| 研究生: |
林群勛 Lin, Chiun-Shiun |
|---|---|
| 論文名稱: |
都市垃圾焚化廠周界環境中空氣、植物及土壤所含多氯戴奧辛/呋喃之調查研究 Levels of Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans in Air, Vegetations and Soils Collected in the Vicinity of a Municipal Waste Incinerator |
| 指導教授: |
李俊璋
Lee, Ching-Chang 廖寶琦 Liao, Pao-Chi |
| 學位類別: |
碩士 Master |
| 系所名稱: |
醫學院 - 環境醫學研究所 Department of Environmental and Occupational Health |
| 論文出版年: | 2003 |
| 畢業學年度: | 91 |
| 語文別: | 中文 |
| 論文頁數: | 242 |
| 中文關鍵詞: | 土壤 、都市垃圾焚化廠 、多氯呋喃 、植物 、多氯戴奧辛 |
| 外文關鍵詞: | vegetation, soil, MWIs, PCDF, PCDD |
| 相關次數: | 點閱:77 下載:4 |
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多氯戴奧辛(polychlorinated dibenzo-p-dioxins, PCDDs)及多氯呋喃(poly- chlorinated dibenzofurans, PCDFs)是目前倍受重視之持久性有機污染物。在都市垃圾焚化廠運轉的過程中,多氯戴奧辛及多氯呋喃(PCDD/Fs)將隨著焚化廠煙囪的排氣,以氣相及附著於懸浮微粒表面之固相隨大氣乾濕沉降與擴散的方式進入環境中。在土壤中戴奧辛含量可以做為某地區暴露戴奧辛的長期指標,而植物中的戴奧辛濃度則可以界定某地區在植物生長期間的戴奧辛暴露量的短期指標。
本研究欲調查都市垃圾焚化廠周界環境之空氣、植物及土壤中戴奧辛含量濃度資料,以了解戴奧辛在空氣-土壤、空氣-植物、土壤-植物之傳輸情形,因此選取都市垃圾焚化廠周界環境之植物(榕樹葉、牧草)及土壤為對象,依據USEPA M1613B之方法與規範,進行前處理後,利用高解析氣相層析儀/高解析質譜儀(HRGC/HRMS)進行分析以獲得各介質之戴奧辛濃度資料。
本研究進行三季各項環境樣本之採樣與分析,分別得到土壤、榕樹葉、牧草各12個與空氣樣本24個。在空氣採樣期間的最主要風向為北風,平均溫度分別為29.1 ℃、23.5 ℃及21.4 ℃。空氣中PCDD/Fs平均濃度為0.114 (0.069-0.187)pg I-TEQ/Nm3,氣、固相樣本PCDD/Fs平均濃度分別為0.073(0.046-0.106)pg I-TEQ/Nm3、0.041(0.015-0.084)pg I-TEQ/ Nm3,而牧草中PCDD/Fs平均濃度為1.332(0.224-3.405)pg I-TEQ/g,榕樹葉中PCDD/Fs平均濃度為4.049(0.823-8.007) pg I-TEQ/g,土壤中PCDD/Fs平均濃度為5.524(0.486-24.016)pg I-TEQ/ g。各項環境介質在顯宮國小之樣本均得到較高之濃度值,推究其原因與當地之五氯酚污染有關。
同源物、同族物分布之比對方面,空氣固相及總濃度分別與土壤比對之結果發現在安佃國小、土城國小及建功國小之分布比例較為相似,推測在這兩點之土壤中戴奧辛的主要來源為大氣沉降所致,而在顯宮之分布則有較大之差異,推測在這兩點的土壤中PCDD/Fs可能來自其他的污染源;在空氣氣相與榕樹葉之比對結果發現除了在OCDD部分有較大差異外,其他同源物的分布比例是類似的,因此推測在榕樹葉內的低氯數PCDD/Fs可能來自氣孔吸收空氣中氣相之PCDD/Fs所致;在空氣氣固相與牧草之比對結果顯示其分布比例有相似之情形,顯示牧草中高氯數之PCDD/Fs來自與當地固相空氣沉降並附著於表面或藉氣孔吸入小微粒所致牧草中高氯數之PCDD/Fs來自與當地固相空氣沉降並附著於表面或藉氣孔吸入小微粒所致,而低氯數之PCDD/Fs則來自氣相空氣沉降並經氣孔吸收而來。
Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) are important persistent organic pollutants. Literatures showed that PCDD/Fs exist in the exhaust and fly ash from the municipal waste incinerators (MWIs). Due to the dry/wet deposition and dispersion, PCDD/Fs transfer from stack exhaust into the environmental matrices (such as air, vegetations and soils). Levels of PCDD/Fs in soils can be used to describe long-term exposure. Levels of PCDD/Fs in vegetations can bring information on the short-term exposure.
The aim of this study is to investigate the levels of PCDD/Fs in soil, vegetation and air samples collected in the vicinity of a MWI and compare the patterns of PCDD/F congeners in vegetation, soil, and air, which were collected in the same sampling sites to estimate the dispersion and transformation of environmental matrices. Four sampling sites in the vicinity of the MWI were selected and 4 soil, 4 grass, 4 leaf and 8 air samples were collected at each season. After the extraction and cleanup procedures, the quantification of PCDD/Fs is performed with HRGC/HRMS.
All the samples of soil/vegetation and air at four sites were collected and analyzed completely. During the 3 times collection of air sample, the main wind direction is north wind and the averaged temperature is 29.1℃, 23.5 ℃ and 21.4 ℃, respectively. Average and range of PCDD/Fs levels in soil samples were 5.524(0.486-24.016) pg I-TEQ/g, leaves samples were 4.049(0.823-8.007) pg I-TEQ/g, grasses samples were 1.332(0.224-3.405) pg I-TEQ/g and air samples were 0.114(0.069~0.187) pg I-TEQ/Nm3. Because of soil highly polluted by pentachlorophenol (PCP), levels and patterns of PCDD/Fs collected from Xian-Gong were dissimilar with samples collected from the other three sampling sites. According to the comparison of congener and homologue profiles between particle phase of ambient air samples and soil samples, there are similar congener patterns between particle phase and soil were found in An-Dian, Tu-Cheng and Jian-Gong. It conjectured that soil rebounding dominated the particle phase concentrations of ambient air because of the high wind speed (>2.5 m/s). The levels of soil samples in Xian-Gong were higher than the other two sampling sites. According to the pattern of congeners, soil samples in Xian-Gong and An-Dian may be contaminated by pentachlorophenol and open fire of strew respectively. Comparison of the pattern of congeners in gas phase and leaf revealed that it was similar to most congeners besides OCDD. Guess that the major route of PCDD/Fs transfer to leaves tissue was through the stoma absorption from gas phase PCDD/Fs in the air. Furthermore, the patterns of congeners between air (gas/particle phase) and grass were partially alike. The data shows that grasses absorbed the gaseous PCDFs and the PCDDs in the grass may came from the deposition of airborne particulate.
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