簡易檢索 / 詳目顯示

研究生: 方瑞麟
Fang, Ruei-Lin
論文名稱: 薄膜蒸餾式海淡設備之流道分析
Flow Channel Analysis of A SWMD Facility
指導教授: 邱政勳
Chiou, Jenq-Shing
學位類別: 碩士
Master
系所名稱: 工學院 - 機械工程學系
Department of Mechanical Engineering
論文出版年: 2004
畢業學年度: 92
語文別: 中文
論文頁數: 82
中文關鍵詞: 薄膜蒸餾流道分析
外文關鍵詞: Flow Channel Analysis, Membrane Distillation
相關次數: 點閱:64下載:2
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  •   薄膜蒸餾法兼具傳統薄膜法和蒸餾法的優點,未來極可能取代其他如傳統蒸餾法與逆滲透等技術,本文將針對薄膜蒸餾法在實用化與商業化上所遭遇到的困難,如汙堵問題、能源效率利用差、未選用適當薄膜,來提出有效的對策。
      關於處理薄膜的汙堵問題,由之前的研究成果顯示,利用UV殺菌再加上微或超微過濾的前處理系統,能非常有效地減緩薄膜汙堵,使滲透量提高,運轉時間延長。再配合超音波清洗,能有效地清除薄膜汙堵,並且使衰退的滲透量回復。
      本文最主要之重點在於如何提升能源之使用效率,吾人採用多效蒸餾的省能概念,設計出具有高效率熱交換之迴路,在主要測試段(蒸餾實際發生處)之尺寸採用EGM最佳化法來求得。
      現階段省能實驗設備的製作與架設已經完成,管路接頭的洩漏與測試段保溫問題已經解決,系統測試也顯示流體之溫度及流量的穩定性良好,當取得較好較大的MD膜時,即可執行更多之測試,以獲得更佳的實驗結果。

      Membrane distillation (MD) possess almost all the good features that can be found in both conventional membrane method and conventional distillation method. Seawater desalination by MD (SWMD) is not yet commercially available due to the problems such as membrane fouling, poor effectiveness in heat consumption, and lack of a tailor-made membrane for MD.
      The results obtained from previous tests indicate the application of UV light + MF/UF as the pretreatment method for SWMD can be a very effective way to slow down the fouling process and extend the operation time. By the use of ultrasonic cleaning technique, the foulant on the membrane can be effectively shocked off and restore the membrane’s permeate flux.
      The main task of this paper is focused on the efficiency improvement in the ultilization of heating energy during the MD processes. The concept of multi-effect distillation has been adopted in this study to design an energy-efficient flow loop. The channel configurations of main test-section where the distillation process is actually occur is optimized by the application of entropy generation minimization (EGM).
      The set-up of energy-efficient test facility has been completed. The leakage problem found at some pipe joints and the thermal insulation surrounding the test section have been resolved. The test runs were conducted smoothly. More test data will be collected whenever a better and larger MD membrane is available.

