, Trends in Food Science & Technology 77:32-41, 2018.
    Gavahian M, Khaneghah AM. Cold plasma as a tool for the elimination of food contaminants: Recent advances and future trends, Critical reviews in food science and nutrition 60:1581-1592, 2020.
    Gavahian M, Meng‐Jen T, Khaneghah AM. Emerging techniques in food science: The resistance of chlorpyrifos pesticide pollution against arc and dielectric barrier discharge plasma, Quality Assurance and Safety of Crops & Foods 12:9-17, 2020a.
    Gavahian M, Pallares N, Al Khawli F, Ferrer E, Barba FJ. Recent advances in the application of innovative food processing technologies for mycotoxins and pesticide reduction in foods, Trends in Food Science & Technology, 2020b.
    Grill A. Cold plasma in materials fabrication:IEEE Press, New York, 1994.
    Gupta RC, Mukherjee IRM, Doss RB, Malik JK, Milatovic D. Organophosphates and carbamates. In: Reproductive and developmental toxicology:Elsevier, 609-631, 2017.
    Hassaan MA, El Nemr A. Pesticides pollution: Classifications, human health impact, extraction and treatment techniques, The Egyptian Journal of Aquatic Research, 2020.
    Hassan H, Abd El Raof AE, Salman S. Coupling between laser irradiation and tio2 nanoparticles on efficient decontamination of some pesticide's residues from orange and tomato puree, Egyptian Journal of Chemistry 64:3-8, 2021.
    He J, Evans NM, Liu H, Zhu Y, Zhou T, Shao S. Uv treatment for degradation of chemical contaminants in food: A review, Comprehensive Reviews in Food Science and Food Safety 20:1857-1886, 2021.
    Hendriadi A, Sulistiyorini S, Devilana MR. Pesticides residues in fresh food of plant origin: Study case in indonesia, Agrivita 43:285, 2021.
    Heo NS, Lee M-K, Kim GW, Lee SJ, Park JY, Park TJ. Microbial inactivation and pesticide removal by remote exposure of atmospheric air plasma in confined environments, Journal of bioscience and bioengineering 117:81-85, 2014.
    Hertwig C, Leslie A, Meneses N, Reineke K, Rauh C, Schlüter O. Inactivation of salmonella enteritidis pt30 on the surface of unpeeled almonds by cold plasma, Innovative food science & emerging technologies 44:242-248, 2017.
    Hu C. Dietary chinese herbs. In: Springer2015, (Liu Y, Wang Z, Zhang J, eds), 688, 2015.
    Hu Y, Bai Y, Li X, Chen J. Application of dielectric barrier discharge plasma for degradation and pathways of dimethoate in aqueous solution, Separation and purification technology 120:191-197, 2013.
    Hüppe R, Zander K. Consumer perspectives on processing technologies for organic food, Foods 10:1212, 2021.
    Hutapea D, Hidayat P, Sartiami D. Farmers’ perceptions and knowledge on chrysanthemum pests and its management in west java, indonesia. In: Proceedings of the IOP Conference Series: Earth and Environmental Science, 2021, Vol. 694IOP Publishing, 012011.
    ICNIRP. Guidelines on limits of exposure to ultraviolet radiation of wavelengths between 180 nm and 400 nm (incoherent optical radiation), Health Physics 87:171-186, 2004.
    Iizuka T, Shimizu A. Removal of pesticide residue from brussels sprouts by hydrostatic pressure, Innovative Food Science & Emerging Technologies 22:70-75, 2014.
    Jiang M, Zhang W, Zhang T, Liang G, Hu B, Han P, et al. Assessing transfer of pesticide residues from chrysanthemum flowers into tea solution and associated health risks, Ecotoxicology and environmental safety 187:109859, 2020.
    Jiang Y, Gan Z, Li Q, Shi P, Qing Y, Li H, et al. Investigation of heavy metals content and pesticide residues in 4 kinds of herb teas, Journal of Food Safety and Quality 7:4113-4117, 2016.
    Jorsaraei SGA, Maliji G, Azadmehr A, Moghadamnia AA, Faraji AA. Immunotoxicity effects of carbaryl in vivo and in vitro, Environmental toxicology and pharmacology 38:838-844, 2014.
