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研究生: 闕瑞甫
Chueh, Jui-Fu
論文名稱: 大面積鎳銅鋅鐵氧磁體基板之材料及製程研究
Materials and processes to prepare large area NiCuZn ferrite substrates
指導教授: 向性一
Hsiang, Hsing-I
學位類別: 碩士
Master
系所名稱: 工學院 - 資源工程學系
Department of Resources Engineering
論文出版年: 2014
畢業學年度: 102
語文別: 中文
論文頁數: 85
中文關鍵詞: 直流電源轉換器模組鎳銅鋅鐵氧磁體束縛燒結直流疊加特性
外文關鍵詞: DC superposition, NiCuZn ferrites, constrained sintering
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  • 由於可攜式無線通訊產品不斷往小型化及薄型化發展,而單靠元件之複合化,仍無法完全滿足行動通訊產品對組裝空間之要求,需靠模組化之技術才可進一步節省30-40%之空間,使得直流電源轉換器模組將成為未來可攜式無線通訊產品元件市場之主流,因而使得大面積功率鎳銅鋅鐵氧磁體基板之研究亦成為重要課題。本研究並將第四章結論之“添加2wt% Bi2O3之鎳銅鋅鐵氧磁體之直流疊加特性”採用ZrO2生胚同時作為非磁性介質材料及燒結束縛層,以積層技術整合鎳銅鋅鐵氧磁體及非磁性ZrO2材料,除可解決大面積鎳銅鋅鐵氧磁體基板燒結翹曲、變形及分層之問題外,並可藉由產生之洩漏磁通,破壞磁蕊中之封閉磁性迴路,增加元件之磁飽和量,進而提昇積層晶片電感之直流疊加特性。本研究成功開發出積層型直流電源轉換器模組所需之關鍵技術:(1)具高起始導磁係數、高飽和磁通密度及高額定電流等磁特性之鎳銅鋅鐵氧磁體、(2)可與鎳銅鋅鐵氧磁體共燒之非磁性介質材料、(3)大面積鐵氧磁體基板之束縛燒結技術。

    Due to the advances in mobile communications, not only the electronic devices are getting smaller, but also their functions are upgraded continuously. Discrete components cannot completely meet the requirements of miniaturization. Moreover, portable devices continue to develop toward low-profile and multi-functionality, which results in the diversification of operating voltages. Therefore, the demand for integrating individual components into modules to reduce the size and increase the power density for DC-DC converters is increasing.
    Therefore, to prepare the large-area power NiCuZn ferrite substrate has become an important issue. In this study, the additional of Bi2O3 effects on the densification mechanism, magnetic properties and DC superposition behavior of NiCuZn ferrites were investigated. Through these investigations the densification mechanism of NiCuZn ferrites added with Bi2O3 was proposed and a suitable compromise between the initial permeability and DC-bias superposition characteristic can be obtained by adding the proper amount of Bi2O3. Moreover, this study also integrated magnetic ZrO2 green sheets acting simultaneously as the magnetic gap and constraining layer ceramic processing and low-pressure assisted constrained sintering technologies to prepare large area NiCuZn ferrite substrates.
    This study successfully developed the key technologies for making a DC-DC converter module: (1) a low temperature sintering NiCuZn ferrites with superior DC-bias-superposition characteristics, (2) the nonmagnetic material co-fired with the magnetic NiCuZn ferrites, (3) the low-pressure assisted constrained sintering process for the large area NiCuZn ferrites substrates.

    目錄 第一章、緒論 1 1-1 前言 1-2研究目的 2 第二章 前人文獻與研究 3 2-1積層電感之特性與製程 3 2-1-1電感之介紹 3 2-1-2積層電感之結構 3 2-2-1電感之品質因子 6 2-2-2電感之感抗 6 2-2-3直流疊加特性 7 2-2-4積層電感製程 9 2-3 鎳銅鋅鐵氧磁體材料 12 2-3-1尖晶石鐵氧磁體結構 12 2-3-2鋅鐵氧磁體 15 2-3-3 NiCuZn鐵氧磁體之成分比例影響特性 17 2-3-4 添加劑降低NiCuZn鐵氧磁體之燒結溫度 19 2-4 液相燒結 20 2-4-1 接觸角 25 2-4-2 溶解度之影響 26 2-5-1初導磁係數 29 2-5-2磁損失 31 2-5-3 磁異向性 32 2-5-4 磁滯曲線 35 2-6共燒 37 2-6-1低溫共燒陶瓷 37 2-6-2多層共燒行為與缺陷 39 2-6-3束縛燒結 40 第三章 實驗步驟與方法 41 3-1實驗藥品 41 3-2實驗流程 42 3-2-1鎳銅鋅鐵氧磁體混合氧化鉍之製程與分析流程圖 42 3-2-3 以ZrO2之束縛燒結製程與試片磁性分析 45 3-3材料特性分析 46 3-3-1 熱收縮曲線及體密度分析 46 3-3-2 熱差/熱重分析儀 46 3-3-3 XRD相鑑定 46 3-3-4 SEM顯微結構分析 47 3-3-5 TEM顯微結構分析 47 3-3-6 EPMA分析 48 3-3-7 磁性質分析 48 3-3-8 直流疊加特性分析 48 3-3-9 磁滯曲線分析 48 第四章 實驗結果與討論 49 4-1開發具高起始導磁係數、高飽和磁通密度、及高直流疊加特性等磁特性之鎳銅鋅鐵氧磁體 49 4-1-1 結晶相鑑定 49 4-1-2 添加Bi2O3對燒結活化能之影響 50 4-1-4顯微結構分析 55 4-1-5熱差分析 59 4-1-6相圖探討 61 4-1-7磁性質分析 62 4-1-8 磁滯曲線分析 64 4-1-9直流疊加特性分析 66 4-2 可與磁性NiCuZn鐵氧磁體共燒之非磁性介質材料之研究 68 4-2-1 NiCuZn鐵氧磁體與CuZn鋅鐵氧磁體之鎳擴散分析 68 4-2-2使用ZrO2與Al2O3對束縛燒結之顯微結構分析 68 4-2-3 ZrO2與含Bi鎳銅鋅鐵氧磁體之擴散現象分析 70 4-2-4使用ZrO2與Al2O3做束縛燒結之結晶相鑑定 70 4-3開發可製作大面積鎳銅鋅鐵氧磁體基板之低壓輔助束縛燒結製程與探討磁性直流疊加特性之研究 73 4-3-1 以ZrO2當束縛層施加不同壓力對X-Y、Z軸收縮量分析 73 4-3-2 以不同層數ZrO2當束縛層之結構分析 76 4-3-3 以ZrO2做束縛層束縛燒結之磁性質分析 77 4-3-4 以ZrO2做束縛層束縛燒結之磁滯曲線分析 78 4-3-5 以ZrO2做束縛層束縛燒結之直流疊加特性分析 79 第五章 結論 81 參考文獻 82

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