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研究生: 黃植葳
Huang, Chih-Wei
論文名稱: 燃料電池不銹鋼雙極板之成型性與流道設計
Study on Formability and Channel Design of Stainless Steel Bipolar Plate for PEMFC
指導教授: 賴維祥
Lai, Wei-Hsiang
學位類別: 碩士
Master
系所名稱: 工學院 - 航空太空工程學系
Department of Aeronautics & Astronautics
論文出版年: 2016
畢業學年度: 104
語文別: 中文
論文頁數: 97
中文關鍵詞: 燃料電池、不銹鋼雙極板、沖壓、應力分析、流道設計
外文關鍵詞: Fuel Cell, Bipolar Plates, Polymer Electrolyte Membrane Fuel Cell, Stress Analysis, Channel Design
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  • 近年來在燃料電池中,雙極板決定了大部分的體積和重量,由於傳統石墨雙極板的加工費用相對較高,也大大增加了整個燃料電池組的成本。故解決電池成本和重量有重要意義。本研究旨在針對雙極板的沖壓成型參數進行成型性的有限元素摸擬分析並探討。模擬中分別改變不同的流道型式及沖壓參數,經由有限元素軟體LS-DYNA求解分析,在變薄率與回彈量間取得一個最佳值,並觀察這些參數對兩者的影響程度。接著量測沖壓後鈑件流道成型深度與預設值做誤差比較,並組裝成單電池測試性能的變化。
    模擬中將改變不同的流道參數包括:流道數目、流道深度、模具倒圓角、鈑件厚度,鈑件厚度的改變對變薄率與回彈量的影響會形成相反的趨勢。由模結果可得知流道成型性主要會因流道與肋條的寬度以及流道長度有關,在9-Channel流道形式下會有最好的成形成型性與最小的回彈產生。
    實驗中所量測得板件流道深度較均勻,但成型率有比較低的情形,故可改變加工製造方式來改善此現象。墊片溝槽量測中,分別用兩種量測方式下得到的結果,在Sample1下誤差最大為18.3%,實際鈑件深度差為0.109mm;Sample2下誤差最大為25%,實際鈑件深度差為0.110mm,從以上結果可知溝槽深度有不均勻的現象。

    Recently, metallic bipolar plates (MBP) determines most of the volume and weight, since the conventional graphite bipolar plates are relatively high processing costs, but also greatly increase the cost of whole fuel cell stack. Therefore, to solve the cost and weight problem of fuel cell are very important. The goal of this study is to simulate the stamping process of MBP. To find out how the flow-field pattern of the flow channel and the conditions of stamping process changing affects thinning rate and springback by using finite element analysis of LS-DYNA and to get the best experiment’s parameters. In the simulation, the parameters, such as metal’s thickness, channel depth, and springback rate were changed. The best flow-field pattern of 9-Channel was found from the results. In the experimental work, two methods were used to measure channel depth after stamping processing. In sample 1, the biggest deviation is 18.3%, and the actual depth of sheet is 0.109mm. In sample 2, the biggest deviation is 25%, and the actual depth is 0.110mm.These results showed that the phenomenon of uneven depth of the channels. It also showed that changing thickness is inversely proportional to thinning rate and spring back rate, and there are better dimension of channel depth. It can be improved by changing manufacturing method.

    目錄 中文摘要 II 英文摘要 III 誌謝 VI 目錄 VII 表目錄 X 圖目錄 XI 符號 XV 第一章 緒論 1 1-1 前言 1 1-2 質子交換膜燃料電池基本構造 5 1-3 雙極板簡介 6 1-3-1 碳/石墨雙極板 8 1-3-2 金屬雙極板 8 1-3-3 複合雙極板 12 1-4 研究動機與目的 13 1-5 質子交換膜燃料電池工作原理 14 第二章 文獻回顧 16 2-1 雙極板流道設計 17 2-2 雙極板成型性 21 2-3 雙極板組裝 22 2-4 雙極板製造 23 2-5 雙極板回彈分析 25 2-6 DYNAFORM簡介 27 2-7 成型極限圖 33 第三章 實驗設備 36 3-1 燃料電池測試機台 36 3-2 雷射掃描式共軛焦顯微鏡(LSCM) 37 3-3 掃描式電子顯微鏡(SEM) 39 3-4 外部加熱器 41 3-5 DYNAFORM模擬設定 42 3-6-1 網格之建立 45 3-6-2網格收斂性測試 46 第四章 研究方法 49 4-1 金屬雙極板單電池 49 4-2 流道設計 50 4-3 相關規格 50 4-4 平整度量測 53 4-5 極化曲線 53 第五章 結果與討論 59 5-1 DYNAFORM模擬鈑件成型與回彈結果 59 5-1-1 流道設計 61 5-1-2 流道深度對於沖壓成型性的影響 65 5-1-3 模具導圓角對於沖壓成型性的影響 72 5-1-4 鈑件厚度對沖壓成型性的影響 75 5-1-5 鈑件深度量測 78 5-1-6 鈑件流道成型性分析 84 5-2 極化曲線測試 87 第六章 結論與未來工作 89 6-1 結論 89 6-2 未來工作 91 參考文獻 92

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