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研究生: 林群勛
Lin, Chiun-Shiun
論文名稱: 都市垃圾焚化廠周界環境中空氣、植物及土壤所含多氯戴奧辛/呋喃之調查研究
Levels of Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans in Air, Vegetations and Soils Collected in the Vicinity of a Municipal Waste Incinerator
指導教授: 李俊璋
Lee, Ching-Chang
廖寶琦
Liao, Pao-Chi
學位類別: 碩士
Master
系所名稱: 醫學院 - 環境醫學研究所
Department of Environmental and Occupational Health
論文出版年: 2003
畢業學年度: 91
語文別: 中文
論文頁數: 242
中文關鍵詞: 土壤都市垃圾焚化廠多氯呋喃植物多氯戴奧辛
外文關鍵詞: vegetation, soil, MWIs, PCDF, PCDD
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  • 多氯戴奧辛(polychlorinated dibenzo-p-dioxins, PCDDs)及多氯呋喃(poly- chlorinated dibenzofurans, PCDFs)是目前倍受重視之持久性有機污染物。在都市垃圾焚化廠運轉的過程中,多氯戴奧辛及多氯呋喃(PCDD/Fs)將隨著焚化廠煙囪的排氣,以氣相及附著於懸浮微粒表面之固相隨大氣乾濕沉降與擴散的方式進入環境中。在土壤中戴奧辛含量可以做為某地區暴露戴奧辛的長期指標,而植物中的戴奧辛濃度則可以界定某地區在植物生長期間的戴奧辛暴露量的短期指標。
    本研究欲調查都市垃圾焚化廠周界環境之空氣、植物及土壤中戴奧辛含量濃度資料,以了解戴奧辛在空氣-土壤、空氣-植物、土壤-植物之傳輸情形,因此選取都市垃圾焚化廠周界環境之植物(榕樹葉、牧草)及土壤為對象,依據USEPA M1613B之方法與規範,進行前處理後,利用高解析氣相層析儀/高解析質譜儀(HRGC/HRMS)進行分析以獲得各介質之戴奧辛濃度資料。
    本研究進行三季各項環境樣本之採樣與分析,分別得到土壤、榕樹葉、牧草各12個與空氣樣本24個。在空氣採樣期間的最主要風向為北風,平均溫度分別為29.1 ℃、23.5 ℃及21.4 ℃。空氣中PCDD/Fs平均濃度為0.114 (0.069-0.187)pg I-TEQ/Nm3,氣、固相樣本PCDD/Fs平均濃度分別為0.073(0.046-0.106)pg I-TEQ/Nm3、0.041(0.015-0.084)pg I-TEQ/ Nm3,而牧草中PCDD/Fs平均濃度為1.332(0.224-3.405)pg I-TEQ/g,榕樹葉中PCDD/Fs平均濃度為4.049(0.823-8.007) pg I-TEQ/g,土壤中PCDD/Fs平均濃度為5.524(0.486-24.016)pg I-TEQ/ g。各項環境介質在顯宮國小之樣本均得到較高之濃度值,推究其原因與當地之五氯酚污染有關。
    同源物、同族物分布之比對方面,空氣固相及總濃度分別與土壤比對之結果發現在安佃國小、土城國小及建功國小之分布比例較為相似,推測在這兩點之土壤中戴奧辛的主要來源為大氣沉降所致,而在顯宮之分布則有較大之差異,推測在這兩點的土壤中PCDD/Fs可能來自其他的污染源;在空氣氣相與榕樹葉之比對結果發現除了在OCDD部分有較大差異外,其他同源物的分布比例是類似的,因此推測在榕樹葉內的低氯數PCDD/Fs可能來自氣孔吸收空氣中氣相之PCDD/Fs所致;在空氣氣固相與牧草之比對結果顯示其分布比例有相似之情形,顯示牧草中高氯數之PCDD/Fs來自與當地固相空氣沉降並附著於表面或藉氣孔吸入小微粒所致牧草中高氯數之PCDD/Fs來自與當地固相空氣沉降並附著於表面或藉氣孔吸入小微粒所致,而低氯數之PCDD/Fs則來自氣相空氣沉降並經氣孔吸收而來。

    Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) are important persistent organic pollutants. Literatures showed that PCDD/Fs exist in the exhaust and fly ash from the municipal waste incinerators (MWIs). Due to the dry/wet deposition and dispersion, PCDD/Fs transfer from stack exhaust into the environmental matrices (such as air, vegetations and soils). Levels of PCDD/Fs in soils can be used to describe long-term exposure. Levels of PCDD/Fs in vegetations can bring information on the short-term exposure.