    Kaushik G, Satya S, Naik S. Food processing a tool to pesticide residue dissipation–a review, Food research international 42:26-40, 2009.
    Khan MS, Debnath M. Pesticide residue in foods: Sources, management, and control. (Khan MS, Rahman MS, eds):Springer, 110-111, 2017.
    Khouryieh HA. Novel and emerging technologies used by the us food processing industry, Innovative Food Science & Emerging Technologies 67:102559, 2021.
    Kim JK, Oh M-S, Kim K-Y, Kim Y-S, Son M-H, Bae H-J, et al. The exposure risk assessment of residual pesticides in tea, The Korean Journal of Pesticide Science 15:28-35, 2011.
    Kim NY, Kim Y-S, Kim M-G, Jung H-R, Kim Y-S, Kim H-T, et al. Survey of multi residual pesticides in materials of korean traditional herbal tea, The Korean Journal of Pesticide Science 16:28-34, 2012.
    Kim SH, Kim JH, Kang B-K. Decomposition reaction of organophosphorus nerve agents on solid surfaces with atmospheric radio frequency plasma generated gaseous species, Langmuir 23:8074-8078, 2007.
    Koureas M, Tsakalof A, Tsatsakis A, Hadjichristodoulou C. Systematic review of biomonitoring studies to determine the association between exposure to organophosphorus and pyrethroid insecticides and human health outcomes, Toxicology letters 210:155-168, 2012.
    Lacombe A, Niemira BA, Gurtler JB, Fan X, Sites J, Boyd G, et al. Atmospheric cold plasma inactivation of aerobic microorganisms on blueberries and effects on quality attributes, Food microbiology 46:479-484, 2015.
    Langhans RW. Chrysanthemums: A manual of the culture, diseases, insects and economics of chrysanthemums:Cornell University Press, 1964.
    Lee KH, Kim H-J, Woo KS, Jo C, Kim J-K, Kim SH, et al. Evaluation of cold plasma treatments for improved microbial and physicochemical qualities of brown rice, Lwt 73:442-447, 2016.
    Lee T, Puligundla P, Mok C. Degradation of benzo [a] pyrene on glass slides and in food samples by low-pressure cold plasma, Food chemistry 286:624-628, 2019.
    Li C, Zhu H, Li C, Qian H, Yao W, Guo Y. The present situation of pesticide residues in china and their removal and transformation during food processing, Food Chemistry:129552, 2021.
    Liang Y, Wang W, Shen Y, Liu Y, Liu X. Effects of home preparation on organophosphorus pesticide residues in raw cucumber, Food Chemistry 133:636-640, 2012.
    Liao X, Li J, Muhammad AI, Suo Y, Chen S, Ye X, et al. Application of a dielectric barrier discharge atmospheric cold plasma (dbd‐acp) for eshcerichia coli inactivation in apple juice, Journal of food science 83:401-408, 2018.
    Lin C-M, Chu Y-C, Hsiao C-P, Wu J-S, Hsieh C-W, Hou C-Y. The optimization of plasma-activated water treatments to inactivate salmonella enteritidis (atcc 13076) on shell eggs, Foods 8:520, 2019.
    Ling Y, Wang H, Yong W, Zhang F, Sun L, Yang M-L, et al. The effects of washing and cooking on chlorpyrifos and its toxic metabolites in vegetables, Food Control 22:54-58, 2011.
    Liu Y, Wang Z, Zhang J. Dietary chinese herbs:Springer, 2015.
    Ma D, Wako Y. Evaluation of phenolic compounds and neurotrophic/neuroprotective activity of cultivar extracts derived from chrysanthemum morifolium flowers, Food Science and Technology Research 23:457-467, 2017.
    Maertens M, Swinnen JF. Standards as barriers and catalysts for trade and poverty reduction. 2006.
    Mahnot NK, Siyu L-P, Wan Z, Keener KM, Misra N. In-package cold plasma decontamination of fresh-cut carrots: Microbial and quality aspects, Journal of Physics D: Applied Physics 53:154002, 2020.
