大氣中二氧化碳之增加主要係由化石燃料大量消耗之結果，二氧化碳會吸收由地球表面反射之紅外線而造成溫度上升、海平面上升等氣候變遷而稱之為” 溫室效應”。由氣候綱要公約及京都議定書之協定均可瞭解：此時已屆研究及發展各項減少溫室效應氣體技術之際，而如何降低二氧化碳之最大排放源產生之二氧化碳更為首要之務。
本研究建立一套去除煙道氣中二氧化碳系統之攪拌槽型式實驗設備，分別 以MEA(aq)、DEA(aq)、MDEA(aq)、NH3(aq)、NaOH(aq)及混合醇胺溶液為吸收劑測定各種操作狀況下之吸收速率，以瞭解其較佳之吸收劑及較適之操作條件，並求得此系統的各項反應動力數據。
本研究成果如下：
1. 以MEA吸收CO2
實驗結果顯示當氣體流速增加，其吸收速率會隨之增加，但隨著氣體流速增加其改變吸收速率的量會越少。而在不同濃度的吸收劑下，當吸收劑的濃度越高，其吸收速率越快，然在MEA=30%時的吸收速率為最大。當進氣CO2濃度越高其吸收速率越快，而吸收劑的情形跟上述雷同。
溫度改變時，當溫度越高其吸收速率會越高，而不同濃度的MEA其情形跟上述雷同。由不同吸收劑濃度之MEA(10~50%)吸收不同進流濃度之CO2(5~20%)，中可以得到下面之反應速率關係式。

在不同溫度的操作條件下，我們可以得到活化能為
Ea=32.26 Kj/mol;
反應速率常數為 [(L/mol)-0.2/sec]

2. 以氨水吸收CO2實驗：
結果顯示吸收速率NA隨氨水濃度、氣體流量、進氣濃度CO2濃度、溫度增加而上升，但不受O2濃度影響。在上述之操作條件下，CO2與NH3（aq）之反應速率分別約與CO2濃度之零次方及NH3（aq）濃度的2次方成正比，其反應動力式為 ，平均反應速率常數值為2235.4（cm3/mol/sec）。CO2之吸收速率皆隨著氣相條件（進氣流量與濃度）以及液相條件（吸收液濃度）之改變而有所變化，然而改變吸收液濃度對於吸收速率的影響較大，因此CO2的吸收可以說是偏向於液膜控制。而改變操作溫度（25℃~65℃）可求得CO2與氨水反應之活化能約為48.0 kj/mol，其反應速率常數與溫度的關係為 。
3. 加入NOx、SO2對MEA吸收CO2之影響
加入NOx = 300~800 ppm或SO2 = 500~1500 ppm或同時加入NOx=500 ppm + SO2=1000 ppm，吸收劑為MEA=10~50% (W/W)的情形下。其結果顯示加入NOx及SO2後，NOx及SO2的存在會對MEA吸收CO2有降低的作用。
4. 比較混合醇胺同時吸收CO2+NOx+SO2之關係
吸收劑分別為MEA/NH3= 30/1、30/3，MEA/DEA=30/10、30/20，MEA/MDEA=30/5、30/10之吸收結果顯示，加入NH3有助於吸收速率的增加，同時又抵抗了NOx、SO2對MEA吸收CO2不良的影響，加入越多的NH3吸收CO2效果越好。加入DEA時對MEA吸收CO2有不良的影響，加入越多其反效果越大。加入MDEA時對MEA吸收CO2有不良的影響，加入越多其反效果越大。
5. 比較不同吸收劑吸收CO2之關係
在溫度50℃，氣體流量12 L/min，進氣CO2濃度15% (V/V) 情行下，吸收劑為NH3=0.57~2.51M、NaOH=1~3M、MEA=1.64~4.91M、DEA=0.98~2.93M、 MDEA=0.87~2.62M。其結果為吸收速率的快慢分別為：NH3>MEA>NaOH>DEA>MDEA。

The increase in atmospheric carbon dioxide has primarily resulted from the consumption of fossil fuels for energy. The atmospheric CO2 is transparent to visible light but absorbs infrared radiation returning from the earth. Thus, the atmospheric CO2 may alter the radioactive balance of the earth and raise the global temperature. This so-called “greenhouse effect” could dramatically cause global climatic and environmental changes in precipitation, storm patterns, and increases in sea level. Therefore, it is the time to research and develop technologies for reducing CO2 emissions from energy production system that is the largest source of CO2 emissions.
This study was set up a bench-scale agitated vessel reactor system to removal CO2 in the simulated fuel gas. To measure the absorption rate of CO2 at various operating conditions; followed by using MEA(aq); DEA(aq); MDEA(aq); NH3(aq); NaOH(aq) and mixing amine as the additive and absorbent, respectively, to determine the chemical kinetics data.
The result of this study shows the following:
1. The effect of MEA concentration on CO2 absorption rate
The result shows that the absorption rate increase by increasing the gas flow rate but the amount of changing absorption rate decrease with increasing the gas flow rate. In different concentration of absorbent condition, the absorption rate increase by increasing the concentration of absorbent, however, the absorption rate is the fast in MEA=30%. The result shows that the absorption rate increase by increasing temperature.
We get the reaction kinetics equation from difference absorbent concentration absorbs difference CO2 concentration.