    The aim of this study is to investigate the levels of PCDD/Fs in soil, vegetation and air samples collected in the vicinity of a MWI and compare the patterns of PCDD/F congeners in vegetation, soil, and air, which were collected in the same sampling sites to estimate the dispersion and transformation of environmental matrices. Four sampling sites in the vicinity of the MWI were selected and 4 soil, 4 grass, 4 leaf and 8 air samples were collected at each season. After the extraction and cleanup procedures, the quantification of PCDD/Fs is performed with HRGC/HRMS.
    All the samples of soil/vegetation and air at four sites were collected and analyzed completely. During the 3 times collection of air sample, the main wind direction is north wind and the averaged temperature is 29.1℃, 23.5 ℃ and 21.4 ℃, respectively. Average and range of PCDD/Fs levels in soil samples were 5.524(0.486-24.016) pg I-TEQ/g, leaves samples were 4.049(0.823-8.007) pg I-TEQ/g, grasses samples were 1.332(0.224-3.405) pg I-TEQ/g and air samples were 0.114(0.069~0.187) pg I-TEQ/Nm3. Because of soil highly polluted by pentachlorophenol (PCP), levels and patterns of PCDD/Fs collected from Xian-Gong were dissimilar with samples collected from the other three sampling sites. According to the comparison of congener and homologue profiles between particle phase of ambient air samples and soil samples, there are similar congener patterns between particle phase and soil were found in An-Dian, Tu-Cheng and Jian-Gong. It conjectured that soil rebounding dominated the particle phase concentrations of ambient air because of the high wind speed (>2.5 m/s). The levels of soil samples in Xian-Gong were higher than the other two sampling sites. According to the pattern of congeners, soil samples in Xian-Gong and An-Dian may be contaminated by pentachlorophenol and open fire of strew respectively. Comparison