    Margni M, Rossier D, Crettaz P, Jolliet O. Life cycle impact assessment of pesticides on human health and ecosystems, Agriculture, ecosystems & environment 93:379-392, 2002.
    Min SC, Roh SH, Niemira BA, Boyd G, Sites JE, Uknalis J, et al. In-package inhibition of e. Coli o157: H7 on bulk romaine lettuce using cold plasma, Food microbiology 65:1-6, 2017.
    Mir S, Siddiqui M, Dar B, Shah M, Wani M, Roohinejad S, et al. Promising applications of cold plasma for microbial safety, chemical decontamination and quality enhancement in fruits, Journal of applied microbiology 129:474-485, 2020.
    Misra N, Moiseev T, Patil S, Pankaj S, Bourke P, Mosnier J, et al. Cold plasma in modified atmospheres for post-harvest treatment of strawberries, Food and bioprocess technology 7:3045-3054, 2014a.
    Misra N, Pankaj S, Walsh T, O’Regan F, Bourke P, Cullen P. In-package nonthermal plasma degradation of pesticides on fresh produce, Journal of hazardous materials 271:33-40, 2014b.
    Misra N, Schlüter O, Cullen PJ. Cold plasma in food and agriculture: Fundamentals and applications. In: Cold plasma in food and agriculture: Fundamentals and applications:Academic Press, 2016.
    Misra NN, Keener KM, Bourke P, Mosnier J-P, Cullen PJ. In-package atmospheric pressure cold plasma treatment of cherry tomatoes, Journal of bioscience and bioengineering 118:177-182, 2014.
    Morton J. Chrysanthemum culture for america: A book about chrysanthemums, their history, classification and care:Rural Publishing Company, 1891.
    Mousavi SM, Imani S, Dorranian D, Larijani K, Shojaee M. Effect of cold plasma on degradation of organophosphorus pesticides used on some agricultural products, Journal of plant protection research, 2017.
    Nicolopoulou-Stamati P, Maipas S, Kotampasi C, Stamatis P, Hens L. Chemical pesticides and human health: The urgent need for a new concept in agriculture, Frontiers in public health 4:148, 2016.
    Niemira BA. Cold plasma decontamination of foods, Annual review of food science and technology 3:125-142, 2012.
    Nuvolone D, Petri D, Voller F. The effects of ozone on human health, Environmental Science and Pollution Research 25:8074-8088, 2018.
    Oehmigen K, Hähnel M, Brandenburg R, Wilke C, Weltmann KD, Von Woedtke T. The role of acidification for antimicrobial activity of atmospheric pressure plasma in liquids, Plasma processes and polymers 7:250-257, 2010.
    Pallarés N, Tolosa J, Gavahian M, Barba FJ, Khaneghah AM, Ferrer E. The potential of hpp for minimizing pesticides and toxins in food products. In: Present and future of high pressure processing:Elsevier, 173-184, 2020a.
    Pallarés N, Tolosa J, Gavahian M, Barba FJ, Mousavi-Khaneghah A, Ferrer E. The potential of pulsed electric fields to reduce pesticides and toxins. In: Pulsed electric fields to obtain healthier and sustainable food for tomorrow:Elsevier, 141-152, 2020b.
    Panorama T. Available: https://www.taiwan-panorama.com.tw/Articles/Details?Guid=bf451864-40fe-4964-a270-4e9dbe70c968&langId=3&CatId=7, 2012.
    Park J, Lee H, Oh M, Kim J, Jang T, You Y, et al. A survey on pesticide residues of commercial flowering teas, The Korean Journal of Pesticide Science 17:1-5, 2013.
    Phan KTK, Phan HT, Brennan CS, Phimolsiripol Y. Nonthermal plasma for pesticide and microbial elimination on fruits and vegetables: An overview, International journal of food science & technology 52:2127-2137, 2017.
    Phan KTK, Phan HT, Boonyawan D, Intipunya P, Brennan CS, Regenstein JM, et al. Non-thermal plasma for elimination of pesticide residues in mango, Innovative food science & emerging technologies 48:164-171, 2018.
