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研究生: 彭雅蓮
Peng, Ya-Lien
論文名稱: 探討不同可呼吸性粉塵採樣器所採集之粉塵在濾紙上分佈之均勻性及其對結晶型二氧化矽定量的影響
Accessing the Uniformity of Aerosols Deposited on Filters of Various Respirable Samplers and its Impacts on Quantification of Crystalline Silica Contents
指導教授: 蔡朋枝
Tsai, Perng-Jy
學位類別: 碩士
Master
系所名稱: 醫學院 - 環境醫學研究所
Department of Environmental and Occupational Health
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 53
中文關鍵詞: 均勻性定量分析旋風分離器α-石英可呼吸性粉塵採樣
外文關鍵詞: Respirable sampling, Cyclone, uniformity, α-quartz, quantification
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  • 本研究目的在於探討以不同之可呼吸性粉塵採樣器所採集之粉塵,在捕集濾紙上均勻性之情形,並瞭解均勻性對定量造成之干擾。本研究以37-mm SKC、25-mm SKC、 Nylon Cyclone、IOSH Cyclone進行鑄造廠之可呼吸性粉塵採樣,並評估粉塵及α-石英於濾紙上之均勻性。並藉Marple進行粒徑分佈採樣,以瞭解均勻性與粒徑分佈之關係。研究結果發現無論在何區,四種採樣器所採集之可呼吸性粉塵及α-石英濃度無顯著差異。可呼吸性粉塵濃度及其α-石英含量由高而低,依序為拆模區、噴砂區、及造模區。可呼吸性粉塵之氣動粒徑質量中位數 (MMAD) 分別為2.07、1.47、1.72µm,幾何平均標準偏差 (GSD) 分別為1.98、2.31、2.43。可呼吸性粉塵及α-石英均勻度評估之結果發現,四種採樣器之均勻性優劣依序為37 mm SKC、25 mm SKC、Nylon Cyclone、IOSH Cyclone,且拆模區之均勻性優於噴砂區優於造模區,此結果與MMAD趨勢有一致性。就均勻性對定量上的干擾,分別以 NIOSH 7500分析方法及濾紙直接分析法 (on-filter analysis) 分析α-石英之含量。由於on-filter analysis只分析濾紙的中心部份,本研究亦發現到與NIOSH 7500相比有高估的情形產生。由於以on-filter analysis分析結晶型二氧化矽會受到均勻性之影響而有所限制,因此未來應可進一步發展新的可呼吸性粉塵採樣器,使其所捕集之粉塵能
    均均勻分布於濾紙上,以減小因均勻性所帶來的誤差。

    The objective of this study is to assess the uniformity of respirable aerosols deposited on filter while using various types of respirable samplers, and to assess the impact of the above uniformity on quantifying crystalline silica contents. The study used 37-mm SKC, 25-mm SKC, Nylon Cyclone, and IOSH Cyclone for conducting respirable sampling to assess the uniformity of dust deposited on various types of filter. Marple cascade impactor was used for characterizing particle size distribution of workplace aerosols to access their effects on uniformity. Results showed that the concentration of respirable aerosols and α-quartz had no significant difference among different workplaces. Respirable aerosols and α-quartz concentrations in sequence shared the same trend as: demolition area > blasting > molding area. The mass median aerodynamic diameters (MMAD) and geometric standard deviations (GSD) for the above three areas were 2.07, 1.47, 1.72 µm and 1.98, 2.31, 2.43, respectively. For uniformity testing, we found that both respirable aerosols and α-quartz concentrations shared the same trend as :37-mm SKC>25-mm SKC> Nylon Cyclone>IOSH Cyclone. The uniformity in demolition area was better than that in blasting area. The uniformity in blasting area was better than that in molding area, results obtained from by both and the same trend of can be found in MMAD. To assess the impact of uniformity on α-quartz quantification, we compared on-filter analysis and NIOSH 7500. Because on-filter analysis only analyzes the center of filter, our results did show that it’s had resulted in α-quartz higher concentrations than that by NIOSH 7500. It is concluded that the uniformity can cause interference on quantitative crystalline silica. This study urges the need for the development of new aerosol sampler with more uniformly aerosol
    deposition characteristics on filter in the future.

    第一章 緖論 1 壹、研究源起 1 貳、研究目的 2 參、研究意義與重要性 3 第二章 文獻回顧 4 壹、何謂結晶型二氧化矽 4 貳、結晶型二氧化矽危害特性 5 一、矽肺症 (Silicosis) 5 二、感染性肺部疾病 (Infections) 6 三、肺癌 (Lung Cancer) 6 四、肺功能異常 (Abnormalities in Pulmonary Function Tests) 7 伍、非致命之呼吸系統疾病 (Nonmalignant Respiratory Diseases) 7 六、免疫系統疾病 (Autoimmune Disease) 7 七、肺心症 (Cor pulmonale) 7 八、腎臟發炎 (Nephritis) 8 參、結晶型二氧化矽法令規範 8 肆、結晶型二氧化矽採樣及分析方法 8 一、分光光度法: 9 二、傅立葉紅外光譜分析法: 9 三、X光繞射法: 9 伍、目前XRD分析方法面臨之問題 10 第三章 研究方法 15 壹、研究內容 15 貳、研究對象 15 參、採樣策略及方法 15 一、空氣樣本採樣 15 二、樣本標準分析方法 17 三、樣本on filter analysis直接濾紙分析方法 21 肆、樣本分析之品質控制 21 伍、均勻度評估 23 一、可呼吸性粉塵之均勻度評估 23 二、α-石英之均勻度評估 26 第四章 結果與討論 35 壹、各作業場所空氣中粉塵及結晶型二氧化矽濃度及粒徑分布特徵 35 一、濃度 35 二、作業現場粉塵之粒徑分佈 36 貳、均勻性分析 37 參、均勻性對α-石英定量之影響 38 第五章 結論與建議 46 第六章 參考文獻 47

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