of the pattern of congeners in gas phase and leaf revealed that it was similar to most congeners besides OCDD. Guess that the major route of PCDD/Fs transfer to leaves tissue was through the stoma absorption from gas phase PCDD/Fs in the air. Furthermore, the patterns of congeners between air (gas/particle phase) and grass were partially alike. The data shows that grasses absorbed the gaseous PCDFs and the PCDDs in the grass may came from the deposition of airborne particulate.

    第一章 序論 1 1-1 研究背景 1 1-2 研究目的 2 第二章 文獻回顧 3 2-1 何謂戴奧辛? 3 2-1-1 戴奧辛之物理化學性質 3 2-1-2 戴奧辛之產生源 3 2-1-3 戴奧辛之毒理性質 4 2-1-4 近年發生之PCDD/Fs污染事件 6 2-2 PCDD/Fs在環境中之傳輸 6 2-3 PCDD/Fs之大氣傳輸 7 2-3-1 氣固相分配 7 2-3-2 乾沉降 7 2-3-3 濕沉降 8 2-4 PCDD/Fs之土壤傳輸 8 2-5 PCDD/Fs之植物傳輸 9 2-5-1 植物根部吸收作用 10 2-5-2 土壤揮發作用及土壤再揚起作用 10 2-5-3 大氣中氣相沉降之吸收作用與固相沉降之吸附作用 11 2-6 世界各國空氣、植物及土壤中PCDD/Fs濃度分布 12 2-6-1 空氣 12 2-6-2 土壤 13 2-6-3 植物 14 2-7 植物中PCDD/Fs分析方法比較 16 第三章 研究材料與方法 18 3-1 研究對象選取 18 3-2 採樣策略與方法 18 3-2-1 採樣對象 18 3-2-2 採樣地點選取 18 3-2-3 採樣時間與頻率 18 3-2-4 空氣樣本採樣方法 19 3-2-5 土壤樣本採樣方法 20 3-2-6 植物樣本採樣方法 21 3-3 PCDD/Fs空氣氣固相樣本前處理及分析方法 22 3-4 PCDD/Fs土壤樣本前處理及分析方法 26 3-4-1 土壤樣本乾燥前處理方法 26 3-4-2 土壤樣本前處理方法 26 3-5 PCDD/Fs植物樣本前處理及分析方法 30 3-5-1 植物樣本乾燥前處理方法 30 3-5-2 植物樣本前處理方法 31 3-6 樣本儀器分析方法 34 3-6-1 空氣樣本 34 3-6-2 土壤樣本 34 3-6-3 植物樣本 34 3-6-4 分析儀器及操作條件設定 35 3-7 樣本數據品質保證及品質管制(QA/QC) 36 3-7-1 採樣及前處理之品保品管 36 3-7-2 儀器分析之品保品管 39 3-7-3 儀器檢量線 40 3-8 數據計算方式 41 第四章 結果與討論 42 4-1 品保品管資料 42 4-1-1 滯留時間之建立 42 4-1-2 起始檢量線之建立 42 4-1-3 起始檢量線校正 42 4-1-4 層析管柱解析度查核 43 4-1-5 儀器靈敏度 43 4-1-6 基質添加分析 43 4-1-7 實驗室空白分析 43 4-2 氣象資料整理 43 4-2-1 大氣溫度 44 4-2-2 風速與風向 44 4-3 空氣中PCDD/Fs濃度值之分布 45 4-3-1空氣PCDD/Fs分析結果 45 4-3-1-1 第一季空氣樣本分析結果(2002/09/03-2002/09/06) 45 4-3-1-2 第二季空氣樣本分析結果(2002/11/08-2002/11/11) 46 4-3-1-3 第三季空氣樣本分析結果(2003/02/14-2003/02/17) 47 4-3-1-4 三季空氣樣本綜合比較 48 4-3-1-5 國內外空氣中PCDD/Fs研究結果比較 50 4-3-2 空氣中氣固相戴奧辛分析結果 51 4-3-2-1 第一季氣固相採樣分析結果(2002/09/03-2002/09/06) 51 4-3-2-2 