| 研究生: |
吳國龍 Wu, Kuo-Lung |
|---|---|
| 論文名稱: |
氣態氫化鈉分子C1S+能態
高能位與低能位的光譜探討 Spectroscopic Study of the NaH C1S+ Higher and Lower Vibrational State Levels |
| 指導教授: |
黃守仁
Whang, Thou-Jen |
| 學位類別: |
碩士 Master |
| 系所名稱: |
理學院 - 化學系 Department of Chemistry |
| 論文出版年: | 2002 |
| 畢業學年度: | 90 |
| 語文別: | 中文 |
| 論文頁數: | 127 |
| 中文關鍵詞: | 雙光子共振螢光減弱光譜 、氫化鈉分子 、激發光譜法 、雷射誘導螢光光譜法 |
| 外文關鍵詞: | LIF, laser induced fluorescence, NaH, excitation spectrum, Optical- Optical Double Resonance Fluorescence D |
| 相關次數: | 點閱:201 下載:1 |
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在本光譜學研究中,我們利用兩台脈衝式染料雷射進行雙光子共振螢光衰減光譜技術(Optical-Optical Double Resonance Fluorescence Depletion Spectroscopy)來偵測氣態氫化鈉分子高能位的C1+電子態,我們採用疊加式雙光子激發(Stepwise OODR excitation)的方式進行實驗,並藉由檢測A1+ X1+的螢光衰減訊號來找尋C1+電子態的振轉能級。
我們觀測的能量範圍位於36690 ~ 41500 cm-1總共得到v*-15 ~ v*-6及v*+9 ~ v*+17共19個振動量子數。觀測的轉動量子數分佈於J=1 ~ 11中,共計有223個振轉能階被觀測到。其振動能階能量差ΔGv+1/2分佈於189 ~ 89 cm-1中,轉動常數Bv則分佈於0.488 ~ 0.636 cm-1中。
未來期望能再加入更詳盡的實驗數據,且進一步確認絕對振動量子數v值並推得分子常數,使氫化鈉分子C1+電子態的位能曲線更臻完整。
In this study, nineteen vibrational levels of the NaH C1+ electronic state have been observed by the Optical-Optical Double Resonance Fluorescence Depletion Spectroscopy (OODR-FDS) technique. We applied the stepwise OODR excitation in our experiments. The OODR spectra of the NaH C1+ electronic state have been taken by monitoring the fluorescence depletion of the A1+ state to the X1+ state.
We have observed 223 rovibrational levels (including 19 vibrational levels) of the C1+ electronic state, they are in the range of 36690 ~ 41500 cm-1. The observed vibrational level spacings of ΔGv+1/2 are in the range 189 ~ 89 cm-1and derived rotational constants Bv are 0.488 ~ 0.636 cm-1.
However, we have to confirm the absolute vibrational quantum number by a further study and the Dunham coefficients can be derived to construct the complete potential energy curve of the NaH C1+ electronic state.
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