    Ramazzina I, Berardinelli A, Rizzi F, Tappi S, Ragni L, Sacchetti G, et al. Effect of cold plasma treatment on physico-chemical parameters and antioxidant activity of minimally processed kiwifruit, Postharvest Biology and Technology 107:55-65, 2015.
    Ramirez R, Saraiva J, Lamela CP, Torres JA. Reaction kinetics analysis of chemical changes in pressure-assisted thermal processing, Food Engineering Reviews 1:16-30, 2009.
    Rana S, Mehta D, Bansal V, Shivhare U, Yadav SK. Atmospheric cold plasma (acp) treatment improved in-package shelf-life of strawberry fruit, Journal of food science and technology 57:102-112, 2020.
    Ranjitha Gracy TK, Gupta V, Mahendran R. Influence of low‐pressure nonthermal dielectric barrier discharge plasma on chlorpyrifos reduction in tomatoes, Journal of food process engineering 42:e13242, 2019.
    Sakr M, Liu S. A comprehensive review on applications of ohmic heating (oh), Renewable and Sustainable Energy Reviews 39:262-269, 2014.
    Samir D, Asma S. Triazinone herbicide metribuzin induced acute liver injury: A study of animal model, Journal of Acute Disease 7:152, 2018.
    Sarangapani C, Misra N, Milosavljevic V, Bourke P, O’Regan F, Cullen P. Pesticide degradation in water using atmospheric air cold plasma, Journal of Water Process Engineering 9:225-232, 2016.
    Sarangapani C, Devi RY, Thirumdas R, Trimukhe AM, Deshmukh RR, Annapure US. Physico-chemical properties of low-pressure plasma treated black gram, LWT-food Science and Technology 79:102-110, 2017a.
    Sarangapani C, O'Toole G, Cullen P, Bourke P. Atmospheric cold plasma dissipation efficiency of agrochemicals on blueberries, Innovative Food Science & Emerging Technologies 44:235-241, 2017b.
    Schilling R. Which are the most and least contaminated crops, 2021.
    Sellamuthu PS, Denoya GI, Sivakumar D, Polenta GA, Soundy P. Comparison of the contents of bioactive compounds and quality parameters in selected mango cultivars, Journal of Food Quality 36:394-402, 2013.
    Singh D, Singh SK, Modi A, Singh PK, Zhimo VY, Kumar A. Impacts of agrochemicals on soil microbiology and food quality. In: Agrochemicals detection, treatment and remediation:Elsevier, 101-116, 2020.
    Solaimani Mehr S, Raftani Amiri Z, Esmaeilzadeh Kenari R, Sadeghi E. Effect of microwave irradiation on pesticides residues and physiochemical and microbial properties of dried apricots during storage time, Journal of Food Research 30:151-167, 2020.
    Taiwo AM. A review of environmental and health effects of organochlorine pesticide residues in africa, Chemosphere 220:1126-1140, 2019.
    Tappi S, Berardinelli A, Ragni L, Dalla Rosa M, Guarnieri A, Rocculi P. Atmospheric gas plasma treatment of fresh-cut apples, Innovative Food Science & Emerging Technologies 21:114-122, 2014.
    Thirumdas R, Sarangapani C, Annapure US. Cold plasma: A novel non-thermal technology for food processing, Food biophysics 10:1-11, 2015.
    Thirumdas R, Saragapani C, Ajinkya M, Deshmukh R, Annapure U. Influence of low pressure cold plasma on cooking and textural properties of brown rice, Innovative Food Science & Emerging Technologies 37:53-60, 2016.
    Thompson DA, Lehmler H-J, Kolpin DW, Hladik ML, Vargo JD, Schilling KE, et al. A critical review on the potential impacts of neonicotinoid insecticide use: Current knowledge of environmental fate, toxicity, and implications for human health, Environmental Science: Processes & Impacts 22:1315-1346, 2020.
    TK RG, PS S, Radhakrishnan M. Non-thermal technologies: Solution for hazardous pesticides reduction in fruits and vegetables, Critical Reviews in Food Science and Nutrition:1-18, 2020.
    Trolinger J, McGovern R, Elmer W, Rechcigl N, Shoemaker C. Diseases of chrysanthemum, Handbook of Florists’ Crops Diseases Springer, Cham:439-502, 2018.