第二季氣固相採樣分析結果(2002/11/08-2002/11/11) 52 4-3-2-3 第三季氣固相採樣分析結果(2003/02/14-2003/02/17) 53 4-3-2-4 三季空氣氣固相樣本綜合比較 54 4-4 土壤中PCDD/Fs濃度值之分布 55 4-4-1 第一季土壤採樣分析結果(2002/08/26) 55 4-4-2 第二季土壤採樣分析結果(2002/11/16) 56 4-4-3 第三季土壤採樣分析結果(2003/02/22) 57 4-4-4 三季土壤樣本比較 58 4-4-5 土壤樣本與國內外研究比較 59 4-5 牧草中PCDD/Fs濃度值之分布 60 4-5-1 第一季牧草樣本採樣分析結果(2002/08/26) 60 4-5-2 第二季牧草樣本採樣分析結果(2002/11/16) 60 4-5-3 第三季牧草樣本採樣分析結果(2003/02/22) 61 4-5-4三季牧草樣本結果比較 62 4-5-5 牧草樣本與國外文獻比較 63 4-6 榕樹葉中PCDD/Fs濃度值之分布 64 4-6-1 第一季榕樹葉樣本採樣分析結果(2002/08/26) 64 4-6-2 第二季榕樹葉樣本採樣分析結果(2002/11/16) 65 4-6-3 第三季榕樹葉樣本採樣分析結果(2003/02/22) 66 4-6-4 三季榕樹葉樣本結果比較 67 4-6-5 榕樹葉樣本與國內外研究比較 68 4-7安佃國小、土城國小、建功國小各項介質之PCDD/Fs分布比較 69 4-7-1 空氣(總濃度/固相/氣相) v.s. 牧草 69 4-7-2 空氣(總濃度/固相/氣相) v.s. 榕樹葉 70 4-7-3 空氣(總濃度/固相/氣相) v.s. 土壤 71 4-8 顯宮國小各項介質之PCDD/Fs分布比較 72 4-8-1 空氣(總濃度/固相/氣相) v.s. 牧草 72 4-8-2 空氣(總濃度/固相/氣相) v.s. 榕樹葉 72 4-8-3 空氣(總濃度/固相/氣相) v.s. 土壤 73 第五章 結論與建議 75 5-1 結論 75 5-2 建議 77 參考文獻 78 附錄 238 表2-1-1 PCDDs之物理化學性質 87 表2-1-2 PCDFs之物理化學性質 88 表2-1-3 世界各國PCDD/Fs之排放資料 89 表2-1-4 I-TEF及WHO-TEF值 90 表2-6-1 國外周界空氣中PCDD/Fs濃度之比較 91 表2-6-1 國外周界空氣中PCDD/Fs濃度之比較(續) 92 表2-6-2 國外土壤中PCDD/Fs濃度之比較 93 表2-6-3 國外植物(草類)中PCDD/Fs濃度之比較 94 表2-6-3 國外植物(草類)中PCDD/Fs濃度之比較(續) 95 表2-6-4 國外植物(非草類)中PCDD/Fs濃度之比較 96 表2-7-1 各植物PCDD/Fs相關研究之萃取方法比較 97 表3-1 採樣點之UTM座標及與焚化廠之距離 98 表3-2 空氣PCDD/Fs分析方法之各種添加標準品與回收率規範 99 表3-3 土壤PCDD/Fs分析方法之各種添加標準品與回收率規範 100 表3-4 植物PCDD/Fs分析方法之各種添加標準品與回收率規範 101 表3-5 PCDD/Fs之理論離子強度比及品管規範值 102 表3-6 空氣PCDD/Fs分析方法起始檢量線標準品之濃度 103 表3-7 土壤及植物PCDD/Fs分析方法起始檢量線標準品之濃度 104 表3-8 檢量校正相對感應因子品管限值 105 表3-9 檢量線中點查核品管規範 106 表4-1-1 檢量線校正相對感應因子品管數據表 107 表4-1-2 空氣樣本基質添加回收率測試結果 108 表4-1-3 牧草、榕樹葉樣本基質添加回收率測試結果 109 表4-1-4 土壤樣本基質添加回收率測試結果 110 表4-1-5 空氣及牧草樣本實驗室空白分析結果 111 表4-1-6 榕樹葉及土壤樣本實驗室空白分析結果 112 表4-2-1 空氣採樣期間台南測站之溫度、風速及濕度資料 113 表4-3-1 第一季空氣樣本中PCDD/Fs原始濃度分布 114 表4-3-2 第一季空氣樣本中PCDD/Fs總毒性當量濃度分布 115 表4-3-3 第二季空氣樣本中PCDD/Fs原始濃度分布 116 表4-3-4 第二季空氣樣本中PCDD/Fs總毒性當量濃度分布 117 表4-3-5 第三季空氣樣本中PCDD/Fs原始濃度分布 118 表4-3-6 