石油與煤碳為全球節能減碳之重要環保議題，本研究以乳化重油及含碳飛灰為兩大主要探討題材，工作項目如下: ㄧ、使用高濃度含油廢水及自來水，分別製成含水量20%之乳化重油，並評估使用此二種乳化燃料與傳統重油之工業鍋爐能源效率，並檢測煙道廢氣中空氣污染物，包含一氧化碳、氮氧化物、硫氧化物、粒狀污染物及多環芳香烴化合物之濃度；二、添加生化溶液(NOE-7F)於廢輪胎與煤炭混燒產生之含碳飛灰，探討生化溶液於含碳飛灰熱處理過程節能減碳之機制及效率。
第一部分之研究結果顯示：含油廢水乳化重油之油品穩定性較自來水乳化重油為高，且含油廢水乳化重油之油滴粒徑較小(D50<2.82 μm)，分佈亦較均勻，於鍋爐之燃燒效率較佳。含油廢水乳化重油與傳統重油比較，可節能13%以上，亦可完善處理高濃度含油工業廢水。再者，使用含油廢水乳化重油，平均可降低二氧化碳排放13%、降低一氧化碳排放84%、降低氮氧化物排放17%、降低粒狀污染物排放36%、降低硫氧化物排放13%、降低總芳香烴化合物排放36%及降低毒性當量(BaPeq) 排放47%。台灣地區每年消耗之重油約1,500萬公秉，若每公秉油價為新台幣10,000元且淨節能以10%計，全面使用本研究所研發之乳化重油技術，台灣地區每年可節省之重油燃料成本約新台幣150億元。
第二部分之研究結果顯示：廢輪胎與煤炭混燒之飛灰色澤呈現深黑色，而添加生化溶液(NOE-7F)熱處理後，飛灰色澤轉為灰白色，生化溶液(NOE-7F)可有效催化飛灰中碳成份之燃燒反應。經熱處理後，比較添加10%生化溶液(E10)與未添加(E0)，E10平均可減少飛灰中碳含量37%，並可提升熱含量指數(IHC)約45.7%。再者，添加10%生化溶液(E10)並經熱處理過程，可使飛灰中碳成份大幅減少，且增加飛灰混凝土抗壓強度約7%，提升飛灰資源化之可行性，並減低高含碳飛灰之處理成本。本研究之成果亦顯示生化溶液(NOE-7F)於燃燒過程，為高效率之犧牲型觸媒，未來積極研發，或可於燃煤電廠扮演節能減碳之重要角色。

Decreasing the use of petroleum and coal are important environmental issues in reduction of CO2 emissions and consumption of fossil fuels. This study develops two related technologies, water emulsified fuel and carbon containing fly ashes. The aims of this study are as follows: First, this study uses wastewater and water to make the emulsified oil to evaluate energy efficiencies and flue gase pollutant emissions of industrial boilers. Second, this study applies bio-catalyst (NOE-7F) in the thermal treatment of waste-tire combustion ashes. The mechanism and efficiency of reducing the carbon content, after addition of the bio-catalyst are discussed. The results of the first part of reserch are as follows: better emulsion stability is found in wastewater emulsified oil as compared to water emulsified oil. Moreover, water/oil droplets are relatively uniform and smaller in wastewater emulsified fuel, and thus provide better combustion efficiency in boilers than heavy oil fuels, providing an energy saving of about 13%, as well as facilitating safe disposal of industrial wastewater. Furthermore, the wastewater emulsified oil fuel results in significant reductions in CO2 (13%), CO (84%), NOx (17%), particulate matter (36%), SO2 (13%), and total-PAHs (36%), and total-BaPeq (47%), as compared to heavy oil fuel. Considering the annual fuel consumption of 15 Mm3 in Taiwan with the fuel cost (NT $10,000 per m3), the potential overall fuel saving of such an approach is NT $15 billion. The results of the second part of reserch are as follows: The color of raw fly ashes was dark black and thermal treatment with NOE-7F made this change to white. The use of NOE-7F could improve the combustion efficiency of carbon content during thermal treatment. After thermal treatment of fly ashes by adding 10% NOE-7F, the carbon contents reduced by 37.6% (E10) and IHC increased by 45.7%. Moreover, with the significant carbon reduction due to adding NOE-7F, the compressive strength of mixture concrete of the fly ashes increased by 7%. Using NOE-7F may thus reduce the amount of fly ashes in landfill and the related decrease treatment costs. The results indicate that NOE-7F has a catalytic effect on combustion and enhances the energy released. Adding NOE-7F in the co-combustion of waste tires and coal can be further investigated in commercial boiler for energy saving and pollution reduction, and thus NOE-7F may play an important role in coal power plant for energy saving in the future.

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