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研究生: 郭峻豪
Kuo, Chun-Hao
論文名稱: 某類高純度二甲基甲醯胺(DMF)回收控制系統之研究
The study of a class of high-purity Dimethylformamide(DMF) recovery control systems
指導教授: 吳煒
Wu, Wei
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2014
畢業學年度: 102
語文別: 中文
論文頁數: 65
中文關鍵詞: 廢水回收閃蒸塔蒸餾塔
外文關鍵詞: Wastewater recovery, Flash drum, Distillation column
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  •   DMF廢水的回收再利用一直以來皆有許多不同的處理方式,其中有效地分離純化DMF廢水是具有經濟效益且可以達到環境保護的做法。
      由於目前商業運轉DMF廢水回收系統,均是以雙塔蒸餾方式回收高純度DMF為主。對於國內較小規模代處理業者而言,雙塔建置成本不僅較高且處理小量廢液較不適宜。為提高回收DMF經濟價值,需開發簡易型DMF回收系統強調DMF純度能與新品一致且系統總成本能低於原有雙塔程序設計為原則。本研究提出閃蒸塔與單一蒸餾塔組合成的回流操作DMF回收系統並進行各項分析與評估工作。利用Aspen Plus為主模擬平台綜合評估各項分析指標包括耗能,純度,操作彈性等結果,確認提出的具回流操作型態DMF回收系統有達到環保排放之標準,並且需符合合作廠商預期要求後進行初步的製程動態模擬。

    There are many DMF recovery techniques for the DMF-containing wastewater, where the effective separation/purification of DMF can achieve economic benefits as well as meet the criterion of environmental protection. Currently, the commercialized DMF recovery plant adopts the two distillation columns to recover the high-purity DMF. However, the capital cost of two column design is large, so it is not suitable to treat the small amount of DMF wastewater. To address the revenue of DMF recovery technique, a simplistic DMF recovery system is developed to guarantee the high-purity of DMF that even compete the price of the new DMF product. The study develops a combination of a flash drum and a distillation column to carry out the reflux DMF recovery system. The evaluation and analysis of the design include energy consumption, purity and flexibility. Finally, the DMF recovery system can achieve the criterion of wastewater effluent. After its performance meet the request of cooperation company, the dynamic simulation of the process would be performed.

    目錄 摘要 II ABSTRACT III 致謝 VIII 表目錄 XI 圖目錄 XII 符號說明 XIII 第一章 緒論 1 1.1前言 1 1.2二甲基甲醯胺(N, N-DIMETHYLFORMAMIDE) 2 1.3二甲基胺(DIMETHYLAMINE) 3 1.4蒸發器 4 1.5精餾塔 7 1.6研究動機 10 第二章 建模理論 11 2.1DMF水解反應 11 2.1.1 基本介紹 11 2.1.2 宏觀反應動力學 12 2.1.3 DMF水解反應動力學模型 13 2.1.4 DMF水解活化能計算 14 2.2工廠現場資料與產品價格探討 16 2.2.1 工廠現場資料 16 2.2.2 進料條件 20 2.2.3 產品價格 20 2.3單一蒸餾塔初步模擬 22 2.4經濟效益評估原理 25 2.5控制策略 26 2.5.1 Aspen Dynamic動態系統介紹 26 2.5.2 Pressure-Driven 26 2.5.3 Flow-Driven 26 2.5.4控制器簡介 27 第三章 DMF廢水回收製程之穩態分析 30 3.1各項DMF廢水回收操作製程穩態模擬結果 30 3.1.1 單一蒸餾塔DMF廢水回收操作製程 30 3.1.2 雙塔DMF廢水回收操作製程 32 3.1.3 閃蒸塔加單一蒸餾塔DMF廢水回收操作製程 35 3.1.4 閃蒸塔加單一蒸餾塔DMF廢水回收間歇性操作製程 37 3.1.5 閃蒸塔加單一蒸餾塔DMF廢水回收回流操作製程 41 3.2各項DMF廢水回收操作製程比較 46 3.2.1 各項DMF廢水回收操作製程耗能與產品純度之比較 46 3.2.2 各項DMF廢水回收操作製程年總成本計算 49 3.3穩態分析之結果討論 52 第四章 製程最適化與動態模擬 55 4.1最適化理論 55 4.2製程操作條件最適化 58 4.3製程動態模擬 60 第五章 結論與未來展望 63 參考文獻 64

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