第三季空氣樣本中PCDD/Fs總毒性當量濃度分布 119 表4-3-7 各季各採樣點空氣之採氣體積、懸浮微粒量及微粒濃度值 120 表4-3-8 各季各採樣點空氣中PCDD/Fs原始濃度與毒性當量濃度分布 121 表4-3-9 各季各採樣點空氣中PCDFs/PCDDs比值 121 表4-3-10 國內周界空氣中PCDD/Fs濃度之比較 122 表4-3-10 國內周界空氣中PCDD/Fs濃度之比較(續) 123 表4-3-11 本研究之空氣中戴奧辛濃度與過去研究之比較 124 表4-3-12 第一季空氣中氣固相PCDD/Fs同源物原始濃度分布 125 表4-3-13 第一季空氣中氣固相PCDD/Fs同源物毒性當量濃度分布 126 表4-3-14 第一季空氣中氣固相PCDD/Fs同源物毒性當量濃度分布百分比 127 表4-3-15 第二季空氣中氣固相PCDD/Fs同源物原始濃度分布 128 表4-3-16 第二季空氣中氣固相PCDD/Fs同源物毒性當量濃度分布 129 表4-3-17 第二季空氣中氣固相PCDD/Fs同源物毒性當量濃度分布百分比 130 表4-3-18 第三季空氣中氣固相PCDD/Fs同源物原始濃度分布 131 表4-3-19 第三季空氣中氣固相PCDD/Fs同源物毒性當量濃度分布 132 表4-3-20 第三季空氣中氣固相PCDD/Fs同源物毒性當量濃度分布百分比 133 表4-3-21 各季各採樣點空氣中氣固相PCDD/Fs原始濃度與毒性當量濃度分布 134 表4-4-1 第一季土壤中PCDD/Fs同源物原始濃度分布 135 表4-4-2 第一季土壤中PCDD/Fs同源物毒性當量濃度分布 136 表4-4-3 第一季土壤中PCDD/Fs同族物分布 137 表4-4-4 第二季土壤中PCDD/Fs同源物原始濃度分布 138 表4-4-5 第二季土壤中PCDD/Fs同源物毒性當量濃度分布 139 表4-4-6 第二季土壤中PCDD/Fs同族物分布 140 表4-4-7 第三季土壤中PCDD/Fs同源物濃度分布 141 表4-4-8 第三季土壤中PCDD/Fs同源物毒性當量濃度分布 142 表4-4-9 第三季土壤中PCDD/Fs同族物分布 143 表4-4-10 各季各採樣點土壤樣本中PCDD/Fs濃度值 144 表4-4-11 各季各採樣點土壤樣本中PCDFs/PCDDs比值 144 表4-4-12 國內土壤中PCDD/Fs濃度之比較 145 表4-4-12 國內土壤中PCDD/Fs濃度之比較(續) 146 表4-5-1 第一季牧草中PCDD/Fs同源物原始濃度分布 147 表4-5-2 第一季牧草中PCDD/Fs同源物毒性當量濃度分布 148 表4-5-3 第一季牧草中PCDD/Fs同族物分布 149 表4-5-4 第二季牧草中PCDD/Fs同源物原始濃度分布 150 表4-5-5 第二季牧草中PCDD/Fs同源物毒性當量濃度分布 151 表4-5-6 第二季牧草中PCDD/Fs同族物分布 152 表4-5-7 第三季牧草中PCDD/Fs同源物原始濃度分布 153 表4-5-8 第三季牧草中PCDD/Fs同源物毒性當量濃度分布 154 表4-5-9 第三季牧草中PCDD/Fs同族物分布 155 表4-5-10 各季各採樣點牧草中PCDD/Fs濃度值 156 表4-5-11 各採樣點各季之牧草PCDD/Fs原始濃度分布綜合比較 156 表4-6-1 第一季榕樹葉中PCDD/Fs同源物原始濃度分布 157 表4-6-2 第一季榕樹葉中PCDD/Fs同源物毒性當量濃度分布 158 表4-6-3 第一季榕樹葉中PCDD/Fs同族物分布 159 表4-6-4 第二季榕樹葉中PCDD/Fs同源物原始濃度分布 160 表4-6-5 第二季榕樹葉中PCDD/Fs同源物毒性當量濃度分布 161 表4-6-6 第二季榕樹葉中PCDD/Fs同族物分布 162 表4-6-7 第三季榕樹葉中PCDD/Fs同源物原始濃度分布 163 表4-6-8 第三季榕樹葉中PCDD/Fs同源物毒性當量濃度分布 164 表4-6-9 第三季榕樹葉中PCDD/Fs同族物分布 165 表4-6-10 各季各採樣點榕樹葉中PCDD/Fs濃度值 166 表4-6-11 各採樣點之植物含水率分布綜合比較 166 表4-6-12 各季之榕樹葉及牧草PCDD/Fs同族物分布比例之比較 167 表4-6-13 各採樣點各季之榕樹葉PCDD/Fs原始濃度分布綜合比較 167 