本研究係針對Y地區一興建中垃圾焚化廠周遭環境進行大氣、水體及底泥中PCDD/Fs之檢測，期望能建立當地環境中PCDD/Fs之背景濃度及特徵剖面。同時進一步以所測得之戴奧辛背景濃度及依照該焚化廠排放特性經擴散模擬所得之增量濃度，來評估未來焚化廠運轉後，附近居民經由大氣吸入與飲用水食入之戴奧辛暴露風險。所得結論歸納如下：1. Y地區周界大氣中PCDD/Fs之濃度介於0.427~32.4 pg/Nm3之間，平均值為6.43 pg/Nm3；總TEQ濃度介於0.0244~0.493 pg I-TEQ/Nm3之間，平均值為0.205 pg I-TEQ/Nm3。2.大氣中PCDD/Fs濃度之氣固相分佈皆是以固相所佔之比例較高，固相比例介於84.8％~96.1％之間；總PCDD/Fs I-TEQ濃度固相所佔比例介於30.9％~69.9％之間。3.Y地區周界水體中自然水體(河水)與自來水體(淨水)採樣點之PCDD/Fs濃度分別介於0.874~13.3和0.0500~0.159pg/L之間，平均分別3.58和0.103 pg/L，總TEQ濃度分別介於0.00647~0.146和0.00141~0.00659 pg I-TEQ/L之間，平均總TEQ濃度分別為0.0307和0.00370 pg I-TEQ/L。4. Y地區周界底泥之PCDD/Fs含量介於2.21~651 pg/g 之間，平均為128.3 pg/g，總TEQ含量介於0.0786~1.87 pg I-TEQ/g之間，平均為0.692 pg I-TEQ/g。5. 經ISC3模式模擬Y焚化廠運轉後周遭大氣戴奧辛增量濃度介於0.0148~1.59 fg I-TEQ/m3之間，平均為0.180 fg I-TEQ/m3，而總沈降率則介於2.73×10-3~4.82 fg I-TEQ/m2 day之間，平均為0.527 fg I-TEQ/m2 day。6. 推估Y焚化廠運轉後淨水廠水中戴奧辛之增量濃度為1.24×10-8 pg I-TEQ/L。7.附近居民經由大氣吸入與飲用水食入之戴奧辛終生平均每日劑量為1.62×10-2 pg I-TEQ/kg/day，其值低於世界衛生組織所公布之戴奧辛容許暴露劑量1-4 pg I-TEQ/kg/day。而戴奧辛致癌風險值為2.53×10-6其值仍低於風險管理的風險值上界1×10-5。

　　The characteristics of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in ambient air, water and sediment from the surrounding locations of a constructing municipal solid waste incineration plant(MSWI) in rural areas(Y) were investigated. Additionally, we used the USEPA ISCST Model to predict the PCDD/F concentration in ambient air, and assessed the health risk of inhabitants through air and water. The conclusions of this study are summarized as follows: 1. The PCDD/F concentration in the atmosphere of Y area are between 0.427 and 32.4 pg/Nm3, and mean were 6.43 pg/Nm3. The toxic equivalency (TEQ) concentration in the atmosphere of PCDD/Fs were from 0.0244 to 0.493 pg I-TEQ/Nm3 with a mean value of 0.205 pg I-TEQ/Nm3. 2. The percentage of PCDD/Fs particle-bound concentration in the atmosphere ranged from 84.8% to 96.1%. 3. The PCDD/F concentration(TEQ) in river and tap-water were from 0.00647 to 0.146 pg I-TEQ/L (mean=0.0307 pg I-TEQ/L) and from 0.00141 to 0.00659 pg I-TEQ/L (mean=0.00370 pg I-TEQ/L), respectively. 4. The PCDD/Fs content(TEQ) in sediment samples of three sampling sites in four seasons ranged from 0.0786 to 1.87 pg I-TEQ/g, and the mean were 0.692 pg I-TEQ/g. 5. Simulation with ISCST Model revealed that the increment of PCDD/F concentration in ambient air and tap-water would be 1.59 fg I-TEQ/m3(maximun) and 1.24 fg I-TEQ/L(maximun), respectively after the operation of MSWI. 6. Health risk assessment revealed that the value of the maximum cancer risk of a person in the average life-time(70 years) was 2.53×10-6, which were still lower than the limiting value (1×10-5) of risk management.

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