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研究生: 蕭棟升
Hsiao, Tung-Sheng
論文名稱: 以雷射剝離技術進行具鍍鎳基板氮化鎵蕭基二極體之研製
The Fabrication of GaN Schottky Barrier Diodes With a Nickel Pseudo-substrate using Laser Lift-Off Technology
指導教授: 王水進
Wang, Shui-Jinn
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 微電子工程研究所
Institute of Microelectronics
論文出版年: 2005
畢業學年度: 93
語文別: 中文
論文頁數: 64
中文關鍵詞: 雷射剝離氮化鎵鍍鎳基板蕭基二極體
外文關鍵詞: Gallium Nitride, Nickel substrate, Schottky diodes, Laser lift off
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  • 本論文主旨在進行具鍍鎳基板垂直結構氮化鎵蕭基二極體之研製。我們採用雷射剝離技術(Laser Lift Off, LLO)分離技術和電鍍鎳金屬以進行基板轉置的工作。

    實驗結果歸納所得雷射剝離時的最佳加工條件是能量密度為850mJ/cm2 (對於1.70 A、5.20 V、溫度55oC,定電流鍍鎳90分鐘的條件下)。實驗中係以Ti/Al/Ti/Au製作n型GaN之歐姆接觸,經詳細分析退火條件對其接觸電阻值的影響,結果顯示Ti/Al/Ti/Au系統具有優良的熱穩定性和特徵接觸電阻值6.644×10-5 cm2。LLO製程後以AFM觀察undoped-GaN薄膜,其RMS值為4.598 nm。蕭基接觸研究方面,修正型Norde method萃取參數被用以評估不同的ICP及KOH表面處理條件下,對所製得的蕭基二極體電特性的影響,最後再以掃描式電子顯微鏡觀測其表面型態的改變。

    In this thesis, the fabrication of GaN vertical Schottky Barrier diodes (SBDs) with Ni pseudo-substrate is studied. Laser Lift Off and Ni electroplating were employed for the removal of the GaN epilayers from the sapphire substrate and serving as a mechanical support for the huge strain in the epilayer as well as conducting substrate, respectively, for the realization of vertical-structure GaN SBDs.
    The optimal laser energy to separate GaN epi layer and sapphire substrate is found to be of 850 mJ/cm2 with the nickel substrate was electroplated under the condition of 1.70A、5.20V at 55oC. Ti/Al/Ti/Au metal system was used as ohmic metal to the heavily doped n-type GaN. The influence of annealing condition on the Specific Contact Resistance (SCR) of the (Au/Ti/Al/Ti)/n-GaN contact system is also investigated. Experimental results reveal that the (Au/Ti/Al/Ti)/n-GaN contact system has a good thermal stability and a SCR value as low as 6.644×10-5 cm2. After laser lift off, surface quality of undoped GaN films was also observed by Atom Force Microscope (AFM) and Secondary Emission Microscopy (SEM) technology. Root-mean-square of surface roughness of 4.598 nm was obtained. Electronic characteristics of Schottky barrier diodes (SBDs) were also studied under different ICP and KOH surface treatment conditions.

    中文摘要 Ⅰ 英文摘要 Ⅲ 目錄 Ⅴ 表目錄 Ⅷ 圖目錄 Ⅸ 第一章 緒論 1.1 氮化鎵的發展歷史--------------------------------1 1.1.1 氮化鎵的體單晶成長----------------------------1 1.1.2 氮化鎵的異質磊晶技術--------------------------2 1.2 氮化鎵的性質------------------------------------5 1.2.1 氮化鎵的電學特性------------------------------5 1.2.2 氮化鎵的材料特性------------------------------8 1.3 研究動機和本文結構------------------------------12 第二章 金屬與氮化鎵之歐姆接觸---------------------------15 2.1 引言--------------------------------------------15 2.2 金半接觸原理------------------------------------15 2.3 CTLM歐姆接觸電阻率測試原理和方法----------------17 2.4 垂直式氮化鎵蕭基二極體歐姆接觸製作--------------19 2.4.1 環型傳輸線模型實驗----------------------------20 2.4.2 Ti/Al/Ti/Au/n-GaN歐姆接觸---------------------22 2.4.3 熱穩定度分析----------------------------------25 2.4.4 CTLM量測結果整理------------------------------26 第三章 電鍍鎳基板及雷射剝離製程-------------------------30 3.1 電鍍鎳製程和沿革--------------------------------30 3.1.1 電鍍鎳技術和原理------------------------------30 3.1.2 電鍍液組成------------------------------------32 3.1.3 電鍍作業--------------------------------------33 3.2 雷射剝離原理------------------------------------36 3.2.1 準分子雷射系統簡介----------------------------37 3.2.2 氮化鎵的雷射加工機制--------------------------39 3.3 藍寶石基板剝離後結果----------------------------41 第四章 垂直式氮化鎵蕭基二極體之製作與量測分析-----------44 4.1 邊緣終結(Edge termination)技術------------------44 4.2 實驗步驟----------------------------------------46 4.3 結果和討論--------------------------------------50 4.3.1 參數萃取方法----------------------------------50 4.3.2 電性量測結果----------------------------------51 4.3.3 掃描式電子顯微鏡觀察分析----------------------57 4.3.4 雷射剝離後表面處理之必要性--------------------59 第五章 結論---------------------------------------------60 參考文獻-------------------------------------------------62

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