表4-6-14 國內榕樹葉中PCDD/Fs毒性當量濃度之比較 168 表4-6-14 國內榕樹葉中PCDD/Fs濃度之比較(續) 169 表4-7-1 顯宮國小之各項環境介質之PCDD/Fs同族物分布比例與其餘採樣點之統計分析結果 170 表4-8-1 顯宮國小與其餘三採樣點之榕樹葉分布比例及原始濃度 170 表4-8-2 顯宮國小與其餘三採樣點之固相空氣分布比例及原始濃度 171 圖2-1 PCDD與PCDF之化學結構式 172 圖2-2 PCDD/Fs進入植物體內的途徑 173 圖3-1 本研究所選取四個採樣點之相對位置圖 174 圖3-2 空氣樣本萃取流程圖 175 圖3-3 空氣樣本酸洗淨化流程圖 176 圖3-4 空氣樣本酸性矽膠管柱淨化流程圖 177 圖3-5 空氣樣本酸性氧化鋁管柱淨化流程圖 178 圖3-6 空氣樣本活性碳管柱淨化流程圖 179 圖3-7 土壤樣本萃取流程圖 180 圖3-8 土壤樣本酸洗淨化流程圖 181 圖3-9 土壤樣本酸性矽膠管柱淨化流程圖 182 圖3-10 土壤樣本酸性氧化鋁管柱淨化流程圖 183 圖3-11 土壤樣本活性碳管柱淨化流程圖 184 圖3-12 植物樣本萃取流程圖 185 圖3-13 植物樣本酸洗淨化流程圖 186 圖3-14 植物樣本酸性矽膠管柱淨化流程圖 187 圖3-15 植物樣本酸性氧化鋁管柱淨化流程圖 188 圖3-16 植物樣本矽酸鎂管柱淨化流程圖 189 圖4-1-1 本研究建立之PCDD/Fs滯留時間 190 圖4-1-2 本研究建立之管柱解析度 191 圖4-1-3 本研究建立之檢量線訊雜比 192 圖4-2-1 第一季空氣採樣期間(2002/09/02~05)台南測站之風向分布圖 193 圖4-2-2 第二季空氣採樣期間(2002/11/08~11)台南測站之風向分布圖 193 圖4-2-3 第三季空氣採樣期間(2003/02/14~17)台南測站之風向分布圖 194 圖4-3-1 各季各採樣點空氣中PCDD/Fs原始濃度分布 195 圖4-3-2 各季各採樣點空氣中PCDD/Fs毒性當量濃度分布 196 圖4-3-3 各季各採樣點空氣中PCDD/Fs TEQ值與日本環境廳標準 197 圖4-3-4 第一季各採樣點空氣中固相PCDD/Fs同源物原始濃度分布比例 198 圖4-3-5 第一季各採樣點空氣中氣相PCDD/Fs同源物原始濃度分布比例 198 圖4-3-6 第一季各採樣點空氣中固相PCDD/Fs同源物TEQ分布比例 199 圖4-3-7 第一季各採樣點空氣中氣相PCDD/Fs同源物TEQ分布比例 199 圖4-3-8 第二季各採樣點空氣中固相PCDD/Fs同源物原始濃度分布比例 200 圖4-3-9 第二季各採樣點空氣中氣相PCDD/Fs同源物原始濃度分布比例 200 圖4-3-10 第二季各採樣點空氣中固相PCDD/Fs同源物TEQ分布比例 201 圖4-3-11 第二季各採樣點空氣中氣相PCDD/Fs同源物TEQ分布比例 201 圖4-3-12 第三季各採樣點空氣中固相PCDD/Fs同源物原始濃度分布比例 202 圖4-3-13第三季各採樣點空氣中氣相PCDD/Fs同源物原始濃度分布比例 202 圖4-3-14 第三季各採樣點空氣中固相PCDD/Fs同源物TEQ分布比例 203 圖4-3-15 第三季各採樣點空氣中氣相PCDD/Fs同源物TEQ分布比例 203 圖4-3-16 本研究各季PCDD/Fs同族物固相比(固相/固相+氣相)分布 204 圖4-3-17 過去研究各季PCDD/Fs同族物固相比(固相/固相+氣相)分布 205 圖4-4-1 第一季各採樣點土壤中PCDD/Fs同源物原始濃度分布比例 206 圖4-4-2 第一季各採樣點土壤中PCDD/Fs同源物毒性當量濃度分布比例 206 圖4-4-3 第二季各採樣點土壤中PCDD/Fs同源物原始濃度分布比例 207 圖4-4-4 第二季各採樣點土壤中PCDD/Fs同源物TEQ分布比例 207 圖4-4-5 第三季各採樣點土壤中PCDD/Fs同源物原始濃度分布比例 208 圖4-4-6 第三季各採樣點土壤中PCDD/Fs同源物TEQ分布比例 208 圖4-4-7 文獻中五氯酚污染地區之土壤內PCDD/Fs分布 209 圖4-4-8 文獻中都市焚化廠周界地區之土壤內PCDD/Fs分布 209 圖4-5-1 第一季各採樣點牧草中PCDD/Fs同源物分布比例 210 圖4-5-2 