In difference operating temperature (30~70℃), we can get active energy , and reaction constant equation.
Ea=32.26 Kj/mol ,
kmn=

2. The effect of ammonia solution concentration on CO2 absorption rate
The result shows that the absorption rate NA(mol/sec/cm2) goes up by increasing the concentration of ammonia solution, CO2 inert concentration, gas flow rate and operation temperature, but not affected by the concentration of oxygen. Under the above-mentioned conditions, the reaction orders for CO2 and ammonia solution are respectively about 0 and 2, and the reaction kinetics equation cab be written as ，reaction rate constant is 2235.4（cm3/mol/sec）。. The absorption is varying by changing gas phase condition (gas flow rate and gas concentration) and liquid phase condition (absorbent concentration). However, changing absorbent concentration affects the absorption rate much more than changing gas phase condition does. Therefore, we can say that the absorption of CO2 should tend to liquid-film control. We also can get the active energy （about 48.0 kj/mol）of the reaction between CO2 and ammonia solution by changing operation temperature. The relationship between reaction rate constant and temperature is .
2. The effect of NOx and SO2 on CO2 absorption rate
The result shows that the absorption rate reduces by entering NOx and SO2.
3. The effect of additives CO2 absorption rate
Absorbent MEA/NH3 = 30/1, 30/3, MEA/DEA = 30/10, 30/20, MEA/MDEA = 30/5, 30/10. The result shows that entering NH3 can help to increase absorption rate and compete to NOx, SO2 bad affecting for MEA absorb CO2 and the absorption rate increase with increasing NH3 concentration.
4. The effect of absorbent type on CO2 absorption rate
Absorbent concentration NH3=0.57~2.51M; NaOH=1~3M; MEA=1.64~4.91M; DEA=0.98~2.93M; MDEA=0.87~2.62M. The result shows that the absorption rate is NH3>MEA>NaOH>DEA>MDEA.

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l Teng, T.T. and Mather, A. E. 1989, Solubility of H2S, CO2 and their mixtures in an AMP solution. Can. J. chem. Eng. 67,846-850

l Teng, T.T. and Mather, A. E. 1990, Solubility of CO2 in AMP solution. J. chem. Eng. Data 35,410-411

l Teramoto, M., Ohnishi, N., Takeuchi, N., Kitada, S. and Matsuyama, H., 2003, Seperation and enrichment measurement of carbon dioxide by capillary membrane module with permeation of carrier solution. Sep. Purif. Technol. 30, 215-227

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中文部分

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l 柳中明，「全球氣候變遷對我國的衝擊」，環耕雜誌第七期，p52-59，1997

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l 陳詩叢、潘守保、葉安晉、白曛綾，「以混合醇胺溶液(MEA/AMP)去除二氧化碳氣體之填充式吸收塔設計」，國科會研究計畫NSC 88-2621-Z009-001，民國八十八年，1999。

l 李玉鈴，「台灣二氧化碳減量之因應對策與建議」，工業簡訊第二十八卷 一期，p22-42，1998。
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l 施育林，「在噴霧塔中以氨水溶液去除二氧化碳之研究」，成功大學環工所碩士論文，2001。

l 涂博維，「以亞氯酸鈉與氫氧化鈉在煙道氣中同時除硫除氮之反應動力研究」，國立成功大學環工所碩士論文， 1994。

l 李旂緯，「同時吸收二氧化硫與一氧化氮之研究」，中原大學化工所碩士論文」，1987。

l 廖彥智編譯，「有機化學」，高立出版，1999。

l 朱信、徐偉傑、簡聰文，「南高屏地區空氣污染總量管制規劃：氮氧化物控制技術、效率、及成本資料調查分析」，2000

l 成功大學環境研究中心，「高雄市固定污染源氮氧化物排放減量輔導研究」，1998

l 吳清文，「空氣污染防制設備的基本設計與成本預估模式」，成功大學環境工程研究所碩士論文，1998

l 楊斐喬，「二氧化碳之分離及捕集，民生化工產業溫室氣體減量報導」，第7期，2000。

l 廖培欣，「二氧化碳液體在海洋中的溶解之研究」，國立成功大學化學工程所碩士論文，1999。

l 顧洋，「氣候變遷對工業發展之影響，地球環境變遷-地球溫暖化、溫室效應氣體對策研討會論文集」，pp.99-103，1995。

l 李忠達，「氫氧化鈣與二氧化碳反應之反應動力之研究」，國立成功大學環境工程所碩士論文，1996。

l 吳哲次，「都市焚化爐廢氣中二氧化碳減之探討」，國立臺灣大學環境工程學研究所碩士，2001。

l 康育豪，「深海掩埋液態CO2技術之最佳注入深度及液滴大小探討」，國立交通大學環境工程所碩士論文，2000。

l 陳重修，「二氧化碳與二氧化硫整合性控制技術之研究」，國立臺灣大學環境工程學研究所碩士，2000。

l 康城工程顧問公司，「硝煙、己二酸、氨、煉鋼及非鐵金屬鑄造等業別及排放管制計畫：期中報告」，行政院環保署，1998