    目錄 中文摘要 ……………………………………………………………………I 英文摘要 ……………………………………………………………………II 誌謝 …………………………………………………………………………III 目錄 …………………………………………………………………………IV 表目錄 ………………………………………………………………………VII 圖目錄 ………………………………………………………………………VII 符號說明 ……………………………………………………………………IX 第一章 緒論 ………………………………………………………………1 1-1 前言 …………………………………………………………………1 1-2 薄膜蒸餾概述 ……………………………………………………3 1-2-1 薄膜蒸餾的優點 ……………………………………………………5 1-2-2 薄膜蒸餾的種類 ……………………………………………………6 1-3 文獻回顧 …………………………………………………………9 1-4 本文架構 …………………………………………………………12 第二章 理論基礎 …………………………………………………………13 2-1 前言 ……………………………………………………………13 2-2 直接接觸薄膜蒸餾法之理論分析 …………………………………13 2-2-1 直接接觸薄膜蒸餾法的傳輸過程 …………………………………14 2-2-2 質量傳輸 …………………………………………………………15 2-2-3 熱量傳輸 …………………………………………………………19 2-2-4 極化現象 …………………………………………………………21 第三章 多段省能設備之設計 ……………………………………………23 3-1 薄膜蒸餾海水淡化法之瓶頸 ……………………………………23 3-2 如何選用適當的薄膜 ………………………………………24 3-3 克服汙堵問題 ………………………………………………………24 3-3-1 前處理 …………………………………………………………25 3-3-2 超音波再生洗淨 ……………………………………………………27 3-4 提升能源效率的設計 ………………………………………28 3-5 流道之最佳化設計 …………………………………………33 3-5-1 EGM法(Entropy Generation Minimization Method) ………34 3-5-2 最佳化分析 ………………………………………………………35 第四章 實驗設備與實驗步驟 ……………………………………………43 4-1 最佳化分析之應用 …………………………………………43 4-2 實驗設備之設計 …………………………………………43 4-3 實驗設備之製作 …………………………………………44 4-3-1 冷卻水迴路 ………………………………………………………46 4-3-2 飼水迴路 …………………………………………………………47 4-3-3 測試單元 …………………………………………………………48 4-3-4 前處理單元 ………………………………………………………50 4-3-5 量測記錄元件 ………………………………………………………52 4-3-6 超音波清洗元件 ……………………………………………………54 4-4 實驗運轉程序 ………………………………………………………55 4-5 實驗方法 …………………………………………………………56 4-6 實驗注意事項 ………………………………………………………56 第五章 結果與討論 ……………………………………………………58 5-1 實驗測試結果 ………………………………………………………58 5-2 綜合結論 …………………………………………………………66 5-3 未來研究方向 ………………………………………………………66 參考文獻 ……………………………………………………………………68 附錄A ……………………………………………………………………72 附錄B ……………………………………………………………………82