第一季各採樣點牧草中PCDD/Fs同源物之TEQ分布比例 210 圖4-5-3 第二季各採樣點牧草中PCDD/Fs同源物分布比例 211 圖4-5-4 第二季各採樣點牧草中PCDD/Fs同源物之TEQ分布比例 211 圖4-5-5 第三季各採樣點牧草中PCDD/Fs同源物分布比例 212 圖4-5-6 第三季各採樣點牧草中PCDD/Fs同源物之TEQ分布比例 212 圖4-5-7 各季各採樣點牧草中PCDD/Fs同族物之原始濃度分布 213 圖4-5-8 文獻中都市焚化廠周界地區之牧草內PCDD/Fs分布 214 圖4-6-1 第一季各採樣點榕樹葉中PCDD/Fs同源物分布比例 215 圖4-6-2 第一季各採樣點榕樹葉中PCDD/Fs同源物之TEQ分布比例 215 圖4-6-3 第二季各採樣點榕樹葉中PCDD/Fs同源物分布比例 216 圖4-6-4 第二季各採樣點榕樹葉中PCDD/Fs同源物之TEQ分布比例 216 圖4-6-5 第三季各採樣點榕樹葉中PCDD/Fs同源物分布比例 217 圖4-6-6 第三季各採樣點榕樹葉中PCDD/Fs同源物之TEQ分布比例 217 圖4-6-7 國內研究之焚化廠周界地區榕樹葉內PCDD/Fs分布 218 圖4-6-8 文獻中都市焚化廠周界地區之針葉內PCDD/Fs分布 219 圖4-7-1 總空氣與牧草之PCDD/Fs同族物分布比較 220 圖4-7-2 空氣固相與牧草之PCDD/Fs同族物分布比較 220 圖4-7-3 空氣氣相與牧草之PCDD/Fs同族物分布比較 221 圖4-7-4 土壤與牧草之PCDD/Fs同族物分布比較 221 圖4-7-5 空氣(總濃度/固相/氣相)、土壤與牧草之群集分析 222 圖4-7-6 空氣(總濃度/固相/氣相)、土壤與牧草之主成分分析 222 圖4-7-7 總空氣與榕樹葉之PCDD/Fs同族物分布比較 223 圖4-7-8 空氣固相與榕樹葉之PCDD/Fs同族物分布比較 223 圖4-7-9 空氣氣相與榕樹葉之PCDD/Fs同族物分布比較 224 圖4-7-10 土壤與榕樹葉之PCDD/Fs同族物分布比較 224 圖4-7-11 空氣(總濃度/固相/氣相)、土壤與榕樹葉之群集分析圖 225 圖4-7-12 空氣(總濃度/固相/氣相)、土壤與榕樹葉之主成分分析圖 225 圖4-7-13 總空氣與土壤之PCDD/Fs同族物分布比較 226 圖4-7-14 空氣固相與土壤之PCDD/Fs同族物分布比較 226 圖4-7-15 空氣氣相與土壤之PCDD/Fs同族物分布比較 227 圖4-7-16 空氣(總濃度/固相/氣相)與土壤之群集分析圖 228 圖4-7-17 空氣(總濃度/固相/氣相)與土壤之主成分分析圖 228 圖4-8-1 總空氣與牧草之PCDD/Fs同族物分布比較(顯宮國小) 229 圖4-8-2 空氣固相與牧草之PCDD/Fs同族物分布比較(顯宮國小) 229 圖4-8-3 空氣氣相與牧草之PCDD/Fs同族物分布比較(顯宮國小) 230 圖4-8-4 土壤與牧草之PCDD/Fs同族物分布比較(顯宮國小) 230 圖4-8-5 空氣(總濃度/固相/氣相)與牧草之群集分析(顯宮國小) 231 圖4-8-6 空氣(總濃度/固相/氣相)與牧草之主成分分析圖(顯宮國小) 231 圖4-8-7 空氣與榕樹葉之PCDD/Fs同族物分布比較(顯宮國小) 232 圖4-8-8 空氣固相與榕樹葉之PCDD/Fs同族物分布比較(顯宮國小) 232 圖4-8-9 空氣氣相與榕樹葉之PCDD/Fs同族物分布比較(顯宮國小) 233 圖4-8-10 土壤與榕樹葉之PCDD/Fs同族物分布比較(顯宮國小) 233 圖4-8-11 空氣(總濃度/固相/氣相)與榕樹葉之群集分析圖(顯宮國小) 234 圖4-8-12 空氣(總濃度/固相/氣相)與榕樹葉之主成分分析圖(顯宮國小) 234 圖4-8-13 空氣與土壤之PCDD/Fs同族物分布比較(顯宮國小) 235 圖4-8-14 空氣固相與土壤之PCDD/Fs同族物分布比較(顯宮國小) 235 圖4-8-15 空氣氣相與土壤之PCDD/Fs同族物分布比較(顯宮國小) 236 圖4-8-16 空氣(總濃度/固相/氣相)與土壤之群集分析圖(顯宮國小) 236 圖4-8-17 空氣(總濃度/固相/氣相)與土壤之主成分分析圖(顯宮國小) 237

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