    Verma JP, Jaiswal DK, Sagar R. Pesticide relevance and their microbial degradation: A-state-of-art, Reviews in Environmental Science and Bio/Technology 13:429-466, 2014.
    Wang F, Miao M, Xia H, Yang L-G, Wang S-K, Sun G-J. Antioxidant activities of aqueous extracts from 12 chinese edible flowers in vitro and in vivo, Food & Nutrition Research, 2016.
    Wang Huimin Gu CQW, Hu Hongjiang, Wu Yaming. Available: http://scitech.people.com.cn/BIG5/n/2013/0409/c1007-21063593.html, 2013.
    Wang R, Nian W, Wu H, Feng H, Zhang K, Zhang J, et al. Atmospheric-pressure cold plasma treatment of contaminated fresh fruit and vegetable slices: Inactivation and physiochemical properties evaluation, The European Physical Journal D 66:1-7, 2012.
    Wang S, Hao L-J, Zhu J-J, Zhang Q-W, Wang Z-M, Zhang X, et al. Study on the effects of sulfur fumigation on chemical constituents and antioxidant activity of chrysanthemum morifolium cv. Hang-ju, Phytomedicine 21:773-779, 2014.
    Wang S, Wang J, Li C, Xu Y, Wu Z. Ozone treatment pak choi for the removal of malathion and carbosulfan pesticide residues, Food Chemistry 337:127755, 2021.
    Won MY, Lee SJ, Min SC. Mandarin preservation by microwave-powered cold plasma treatment, Innovative Food Science & Emerging Technologies 39:25-32, 2017.
    Xia Y, Cheng S, Bian Q, Xu L, Collins MD, Chang HC, et al. Genotoxic effects on spermatozoa of carbaryl-exposed workers, Toxicological Sciences 85:615-623, 2005.
    Xiao J-J, Li Y, Fang Q-K, Shi Y-H, Liao M, Wu X-W, et al. Factors affecting transfer of pyrethroid residues from herbal teas to infusion and influence of physicochemical properties of pesticides, International journal of environmental research and public health 14:1157, 2017.
    Xingmin S, Jinren L, Guimin X, Yueming W, Lingge G, Xiaoyan L, et al. Effect of low-temperature plasma on the degradation of omethoate residue and quality of apple and spinach, Plasma Science and Technology 20:044004, 2018.
    Xue J, Li H, Liu F, Xue J, Chen X, Zhan J. Transfer of difenoconazole and azoxystrobin residues from chrysanthemum flower tea to its infusion, Food Additives & Contaminants: Part A 31:666-675, 2014.
    Yang W, Wang Z, Yang B, Jiang Y, Sun M, Liu X, et al. Pesticide degradation on solid surfaces: A moisture dependent process governed by the interaction between tio2 and h2o, New Journal of Chemistry, 2021.
    Yuan H, Jiang S, Liu Y, Daniyal M, Jian Y, Peng C, et al. The flower head of chrysanthemum morifolium ramat.(juhua): A paradigm of flowers serving as chinese dietary herbal medicine, Journal of Ethnopharmacology 261:113043, 2020.
    Yuan S, Li C, Zhang Y, Yu H, Xie Y, Guo Y, et al. Ultrasound as an emerging technology for the elimination of chemical contaminants in food: A review, Trends in Food Science & Technology, 2021.
    Zhao J, Zhang A, Héroux P, Sun Z, Liu Y. Remediation of diesel fuel polluted soil using dielectric barrier discharge plasma, Chemical Engineering Journal 417:128143, 2021.
    Zhou R, Zhou R, Yu F, Xi D, Wang P, Li J, et al. Removal of organophosphorus pesticide residues from lycium barbarum by gas phase surface discharge plasma, Chemical engineering journal 342:401-409, 2018.
    Ziuzina D, Misra N, Han L, Cullen P, Moiseev T, Mosnier J-P, et al. Investigation of a large gap cold plasma reactor for continuous in-package decontamination of fresh strawberries and spinach, Innovative Food Science & Emerging Technologies 59:102229, 2020.

    下載圖示 校內:2025-10-13公開
    校外:2025-10-13公開
    QR CODE