    [1] ME. Findley, “Vaporization through porous membranes” I&EC Process Design and Development. 6:226-230, 1967.
    [2] ME. Findley, V.V. Tanna, Y.B. Rao, and C.L. Yeh, “Mass and heat transfer relations in evaporation through porous membranes” AICHE J. 15:483-489, 1969.
    [3] Fawzi A. Banat and Jana Simandl, “Desalination by membrane distillation: a parametric study” Separation Science and Technology. 33:201-226, 1998.
    [4] K.W. Lawson and D.R. Lloyd, “Review membrane distillation” J. of Membrane Science. 124:1-25, 1997.
    [5] K. Smolders and A.C.M. Franken, “Terminology of membrane distillation” Desalination. 72:249-262, 1989.
    [6] L. Martinez-Diez and M.I. Vazquez-Gonzalez, “Temperature polarization in mass transport through hydrophobic porous membtanes” AICHE J. 42:1844-1852, 1996.
    [7] Kevin W. Lawson and Douglas R. Lloyd, “Membrane distillation. II. Direct contact MD” J. of Membrane Science. 120:123-133, 1996.
    [8] A. Burgoyne and M.M. Vahdati, “Review Direct Contact Membrane Distillation” Separation Science and Technology. 35:1257-1284, 2000.
    [9] L. Martinez and F.J. Florido-Diaz and Vazquez-Gonzalez, “Study of evaporation efficiency in membrane distillation” Desalination 126:193-198, 1999.
    [10] F.A. Banat and J. Simandl, “Theoretical and experimental study in membrane distillation” Desalination. 95:39-52, 1994.
    [11] L. Basini, G. D’Angelo, G.C. Sarti and C. Gostoli, “A desalination process through sweeping gas membrane distillation” Desalination. 64:245-257, 1987.
    [12] Kevin W. Lawson and Douglas R. Lloyd, “Membrane distillation. I. Module design and performance evaluation vacuum membrane distillation” J. of Membrane Science. 120:111-121, 1996.
    [13] D.Y. Cheng, “Method and apparatus for distillation” United States Patent 4265713. (1981).
    [14] D.Y. Cheng and S.J. Wiersma, “Composite membrane for a membrane distillation system” United States Patent 4316772. (1982).
    [15] Einar Matthiasson and Bjorn Sivik, “Concentration polarization and fouling” Desalination. 35:59-103, 1980.
    [16] A.G. Fane, R.W. Schofield and C.J.D. Fell, ”The efficient use of energy in membrane distillation” Desalination. 64:231-243, 1987.
    [17] L. Y. Dudley and E. G. Darton, “Pretreatment procedures to control biogrowth and scale formation in membrane systems” Desalination. 110:11-20, 1997.
    [18] S. Ebrahim et al., “Microfiltration system as a pretreatment for RO units: Technical and economic assessment” Desalination. 109:165-175, 1997.
    [19] J. S. Baker and L. Y. Dudley, “Biofouling in membrane systems – A review” Desalination. 118:81-90, 1998.
    [20] L. Martinez-Diez and M. I. Vazquez-Gonzalez, “Temperature and concentration polarization in membrane distillation of aqueous salt solutions” Distillation. 156:265-273, 1999.
    [21] Chao Zhu and Guangliang Liu, “Modeling of ultrasonic enhancement on membrane distillation” Journal of Membrane Science. 176:31-41, 2000.
    [22] M. Gryta, M. Tomaszewska, J. Grzechulska and A.W. Morawski, “Membrane distillation of NaCl solution containing natural organic matter” Journal of Membrane Science. 181:279-287, 2001.
    [23] S. L. Kim et al., “Study on feed pretreatment for membrane filtration of secondary effluent” Separation and Purification Technology. 29 :171-179, 2002.
    [24] M. Tomaszewska, M. Gryta, A.W. Morawski, “A study of separation by the direct-contact membrane distillation process” Separations Technology. 4:244-248, 1994.
    [25] S.T. Hwang and K. Kammermeyer , Membrane in separations, Wiley, New York, 1975.
    [26] R.W. Schofield, A.G. Fane and C.J.D. Fell, “Heat and mass transfer in membrane distillation” J. of Membrane Science. 33:299-313, 1987.
    [27] R.B. Bird, W.E. Stewart and E.N. Lightfoot, Transport phenomena, Wiley, New York, 1960.
    [28] S. Ebrahim et al., “Fifteen years of R&D program in seawater desalination at KISR Part I. Pretreatment technologies for RO systems” Desalination. 135:141-153, 2001.
    [29] J. S. Baker and L. Y. Dudley, “Biofouling in membrane system-A review”, Desalination 118:81-90, 1998.
    [30] 邱宏茂,“在薄膜海淡系統中前處理對薄膜結垢的影響”,國立成功大學機械工程研究所碩士論文,2003.
    [31] M. Al-Ahmad et al., “Biofouling in RO membrane systems Part 1:Fundamentals and control” Desalination. 132:173-179, 2000.
    [32] 鄭光庭,”利用超音波清除薄膜結垢”,國立成功大學機械工程研究所碩士論文,2002.
    [33] A. Bejan, “Entropy generation minimization :/the method of thermodynamic optimization of finite-size systems and finite-time processes”, CRC Press, Boca Raton, 1995.
    [34] A. Bejan, “Heat transfer”, John Wiley & Sons, Inc., New York, 1993.
    [35] T. G. Leighton, “The Acoustic Bubble”, Harcourt Brance&Company, 1994.
    [36] E. Drioli and Y. Wu, “Membrane distillation: An experimental study” Desalination, 53:339-346, 1985.
    [37] A. Bejan, “Thermodynamic optimization of geometry in engineering flow systems”, Exergy Int. J., 1(4):269-277, 2001.
    [38] J.C. Ordonez, A. Bejan,“Entropy generateon minimizeation in parallel- plates counterflow heat exchangers”, Internat. J. Energy Res., 24: 843- 864, 2000.
    [39]林明雄、江明昆,“薄膜分離技術之一-逆滲透法”,台電工程月刊,443期p.70-77,(1985.4).
    [40]陳志晴,“台灣地區可資開發的新水源-海水淡化廠”,工程月刊,64卷12期p.74-91,(1991.4).
    [41]王啟川,“熱交換器設計”五南出版社,2003.
    [42]吳奇展,“薄膜蒸餾之海水淡化法之研究”,國立成功大學機械工程研究所碩士論文,1998.

    下載圖示 校內:2005-08-02公開
    校外:2007-08-02公開
    QR CODE